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Phenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stages

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Resumo:The rapid increase of the world population has promoted a more sustainable and efficient use of natural resources. To achieve complete and proper upcycling of plant crops, it is important to know their potential for industrial exploitation. Cardoon (Cynara cardunculus L.) is a species native to the Mediterranean basin widely used in different sectors, including food and pharmaceuticals. Despite their multiple industrial applications, not all plant tissues have been incorporated into the value chain. Therefore, this work aimed to characterize the phenolic composition and bioactive properties of cardoon blades throughout the phenological growth cycle. In addition to the structural variety of phytochemicals detected in the blade extracts, their antioxidant, anti-inflammatory, anti-proliferative, and antimicrobial properties were also highlighted. While immature material showed higher levels of phenolic compounds and greater potential to inhibit lipid peroxidation, samples at higher development stages had greater anti-proliferative, anti-inflammatory, and antimicrobial potential. These results demonstrate that the growth cycle influences the bioactive potential of cardoon blades and will be useful to establish suitable industrial applications, such as the development of ingredients for functional foods and nutraceuticals, among other products. Abstract: Cardoon (Cynara cardunculus var. altilis) blades were collected at sixteen sampling dates (B1–B16) to study the influence of the phenological growth stage on the phenolic composition and biological properties. Twenty phenolic compounds were identified, among which trans 3,4-O-dicaffeoylquinic acid, 5-O- caffeoylquinic acid, and luteolin-O-hexoside (39.6, 42.6, and 101.0 mg/g extract, respectively) were the main compounds. Immature blades (B3) had a higher content of phenolic compounds (178 mg/g extract) and a greater ability to inhibit the formation of thiobarbituric acid reactive substances (IC50 of 1.61 μg/mL). Samples at more advanced growth stages revealed a greater capacity to inhibit oxidative hemolysis (B8, IC50 of 25 and 47.4 μg/mL for ∆t of 60 and 120 min, respectively) and higher cytotoxic (B8–B13, GI50 between 7.1 and 17 μg/mL), anti-inflammatory (B13, IC50 of 10 μg/mL), and antibacterial activities. In turn, the antifungal activity varied depending on the tested fungi. All these results suggest that maturity influences the phenolic composition and bioactive properties of cardoon blades, which reveal great potential for the development of bioactive ingredients for food and pharmaceutical applications, among others.
Autores principais:Mandim, Filipa
Outros Autores:Petropoulos, Spyridon Α.; Pinela, José; Dias, Maria Inês; Kostić, Marina; Soković, Marina; Ferreira, Isabel C.F.R.; Barros, Lillian; Santos-Buelga, Celestino
Assunto:Cardoon blades Phenolic compounds Phenological growth stage Antioxidant activity Tumor cell growth inhibition Antibacterial/antifungal activity Sustainable ingredients
Ano:2022
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Instituto Politécnico de Bragança
Idioma:inglês
Origem:Biblioteca Digital do IPB
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author Mandim, Filipa
author2 Petropoulos, Spyridon Α.
Pinela, José
Dias, Maria Inês
Kostić, Marina
Soković, Marina
Ferreira, Isabel C.F.R.
Barros, Lillian
Santos-Buelga, Celestino
author2_role author
author
author
author
author
author
author
author
author_facet Mandim, Filipa
Petropoulos, Spyridon Α.
Pinela, José
Dias, Maria Inês
Kostić, Marina
Soković, Marina
Ferreira, Isabel C.F.R.
Barros, Lillian
Santos-Buelga, Celestino
author_role author
contributor_name_str_mv Biblioteca Digital do IPB
country_str PT
creators_json_txt [{\"Person.name\":\"Mandim, Filipa\",\"Person.identifier.orcid\":\"0000-0002-6494-2326\"},{\"Person.name\":\"Petropoulos, Spyridon Α.\"},{\"Person.name\":\"Pinela, José\",\"Person.identifier.orcid\":\"0000-0001-7523-1637\"},{\"Person.name\":\"Dias, Maria Inês\",\"Person.identifier.orcid\":\"0000-0001-8744-7814\"},{\"Person.name\":\"Kostić, Marina\"},{\"Person.name\":\"Soković, Marina\"},{\"Person.name\":\"Ferreira, Isabel C.F.R.\",\"Person.identifier.orcid\":\"0000-0003-4910-4882\"},{\"Person.name\":\"Barros, Lillian\",\"Person.identifier.orcid\":\"0000-0002-9050-5189\"},{\"Person.name\":\"Santos-Buelga, Celestino\"}]
datacite.contributors.contributor.contributorName.fl_str_mv Biblioteca Digital do IPB
datacite.creators.creator.creatorName.fl_str_mv Mandim, Filipa
Petropoulos, Spyridon Α.
