Publicação
Separation of Branched Alkane Feeds with Metal-Organic Frameworks
| Resumo: | The production of high-quality gasoline is currently achieved through the Total Isomerization Process that separates n/iso-paraffins in the pentane (C5) and hexane (C6) range while not reaching the ultimate goal of a research octane number (RON) higher than 92. This work demonstrates two promising alternatives/strategies using metal-organic frameworks (MOF) that lead to a novel adsorptive separation process to overcome this limitation. Here, the efficient discrimination of C5/C6 alkane isomers into valuable fractions of high RON (HRON – 2,3-dimethylbutane (23DMB; RON 105), 2,2-dimethylbutane (22DMB; RON 94), and isopentane (iC5; RON 93.5)) and low RON (LRON – n-pentane (nC5; RON 61.7), (nC6; RON 30), 2-methylpentane (2MP; RON 74.5), and 3-methylpentane (3MP; RON 75.5)) compounds is achieved. |
|---|---|
| Autores principais: | Henrique, Adriano |
| Outros Autores: | Brântuas, Pedro; Zafanelli, Lucas F.A.S.; Aly, Ezzeldin; Rodrigues, Alírio; Maurin, Guillaume; Serre, Christian; Silva, José A.C. |
| Assunto: | RON improvement of gasoline Pentane and hexane isomers separation by adsorption Metal-Organic Frameworks (MOFs) |
| Ano: | 2024 |
| País: | Portugal |
| Tipo de documento: | póster em conferência |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Instituto Politécnico de Bragança |
| Idioma: | inglês |
| Origem: | Biblioteca Digital do IPB |
| _version_ | 1867173342867357696 |
|---|---|
| author | Henrique, Adriano |
| author2 | Brântuas, Pedro Zafanelli, Lucas F.A.S. Aly, Ezzeldin Rodrigues, Alírio Maurin, Guillaume Serre, Christian Silva, José A.C. |
| author2_role | author author author author author author author |
| author_facet | Henrique, Adriano Brântuas, Pedro Zafanelli, Lucas F.A.S. Aly, Ezzeldin Rodrigues, Alírio Maurin, Guillaume Serre, Christian Silva, José A.C. |
| author_role | author |
| contributor_name_str_mv | Biblioteca Digital do IPB |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Henrique, Adriano\",\"Person.identifier.orcid\":\"0000-0002-5227-9790\"},{\"Person.name\":\"Brântuas, Pedro\",\"Person.identifier.orcid\":\"0000-0002-6488-2001\"},{\"Person.name\":\"Zafanelli, Lucas F.A.S.\",\"Person.identifier.orcid\":\"0000-0001-5187-2042\"},{\"Person.name\":\"Aly, Ezzeldin\",\"Person.identifier.orcid\":\"0000-0003-4840-2597\"},{\"Person.name\":\"Rodrigues, Alírio\"},{\"Person.name\":\"Maurin, Guillaume\"},{\"Person.name\":\"Serre, Christian\"},{\"Person.name\":\"Silva, José A.C.\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | Biblioteca Digital do IPB |
| datacite.creators.creator.creatorName.fl_str_mv | Henrique, Adriano Brântuas, Pedro Zafanelli, Lucas F.A.S. Aly, Ezzeldin Rodrigues, Alírio Maurin, Guillaume Serre, Christian Silva, José A.C. |
| datacite.date.Accepted.fl_str_mv | 2024-01-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2025-01-20T12:09:26Z |
| datacite.date.embargoed.fl_str_mv | 2025-01-20T12:09:26Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | RON improvement of gasoline Pentane and hexane isomers separation by adsorption Metal-Organic Frameworks (MOFs) |
| datacite.titles.title.fl_str_mv | Separation of Branched Alkane Feeds with Metal-Organic Frameworks |
| dc.contributor.none.fl_str_mv | Biblioteca Digital do IPB |
| dc.creator.none.fl_str_mv | Henrique, Adriano Brântuas, Pedro Zafanelli, Lucas F.A.S. Aly, Ezzeldin Rodrigues, Alírio Maurin, Guillaume Serre, Christian Silva, José A.C. |
| dc.date.Accepted.fl_str_mv | 2024-01-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2025-01-20T12:09:26Z |
| dc.date.embargoed.fl_str_mv | 2025-01-20T12:09:26Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/10198/31037 |
| dc.language.none.fl_str_mv | eng |
