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Targeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)

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Resumo:Numerous plants have been used all over the world and in addition to the food properties, their consumption seems to be associated with different beneficial properties for consumers’ health. In this way, several scientific studies have been carried out with the objective of confirming these properties besides the assessment of their nutritional quality1. Hibiscus sabdariffa L., is an annual or perennial plant with red stems and calyces, belonging to the Malvaceae family. It is cultivated mainly in the tropical and subtropical areas of both hemispheres2. The present study aimed to perform a targeted metabolites’ analysis (free sugars, organic acids, tocopherols and fatty acids) of H. sabdariffa dried calyces (Guinea-Bissauan origin), as well as the individual phenolic composition of its infusion and hydroethanolic extracts. Free sugars were identified through an HPLC-RI system, the organic acids by UFLC-PDA, tocopherols by HPLC-fluorescence, fatty acids by GC-FID and the individual phenolic compounds were analysed through HPLC-DAD-ESI/MS. Glucose and quinic acid showed the major concentration for sugars and organic acids, respectively. Palmitic acid and α-tocopherol were the most abundant lipophilic compounds. In the individual phenolic profile, thirteen compounds were identified, five phenolic acids and flavonols, and three anthocyanins. The hydromethanolic extract presented all the identified compounds, while the infusion revealed the presence of twelve molecules, with the absence of caffeic acid. In general, the hydroethanolic extraction seems to have favoured the extraction of non-anthocyanin phenolic compounds, while the infusion was the ideal methodology for the anthocyanins’ extraction. Nevertheless, 3-O-caffeoylquinic acid was the major non-anthocyanin compound, while, delphinidin-3-O-sambubioside was the most abundant anthocyanin, in both extracts. This study demonstrates the high potential of this species highlighting its usage as a functional food or beverage, and as a source of a possible nutraceuticals and natural pigments, giving an added value for future applications in several industrial sectors.
Autores principais:Roriz, Custódio Lobo
Outros Autores:Pereira, Eliana; Caleja, Cristina; Catarino, Luís; Barros, Lillian; Ferreira, Isabel C.F.R.
Assunto:Hibiscus sabdariffa L. calyces Guinea-Bissau
Ano:2019
País:Portugal
Tipo de documento:documento de conferência
Tipo de acesso:acesso aberto
Instituição associada:Instituto Politécnico de Bragança
Idioma:inglês
Origem:Biblioteca Digital do IPB
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author Roriz, Custódio Lobo
author2 Pereira, Eliana
Caleja, Cristina
Catarino, Luís
Barros, Lillian
Ferreira, Isabel C.F.R.
author2_role author
author
author
author
author
author_facet Roriz, Custódio Lobo
Pereira, Eliana
Caleja, Cristina
Catarino, Luís
Barros, Lillian
Ferreira, Isabel C.F.R.
author_role author
contributor_name_str_mv Biblioteca Digital do IPB
country_str PT
creators_json_txt [{\"Person.name\":\"Roriz, Custódio Lobo\",\"Person.identifier.orcid\":\"0000-0002-4021-1078\"},{\"Person.name\":\"Pereira, Eliana\",\"Person.identifier.orcid\":\"0000-0003-2854-6745\"},{\"Person.name\":\"Caleja, Cristina\",\"Person.identifier.orcid\":\"0000-0002-5769-8484\"},{\"Person.name\":\"Catarino, Luís\"},{\"Person.name\":\"Barros, Lillian\",\"Person.identifier.orcid\":\"0000-0002-9050-5189\"},{\"Person.name\":\"Ferreira, Isabel C.F.R.\",\"Person.identifier.orcid\":\"0000-0003-4910-4882\"}]
datacite.contributors.contributor.contributorName.fl_str_mv Biblioteca Digital do IPB
datacite.creators.creator.creatorName.fl_str_mv Roriz, Custódio Lobo
Pereira, Eliana
Caleja, Cristina
Catarino, Luís
Barros, Lillian
Ferreira, Isabel C.F.R.
datacite.date.Accepted.fl_str_mv 2019-01-01T00:00:00Z
datacite.date.available.fl_str_mv 2021-10-29T09:09:16Z
datacite.date.embargoed.fl_str_mv 2021-10-29T09:09:16Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv Hibiscus sabdariffa L. calyces
Guinea-Bissau
datacite.titles.title.fl_str_mv Targeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)
dc.contributor.none.fl_str_mv Biblioteca Digital do IPB
dc.creator.none.fl_str_mv Roriz, Custódio Lobo
Pereira, Eliana
Caleja, Cristina
Catarino, Luís
Barros, Lillian
Ferreira, Isabel C.F.R.