Pinela, José
Dias, Maria Inês
Kostić, Marina
Soković, Marina
Ferreira, Isabel C.F.R.
Barros, Lillian
Santos-Buelga, Celestino
datacite.date.Accepted.fl_str_mv 2022-01-01T00:00:00Z
datacite.date.available.fl_str_mv 2018-01-19T10:00:00Z
datacite.date.embargoed.fl_str_mv 2018-01-19T10:00:00Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv Cardoon blades
Phenolic compounds
Phenological growth stage
Antioxidant activity
Tumor cell growth inhibition
Antibacterial/antifungal activity
Sustainable ingredients
datacite.titles.title.fl_str_mv Phenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stages
dc.contributor.none.fl_str_mv Biblioteca Digital do IPB
dc.creator.none.fl_str_mv Mandim, Filipa
Petropoulos, Spyridon Α.
Pinela, José
Dias, Maria Inês
Kostić, Marina
Soković, Marina
Ferreira, Isabel C.F.R.
Barros, Lillian
Santos-Buelga, Celestino
dc.date.Accepted.fl_str_mv 2022-01-01T00:00:00Z
dc.date.available.fl_str_mv 2018-01-19T10:00:00Z
dc.date.embargoed.fl_str_mv 2018-01-19T10:00:00Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv http://hdl.handle.net/10198/22326
dc.language.none.fl_str_mv eng
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.subject.none.fl_str_mv Cardoon blades
Phenolic compounds
Phenological growth stage
Antioxidant activity
Tumor cell growth inhibition
Antibacterial/antifungal activity
Sustainable ingredients
dc.title.fl_str_mv Phenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stages
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description The rapid increase of the world population has promoted a more sustainable and efficient use of natural resources. To achieve complete and proper upcycling of plant crops, it is important to know their potential for industrial exploitation. Cardoon (Cynara cardunculus L.) is a species native to the Mediterranean basin widely used in different sectors, including food and pharmaceuticals. Despite their multiple industrial applications, not all plant tissues have been incorporated into the value chain. Therefore, this work aimed to characterize the phenolic composition and bioactive properties of cardoon blades throughout the phenological growth cycle. In addition to the structural variety of phytochemicals detected in the blade extracts, their antioxidant, anti-inflammatory, anti-proliferative, and antimicrobial properties were also highlighted. While immature material showed higher levels of phenolic compounds and greater potential to inhibit lipid peroxidation, samples at higher development stages had greater anti-proliferative, anti-inflammatory, and antimicrobial potential. These results demonstrate that the growth cycle influences the bioactive potential of cardoon blades and will be useful to establish suitable industrial applications, such as the development of ingredients for functional foods and nutraceuticals, among other products. Abstract: Cardoon (Cynara cardunculus var. altilis) blades were collected at sixteen sampling dates (B1–B16) to study the influence of the phenological growth stage on the phenolic composition and biological properties. Twenty phenolic compounds were identified, among which trans 3,4-O-dicaffeoylquinic acid, 5-O- caffeoylquinic acid, and luteolin-O-hexoside (39.6, 42.6, and 101.0 mg/g extract, respectively) were the main compounds. Immature blades (B3) had a higher content of phenolic compounds (178 mg/g extract) and a greater ability to inhibit the formation of thiobarbituric acid reactive substances (IC50 of 1.61 μg/mL). Samples at more advanced growth stages revealed a greater capacity to inhibit oxidative hemolysis (B8, IC50 of 25 and 47.4 μg/mL for ∆t of 60 and 120 min, respectively) and higher cytotoxic (B8–B13, GI50 between 7.1 and 17 μg/mL), anti-inflammatory (B13, IC50 of 10 μg/mL), and antibacterial activities. In turn, the antifungal activity varied depending on the tested fungi. All these results suggest that maturity influences the phenolic composition and bioactive properties of cardoon blades, which reveal great potential for the development of bioactive ingredients for food and pharmaceutical applications, among others.
