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Evolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.

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Resumo:Brassica rapa var. rapa L. (turnip) is highly appreciated and consumed by human. In this work, the volatile profile of B. rapa var. rapa was studied during the maturation process. The volatiles of seeds, sprouts with 6 and 9 days, and adult plant were determined using headspace solid-phase microextraction (HS-SPME) combined with gas chromatography/ion trap-mass spectrometry (GC/IT-MS). Several constituents, including alcohols, aldehydes, esters, ketones, norisoprenoids, nitrogen and sulphur compounds were characterized, totalizing 64 compounds. Isothiocyanates are the main volatiles in all matrices, being 3-butenyl isothiocyanate the major compound. Qualitative and quantitative differences were found among the analysed materials. Nitrogen and sulphur compounds decreased during the maturation process, while terpenes, aldehydes, norisoprenoids and ester compounds were present in higher amounts during germination, especially in sprouts with 9 days of development.
Autores principais:Taveira, Marcos
Outros Autores:Fernandes, Fátima; Pinho, P. Guedes de; Andrade, Paula B.; Pereira, J.A.; Valentão, Patrícia
Assunto:Brassica rapa var. rapa L. Turnip Sprouts Seeds Volatile compounds
Ano:2009
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso restrito
Instituição associada:Instituto Politécnico de Bragança
Idioma:inglês
Origem:Biblioteca Digital do IPB
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author Taveira, Marcos
author2 Fernandes, Fátima
Pinho, P. Guedes de
Andrade, Paula B.
Pereira, J.A.
Valentão, Patrícia
author2_role author
author
author
author
author
author_facet Taveira, Marcos
Fernandes, Fátima
Pinho, P. Guedes de
Andrade, Paula B.
Pereira, J.A.
Valentão, Patrícia
author_role author
contributor_name_str_mv Biblioteca Digital do IPB
country_str PT
creators_json_str [{\"Person.name\":\"Taveira, Marcos\"},{\"Person.name\":\"Fernandes, Fátima\"},{\"Person.name\":\"Pinho, P. Guedes de\"},{\"Person.name\":\"Andrade, Paula B.\"},{\"Person.name\":\"Pereira, J.A.\",\"Person.identifier.orcid\":\"0000-0002-2260-0600\"},{\"Person.name\":\"Valentão, Patrícia\"}]
datacite.contributors.contributor.contributorName.fl_str_mv Biblioteca Digital do IPB
datacite.creators.creator.creatorName.fl_str_mv Taveira, Marcos
Fernandes, Fátima
Pinho, P. Guedes de
Andrade, Paula B.
Pereira, J.A.
Valentão, Patrícia
datacite.date.Accepted.fl_str_mv 2009-01-01T00:00:00Z
datacite.date.available.fl_str_mv 2011-01-13T16:36:30Z
datacite.date.embargoed.fl_str_mv 2011-01-13T16:36:30Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_16ec
datacite.subjects.subject.fl_str_mv Brassica rapa var. rapa L.
Turnip
Sprouts
Seeds
Volatile compounds
datacite.titles.title.fl_str_mv Evolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.
dc.contributor.none.fl_str_mv Biblioteca Digital do IPB
dc.creator.none.fl_str_mv Taveira, Marcos
Fernandes, Fátima
Pinho, P. Guedes de
Andrade, Paula B.
Pereira, J.A.
Valentão, Patrícia
dc.date.Accepted.fl_str_mv 2009-01-01T00:00:00Z
dc.date.available.fl_str_mv 2011-01-13T16:36:30Z
dc.date.embargoed.fl_str_mv 2011-01-13T16:36:30Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv http://hdl.handle.net/10198/3110
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Elsevier
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_16ec
dc.subject.none.fl_str_mv Brassica rapa var. rapa L.
Turnip
Sprouts
Seeds
Volatile compounds
dc.title.fl_str_mv Evolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description Brassica rapa var. rapa L. (turnip) is highly appreciated and consumed by human. In this work, the volatile profile of B. rapa var. rapa was studied during the maturation process. The volatiles of seeds, sprouts with 6 and 9 days, and adult plant were determined using headspace solid-phase microextraction (HS-SPME) combined with gas chromatography/ion trap-mass spectrometry (GC/IT-MS). Several constituents, including alcohols, aldehydes, esters, ketones, norisoprenoids, nitrogen and sulphur compounds were characterized, totalizing 64 compounds. Isothiocyanates are the main volatiles in all matrices, being 3-butenyl isothiocyanate the major compound. Qualitative and quantitative differences were found among the analysed materials. Nitrogen and sulphur compounds decreased during the maturation process, while terpenes, aldehydes, norisoprenoids and ester compounds were present in higher amounts during germination, especially in sprouts with 9 days of development.