| dc.rights.cclincense.fl_str_mv | http://creativecommons.org/licenses/by/4.0/ |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.subject.none.fl_str_mv | RON improvement of gasoline Pentane and hexane isomers separation by adsorption Metal-Organic Frameworks (MOFs) |
| dc.title.fl_str_mv | Separation of Branched Alkane Feeds with Metal-Organic Frameworks |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6670 |
| description | The production of high-quality gasoline is currently achieved through the Total Isomerization Process that separates n/iso-paraffins in the pentane (C5) and hexane (C6) range while not reaching the ultimate goal of a research octane number (RON) higher than 92. This work demonstrates two promising alternatives/strategies using metal-organic frameworks (MOF) that lead to a novel adsorptive separation process to overcome this limitation. Here, the efficient discrimination of C5/C6 alkane isomers into valuable fractions of high RON (HRON – 2,3-dimethylbutane (23DMB; RON 105), 2,2-dimethylbutane (22DMB; RON 94), and isopentane (iC5; RON 93.5)) and low RON (LRON – n-pentane (nC5; RON 61.7), (nC6; RON 30), 2-methylpentane (2MP; RON 74.5), and 3-methylpentane (3MP; RON 75.5)) compounds is achieved. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | conferencePoster |
| fulltext.url.fl_str_mv | https://bibliotecadigital.ipb.pt/bitstreams/a97c983b-da11-44dd-a888-02fa12b3a7b1/download |
| funding.funder.alternateName_str_mv | FCT FCT FCT FCT FCT FCT FCT |
| funding.funder.identifier_str_mv | http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 |
| funding.funder.name_str_mv | Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia |
| funding.name_str_mv | 9471 - RIDTI 6817 - DCRRNI ID 6817 - DCRRNI ID 6817 - DCRRNI ID 6817 - DCRRNI ID 6817 - DCRRNI ID |
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| identifier.url.fl_str_mv | http://hdl.handle.net/10198/31037 |
| instacron_str | ipb |
| institution | Instituto Politécnico de Bragança |
| instname_str | Instituto Politécnico de Bragança |
| language | eng |
| network_acronym_str | ipb |
| network_name_str | Biblioteca Digital do IPB |
| oai_identifier_str | oai:bibliotecadigital.ipb.pt:10198/31037 |
| organization_str_mv | urn:organizationAcronym:ipb |
| person_str_mv | Henrique, Adriano Henrique, Adriano https://www.ciencia-id.pt/DB18-4E7D-6696 DB18-4E7D-6696 http://orcid.org/0000-0002-5227-9790 0000-0002-5227-9790 Brântuas, Pedro Brântuas, Pedro https://www.ciencia-id.pt/7019-9B98-EB05 7019-9B98-EB05 http://orcid.org/0000-0002-6488-2001 0000-0002-6488-2001 Zafanelli, Lucas F.A.S. Zafanelli, Lucas F.A.S. https://www.ciencia-id.pt/3D11-114D-1019 3D11-114D-1019 http://orcid.org/0000-0001-5187-2042 0000-0001-5187-2042 Aly, Ezzeldin Aly, Ezzeldin http://orcid.org/0000-0003-4840-2597 0000-0003-4840-2597 Rodrigues, Alírio Maurin, Guillaume Serre, Christian Silva, José A.C. |
| publishDate | 2024 |
| reponame_str | Biblioteca Digital do IPB |
| repository_id_str | urn:repositoryAcronym:ipb |
| service_str_mv | urn:repositoryAcronym:ipb |
| spelling | engpt_PTThe production of high-quality gasoline is currently achieved through the Total Isomerization Process that separates n/iso-paraffins in the pentane (C5) and hexane (C6) range while not reaching the ultimate goal of a research octane number (RON) higher than 92. This work demonstrates two promising alternatives/strategies using metal-organic frameworks (MOF) that lead to a novel adsorptive separation process to overcome this limitation. Here, the efficient discrimination of C5/C6 alkane isomers into valuable fractions of high RON (HRON – 2,3-dimethylbutane (23DMB; RON 105), 2,2-dimethylbutane (22DMB; RON 94), and isopentane (iC5; RON 93.5)) and low RON (LRON – n-pentane (nC5; RON 61.7), (nC6; RON 30), 