dc.date.Accepted.fl_str_mv 2019-01-01T00:00:00Z
dc.date.available.fl_str_mv 2021-10-29T09:09:16Z
dc.date.embargoed.fl_str_mv 2021-10-29T09:09:16Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv http://hdl.handle.net/10198/24129
dc.language.none.fl_str_mv eng
dc.rights.cclincense.fl_str_mv http://creativecommons.org/licenses/by/4.0/
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.subject.none.fl_str_mv Hibiscus sabdariffa L. calyces
Guinea-Bissau
dc.title.fl_str_mv Targeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_c94f
description Numerous plants have been used all over the world and in addition to the food properties, their consumption seems to be associated with different beneficial properties for consumers’ health. In this way, several scientific studies have been carried out with the objective of confirming these properties besides the assessment of their nutritional quality1. Hibiscus sabdariffa L., is an annual or perennial plant with red stems and calyces, belonging to the Malvaceae family. It is cultivated mainly in the tropical and subtropical areas of both hemispheres2. The present study aimed to perform a targeted metabolites’ analysis (free sugars, organic acids, tocopherols and fatty acids) of H. sabdariffa dried calyces (Guinea-Bissauan origin), as well as the individual phenolic composition of its infusion and hydroethanolic extracts. Free sugars were identified through an HPLC-RI system, the organic acids by UFLC-PDA, tocopherols by HPLC-fluorescence, fatty acids by GC-FID and the individual phenolic compounds were analysed through HPLC-DAD-ESI/MS. Glucose and quinic acid showed the major concentration for sugars and organic acids, respectively. Palmitic acid and α-tocopherol were the most abundant lipophilic compounds. In the individual phenolic profile, thirteen compounds were identified, five phenolic acids and flavonols, and three anthocyanins. The hydromethanolic extract presented all the identified compounds, while the infusion revealed the presence of twelve molecules, with the absence of caffeic acid. In general, the hydroethanolic extraction seems to have favoured the extraction of non-anthocyanin phenolic compounds, while the infusion was the ideal methodology for the anthocyanins’ extraction. Nevertheless, 3-O-caffeoylquinic acid was the major non-anthocyanin compound, while, delphinidin-3-O-sambubioside was the most abundant anthocyanin, in both extracts. This study demonstrates the high potential of this species highlighting its usage as a functional food or beverage, and as a source of a possible nutraceuticals and natural pigments, giving an added value for future applications in several industrial sectors.
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funding.funder.name_str_mv Fundação para a Ciência e a Tecnologia
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person_str_mv Roriz, Custódio Lobo
Roriz, Custódio Lobo
https://www.ciencia-id.pt/9519-D97C-6B17
9519-D97C-6B17
http://orcid.org/0000-0002-4021-1078
0000-0002-4021-1078
Pereira, Eliana
Pereira, Eliana
https://www.ciencia-id.pt/BE17-462D-9A75
BE17-462D-9A75
http://orcid.org/0000-0003-2854-6745
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Caleja, Cristina
Caleja, Cristina
https://www.ciencia-id.pt/E218-8DD3-4959
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Catarino, Luís
Barros, Lillian
Barros, Lillian
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Ferreira, Isabel C.F.R.
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spelling engpt_PTNumerous plants have been used all over the world and in addition to the food properties, their consumption seems to be associated with different beneficial properties for consumers’ health. In this way, several scientific studies have been carried out with the objective of confirming these properties besides the assessment of their nutritional quality1. Hibiscus sabdariffa L., is an annual or perennial plant with red stems and calyces, belonging to the Malvaceae family. It is cultivated mainly in the tropical and subtropical areas of both hemispheres2. The present study aimed to perform a targeted metabolites’ analysis (free sugars, organic acids, tocopherols and fatty acids) of H. sabdariffa dried calyces (Guinea-Bissauan origin), as well as the individual phenolic composition of its infusion and hydroethanolic extracts. Free sugars were identified through an HPLC-RI system, the organic acids by UFLC-PDA, tocopherols by HPLC-fluorescence, fatty acids by GC-FID and the individual phenolic compounds were analysed through HPLC-DAD-ESI/MS. Glucose and quinic acid showed the major concentration for sugars and organic acids, respectively. Palmitic acid and