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funding.funder.alternateName_str_mv FCT
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funding.funder.identifier_str_mv http://doi.org/10.13039/501100001871
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funding.funder.name_str_mv Fundação para a Ciência e a Tecnologia
Fundação para a Ciência e a Tecnologia
funding.name_str_mv 6817 - DCRRNI ID
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person_str_mv Mandim, Filipa
Mandim, Filipa
https://www.ciencia-id.pt/F318-9049-EB99
F318-9049-EB99
http://orcid.org/0000-0002-6494-2326
0000-0002-6494-2326
Petropoulos, Spyridon Α.
Pinela, José
Pinela, José
https://www.ciencia-id.pt/771C-2B43-B108
771C-2B43-B108
http://orcid.org/0000-0001-7523-1637
0000-0001-7523-1637
Dias, Maria Inês
Dias, Maria Inês
https://www.ciencia-id.pt/2A13-4BE6-C7CF
2A13-4BE6-C7CF
http://orcid.org/0000-0001-8744-7814
0000-0001-8744-7814
Kostić, Marina
Soković, Marina
Ferreira, Isabel C.F.R.
Ferreira, Isabel C.F.R.
https://www.ciencia-id.pt/9418-CF95-9919
9418-CF95-9919
http://orcid.org/0000-0003-4910-4882
0000-0003-4910-4882
Barros, Lillian
Barros, Lillian
https://www.ciencia-id.pt/9616-35CB-D001
9616-35CB-D001
http://orcid.org/0000-0002-9050-5189
0000-0002-9050-5189
Santos-Buelga, Celestino
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spelling engThe rapid increase of the world population has promoted a more sustainable and efficient use of natural resources. To achieve complete and proper upcycling of plant crops, it is important to know their potential for industrial exploitation. Cardoon (Cynara cardunculus L.) is a species native to the Mediterranean basin widely used in different sectors, including food and pharmaceuticals. Despite their multiple industrial applications, not all plant tissues have been incorporated into the value chain. Therefore, this work aimed to characterize the phenolic composition and bioactive properties of cardoon blades throughout the phenological growth cycle. In addition to the structural variety of phytochemicals detected in the blade extracts, their antioxidant, anti-inflammatory, anti-proliferative, and antimicrobial properties were also highlighted. While immature material showed higher levels of phenolic compounds and greater potential to inhibit lipid peroxidation, samples at higher development stages had greater anti-proliferative, anti-inflammatory, and antimicrobial potential. These results demonstrate that the growth cycle influences the bioactive potential of cardoon blades and will be useful to establish suitable industrial applications, such as the development of ingredients for functional foods and nutraceuticals, among other products. Abstract: Cardoon (Cynara cardunculus var. altilis) blades were collected at sixteen sampling dates (B1–B16) to study the influence of the phenological growth stage on the phenolic composition and biological properties. Twenty phenolic compounds were identified, among which trans 3,4-O-dicaffeoylquinic acid, 5-O- caffeoylquinic acid, and luteolin-O-hexoside (39.6, 42.6, and 101.0 mg/g extract, respectively) were the main compounds. Immature blades (B3) had a higher content of phenolic compounds (178 mg/g extract) and a greater ability to inhibit the formation of thiobarbituric acid reactive substances (IC50 of 1.61 μg/mL). Samples at more advanced growth stages revealed a greater capacity to inhibit oxidative hemolysis (B8, IC50 of 25 and 47.4 μg/mL for ∆t of 60 and 120 min, respectively) and higher cytotoxic (B8–B13, GI50 between 7.1 and 17 μg/mL), anti-inflammatory (B13, IC50 of 10 μg/mL), and