2-methylpentane (2MP; RON 74.5), and 3-methylpentane (3MP; RON 75.5)) compounds is achieved.application/pdfpt_PTSeparation of Branched Alkane Feeds with Metal-Organic FrameworksPersonalHenrique, AdrianoDSpacehttp://dspace.org/items/8f18b8ea-087b-4626-b5f1-9b66b1aa993fDSpacehttp://dspace.org/items/8f18b8ea-087b-4626-b5f1-9b66b1aa993fHenriqueAdrianoCiência IDhttps://www.ciencia-id.ptDB18-4E7D-6696ORCIDhttp://orcid.org0000-0002-5227-9790PersonalBrântuas, PedroDSpacehttp://dspace.org/items/8db5a58b-6e02-4409-9382-218db7fdd233DSpacehttp://dspace.org/items/8db5a58b-6e02-4409-9382-218db7fdd233BrântuasPedroCiência IDhttps://www.ciencia-id.pt7019-9B98-EB05ORCIDhttp://orcid.org0000-0002-6488-2001PersonalZafanelli, Lucas F.A.S.DSpacehttp://dspace.org/items/2578e37a-73f2-45df-8adb-723f6c027606DSpacehttp://dspace.org/items/2578e37a-73f2-45df-8adb-723f6c027606ZafanelliLucas F.A.S.Ciência IDhttps://www.ciencia-id.pt3D11-114D-1019ORCIDhttp://orcid.org0000-0001-5187-2042PersonalAly, EzzeldinDSpacehttp://dspace.org/items/c0a51f8a-4f65-4b81-81e5-32c14291022fDSpacehttp://dspace.org/items/c0a51f8a-4f65-4b81-81e5-32c14291022fAlyEzzeldinORCIDhttp://orcid.org0000-0003-4840-2597Rodrigues, AlírioMaurin, GuillaumeSerre, ChristianSilva, José A.C.HostingInstitutionOrganizationalBiblioteca Digital do IPBe-mailmailto:dspace@ipb.ptdspace@ipb.pt2025-01-20T12:09:26Z20242024-01-01T00:00:00ZHandlehttp://hdl.handle.net/10198/31037http://purl.org/coar/access_right/c_abf2open accessRON improvement of gasolinePentane and hexane isomers separation by adsorptionMetal-Organic Frameworks (MOFs)1932902 bytesFundação para a Ciência e a TecnologiaUpgrading of Total Isomerization Processes with Metal-Organic Frameworks9471 - RIDTICrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaUpgrading of Total Isomerization Processes with Metal Organic FrameworksCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaMountain Research Center6817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaMountain Research Center6817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaALICE - Associate Laboratory in Chemical Engineering6817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials6817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials6817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871other research producthttp://purl.org/coar/resource_type/c_6670conference poster2024http://creativecommons.org/licenses/by/4.0/http://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://bibliotecadigital.ipb.pt/bitstreams/a97c983b-da11-44dd-a888-02fa12b3a7b1/downloadAIChE Annual MeetingSan Diego |
| spellingShingle | Separation of Branched Alkane Feeds with Metal-Organic Frameworks Henrique, Adriano RON improvement of gasoline Pentane and hexane isomers separation by adsorption Metal-Organic Frameworks (MOFs) |
| status | SINGLETON |
| subject.fl_str_mv | RON improvement of gasoline Pentane and hexane isomers separation by adsorption Metal-Organic Frameworks (MOFs) |
| title | Separation of Branched Alkane Feeds with Metal-Organic Frameworks |
| title_full | Separation of Branched Alkane Feeds with Metal-Organic Frameworks |
| title_fullStr | Separation of Branched Alkane Feeds with Metal-Organic Frameworks |
| title_full_unstemmed | Separation of Branched Alkane Feeds with Metal-Organic Frameworks |
| title_short | Separation of Branched Alkane Feeds with Metal-Organic Frameworks |
| title_sort | Separation of Branched Alkane Feeds with Metal-Organic Frameworks |
| topic | RON improvement of gasoline Pentane and hexane isomers separation by adsorption Metal-Organic Frameworks (MOFs) |
| topic_facet | RON improvement of gasoline Pentane and hexane isomers separation by adsorption Metal-Organic Frameworks (MOFs) |
| url | http://hdl.handle.net/10198/31037 |
| visible | 1 |