α-tocopherol were the most abundant lipophilic compounds. In the individual phenolic profile, thirteen compounds were identified, five phenolic acids and flavonols, and three anthocyanins. The hydromethanolic extract presented all the identified compounds, while the infusion revealed the presence of twelve molecules, with the absence of caffeic acid. In general, the hydroethanolic extraction seems to have favoured the extraction of non-anthocyanin phenolic compounds, while the infusion was the ideal methodology for the anthocyanins’ extraction. Nevertheless, 3-O-caffeoylquinic acid was the major non-anthocyanin compound, while, delphinidin-3-O-sambubioside was the most abundant anthocyanin, in both extracts. This study demonstrates the high potential of this species highlighting its usage as a functional food or beverage, and as a source of a possible nutraceuticals and natural pigments, giving an added value for future applications in several industrial sectors.application/pdfpt_PTTargeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)PersonalRoriz, Custódio LoboDSpacehttp://dspace.org/items/d13ab9dd-af85-4652-bae4-88b2a9034d79DSpacehttp://dspace.org/items/d13ab9dd-af85-4652-bae4-88b2a9034d79RorizCustódio LoboCiência IDhttps://www.ciencia-id.pt9519-D97C-6B17ORCIDhttp://orcid.org0000-0002-4021-1078Scopus Author IDhttps://www.scopus.com56151637600PersonalPereira, ElianaDSpacehttp://dspace.org/items/dda60cdc-0a2a-4c10-863e-eaef1e6f1fb9DSpacehttp://dspace.org/items/dda60cdc-0a2a-4c10-863e-eaef1e6f1fb9PereiraElianaCiência IDhttps://www.ciencia-id.ptBE17-462D-9A75ORCIDhttp://orcid.org0000-0003-2854-6745Researcher IDhttps://www.researcherid.comQ-8017-2018Scopus Author IDhttps://www.scopus.com55938912300PersonalCaleja, CristinaDSpacehttp://dspace.org/items/5ef2706d-073c-4c23-9e45-498ac244118cDSpacehttp://dspace.org/items/5ef2706d-073c-4c23-9e45-498ac244118cCalejaCristinaCiência IDhttps://www.ciencia-id.ptE218-8DD3-4959ORCIDhttp://orcid.org0000-0002-5769-8484Scopus Author IDhttps://www.scopus.com36514202500Catarino, LuísPersonalBarros, LillianDSpacehttp://dspace.org/items/3af07ffe-f914-48ba-a5d5-efcf70fdce01DSpacehttp://dspace.org/items/3af07ffe-f914-48ba-a5d5-efcf70fdce01BarrosLillianCiência IDhttps://www.ciencia-id.pt9616-35CB-D001ORCIDhttp://orcid.org0000-0002-9050-5189Researcher IDhttps://www.researcherid.comJ-3600-2013Researcher IDhttps://www.researcherid.comJ-3600-2013Scopus Author IDhttps://www.scopus.com35236343600Scopus Author IDhttps://www.scopus.com57194900801PersonalFerreira, Isabel C.F.R.DSpacehttp://dspace.org/items/bd0d1537-2e03-41fb-b27a-140af9c35db8DSpacehttp://dspace.org/items/bd0d1537-2e03-41fb-b27a-140af9c35db8FerreiraIsabel C.F.R.Ciência IDhttps://www.ciencia-id.pt9418-CF95-9919ORCIDhttp://orcid.org0000-0003-4910-4882Researcher IDhttps://www.researcherid.comE-8500-2013Scopus Author IDhttps://www.scopus.com36868826600HostingInstitutionOrganizationalBiblioteca Digital do IPBe-mailmailto:dspace@ipb.ptdspace@ipb.ptISBNIsPartOf978-989-8124-29-62021-10-29T09:09:16Z20192019-01-01T00:00:00ZHandlehttp://hdl.handle.net/10198/24129http://purl.org/coar/access_right/c_abf2open accessHibiscus sabdariffa L. calycesGuinea-Bissau2174240 bytesFundação para a Ciência e a TecnologiaMountain Research Centre6817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaDevelopment of a new colouring agent from Gomphrena globosa L.: optimization of the extraction process, stability studies and proof-of-concept in a food matrixPOR_NORTECrossref Funder IDhttp://doi.org/10.13039/501100001871other research producthttp://purl.org/coar/resource_type/c_c94fconference object2019http://creativecommons.org/licenses/by/4.0/http://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://bibliotecadigital.ipb.pt/bitstreams/fd0577e3-7fd9-445c-9ba3-00b6148a57dd/download11th National Meeting on ChromatographyCaparica, Portugal
spellingShingle Targeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)
Roriz, Custódio Lobo
Hibiscus sabdariffa L. calyces
Guinea-Bissau
status SINGLETON
subject.fl_str_mv Hibiscus sabdariffa L. calyces
Guinea-Bissau
title Targeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)
title_full Targeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)
title_fullStr Targeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)
title_full_unstemmed Targeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)
title_short Targeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)
title_sort Targeted metabolites’ analysis of Hibiscus sabdariffa L. calyces from Guinea-Bissau (West Africa)
topic Hibiscus sabdariffa L. calyces
Guinea-Bissau
topic_facet Hibiscus sabdariffa L. calyces
Guinea-Bissau
url http://hdl.handle.net/10198/24129
visible 1