Autor(es): Duarte, Abel J. ; Rocha, Célia ; Silveira, Fernando ; Aguilar, Gerardo González ; Jorge, Pedro A. S. ; Leitão, João Miguel Queirós Magno ; Algarra, Manuel ; Silva, Joaquim C. G. Esteves da
Data: 2010
Identificador Persistente: http://hdl.handle.net/10400.22/3033
Origem: Repositório Científico do Instituto Politécnico do Porto
Assunto(s): Chemiluminescence; Fiber optics; Luminol; Silica nanoparticles
Silica based nanostructured composite materials doped with luminol and cobalt(II) ion were synthesized and characterized, resulting in a highly chemiluminescent material in the presence of hydrogen peroxide. A detection system with the CL light guided from the reaction tube to the photomultiplier tube using a one millimeter glass optical fiber was developed and assessed. A linear response was observed using a semi-logarithm calibration between 50–2000 µM hydrogen peroxide with 1 µM as the limit of detection.