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eu_rights_str_mv restrictedAccess
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fulltext.url.fl_str_mv https://bibliotecadigital.ipb.pt/bitstreams/4f05f2c7-8e3a-44a9-be89-d469a1f4f542/download
funding.funder.alternateName_str_mv FCT
funding.funder.identifier_str_mv http://doi.org/10.13039/501100001871
funding.funder.name_str_mv Fundação para a Ciência e a Tecnologia
funding.name_str_mv 5876-PPCDTI
id ipb_2db1bb50fc8a093584efe4e4f6c8180b
identifier.url.fl_str_mv http://hdl.handle.net/10198/3110
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institution Instituto Politécnico de Bragança
instname_str Instituto Politécnico de Bragança
language eng
network_acronym_str ipb
network_name_str Biblioteca Digital do IPB
oai_identifier_str oai:bibliotecadigital.ipb.pt:10198/3110
organization_str_mv urn:organizationAcronym:ipb
person_str_mv Taveira, Marcos
Fernandes, Fátima
Pinho, P. Guedes de
Andrade, Paula B.
Pereira, J.A.
Pereira, J.A.
https://www.ciencia-id.pt/611F-80B2-A7C1
611F-80B2-A7C1
http://orcid.org/0000-0002-2260-0600
0000-0002-2260-0600
Valentão, Patrícia
publishDate 2009
publisher.none.fl_str_mv Elsevier
reponame_str Biblioteca Digital do IPB
repository_id_str urn:repositoryAcronym:ipb
service_str_mv urn:repositoryAcronym:ipb
spelling engElsevierporBrassica rapa var. rapa L. (turnip) is highly appreciated and consumed by human. In this work, the volatile profile of B. rapa var. rapa was studied during the maturation process. The volatiles of seeds, sprouts with 6 and 9 days, and adult plant were determined using headspace solid-phase microextraction (HS-SPME) combined with gas chromatography/ion trap-mass spectrometry (GC/IT-MS). Several constituents, including alcohols, aldehydes, esters, ketones, norisoprenoids, nitrogen and sulphur compounds were characterized, totalizing 64 compounds. Isothiocyanates are the main volatiles in all matrices, being 3-butenyl isothiocyanate the major compound. Qualitative and quantitative differences were found among the analysed materials. Nitrogen and sulphur compounds decreased during the maturation process, while terpenes, aldehydes, norisoprenoids and ester compounds were present in higher amounts during germination, especially in sprouts with 9 days of development.application/pdfporEvolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.Taveira, MarcosFernandes, FátimaPinho, P. Guedes deAndrade, Paula B.PersonalPereira, J.A.DSpacehttp://dspace.org/items/7932162e-a2da-4913-b00d-17babbe51857DSpacehttp://dspace.org/items/7932162e-a2da-4913-b00d-17babbe51857PereiraJosé AlbertoCiência IDhttps://www.ciencia-id.pt611F-80B2-A7C1ORCIDhttp://orcid.org0000-0002-2260-0600Researcher IDhttps://www.researcherid.comL-6798-2014Scopus Author IDhttps://www.scopus.com57204366348Valentão, PatríciaHostingInstitutionOrganizationalBiblioteca Digital do IPBe-mailmailto:dspace@ipb.ptdspace@ipb.pt2011-01-13T16:36:30Z20092009-01-01T00:00:00ZHandlehttp://hdl.handle.net/10198/3110http://purl.org/coar/access_right/c_16ecrestricted accessBrassica rapa var. rapa L.TurnipSproutsSeedsVolatile compounds524893 bytesFundação para a Ciência e a TecnologiaPieris brassicae as laboratory of synthesis of new compounds with biological potential, starting from Brassica oleracea var. costata, Brassica oleracea var. acephala and Brassica rapa var. rapa.5876-PPCDTICrossref Funder IDhttp://doi.org/10.13039/501100001871literaturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_16ecapplication/pdffulltexthttps://bibliotecadigital.ipb.pt/bitstreams/4f05f2c7-8e3a-44a9-be89-d469a1f4f542/downloadMicrochemical Journal93(2)140146
spellingShingle Evolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.
Taveira, Marcos
Brassica rapa var. rapa L.
Turnip
Sprouts
Seeds
Volatile compounds
subject.fl_str_mv Brassica rapa var. rapa L.
Turnip
Sprouts
Seeds
Volatile compounds
title Evolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.
title_full Evolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.
title_fullStr Evolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.
title_full_unstemmed Evolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.
title_short Evolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.
title_sort Evolution of Brassica rapa L. var. rapa volatile composition by HS-SPME and GC/IT-MS.
topic Brassica rapa var. rapa L.
Turnip
Sprouts
Seeds
Volatile compounds
topic_facet Brassica rapa var. rapa L.
Turnip
Sprouts
Seeds
Volatile compounds
url http://hdl.handle.net/10198/3110
visible 1