antibacterial activities. In turn, the antifungal activity varied depending on the tested fungi. All these results suggest that maturity influences the phenolic composition and bioactive properties of cardoon blades, which reveal great potential for the development of bioactive ingredients for food and pharmaceutical applications, among others.application/pdfen_ENPhenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stagesPersonalMandim, FilipaDSpacehttp://dspace.org/items/bcc274d4-7e6c-46a8-8e49-2752f9dbfbcdDSpacehttp://dspace.org/items/bcc274d4-7e6c-46a8-8e49-2752f9dbfbcdMandimFilipaCiência IDhttps://www.ciencia-id.ptF318-9049-EB99ORCIDhttp://orcid.org0000-0002-6494-2326Petropoulos, Spyridon Α.PersonalPinela, JoséDSpacehttp://dspace.org/items/706cd9ff-065b-4c98-98a7-5c0a9e45adc4DSpacehttp://dspace.org/items/706cd9ff-065b-4c98-98a7-5c0a9e45adc4PinelaJoséCiência IDhttps://www.ciencia-id.pt771C-2B43-B108ORCIDhttp://orcid.org0000-0001-7523-1637Researcher IDhttps://www.researcherid.comB-4466-2014Scopus Author IDhttps://www.scopus.com54392272800PersonalDias, Maria InêsDSpacehttp://dspace.org/items/7ca8432b-e7f4-4116-a56e-9eba0d4403bdDSpacehttp://dspace.org/items/7ca8432b-e7f4-4116-a56e-9eba0d4403bdDiasMaria InêsCiência IDhttps://www.ciencia-id.pt2A13-4BE6-C7CFORCIDhttp://orcid.org0000-0001-8744-7814Researcher IDhttps://www.researcherid.comM-8242-2013Scopus Author IDhttps://www.scopus.com54388787000Kostić, MarinaSoković, MarinaPersonalFerreira, Isabel C.F.R.DSpacehttp://dspace.org/items/bd0d1537-2e03-41fb-b27a-140af9c35db8DSpacehttp://dspace.org/items/bd0d1537-2e03-41fb-b27a-140af9c35db8FerreiraIsabel C.F.R.Ciência IDhttps://www.ciencia-id.pt9418-CF95-9919ORCIDhttp://orcid.org0000-0003-4910-4882Researcher IDhttps://www.researcherid.comE-8500-2013Scopus Author IDhttps://www.scopus.com36868826600PersonalBarros, LillianDSpacehttp://dspace.org/items/3af07ffe-f914-48ba-a5d5-efcf70fdce01DSpacehttp://dspace.org/items/3af07ffe-f914-48ba-a5d5-efcf70fdce01BarrosLillianCiência IDhttps://www.ciencia-id.pt9616-35CB-D001ORCIDhttp://orcid.org0000-0002-9050-5189Researcher IDhttps://www.researcherid.comJ-3600-2013Researcher IDhttps://www.researcherid.comJ-3600-2013Scopus Author IDhttps://www.scopus.com35236343600Scopus Author IDhttps://www.scopus.com57194900801Santos-Buelga, CelestinoHostingInstitutionOrganizationalBiblioteca Digital do IPBe-mailmailto:dspace@ipb.ptdspace@ipb.ptDOIIsPartOf10.3390/biology110506992018-01-19T10:00:00Z20222022-01-01T00:00:00ZHandlehttp://hdl.handle.net/10198/22326http://purl.org/coar/access_right/c_abf2open accessCardoon bladesPhenolic compoundsPhenological growth stageAntioxidant activityTumor cell growth inhibitionAntibacterial/antifungal activitySustainable ingredients631838 bytesFundação para a Ciência e a TecnologiaMountain Research Center6817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaIntegrated strategies for the development of a novel functional beverage with sustainable production systemsCrossref Funder IDhttp://doi.org/10.13039/501100001871literaturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://bibliotecadigital.ipb.pt/bitstreams/4c494183-daec-44d8-88bb-7b7176dcad3b/download
spellingShingle Phenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stages
Mandim, Filipa
Cardoon blades
Phenolic compounds
Phenological growth stage
Antioxidant activity
Tumor cell growth inhibition
Antibacterial/antifungal activity
Sustainable ingredients
status SINGLETON
subject.fl_str_mv Cardoon blades
Phenolic compounds
Phenological growth stage
Antioxidant activity
Tumor cell growth inhibition
Antibacterial/antifungal activity
Sustainable ingredients
title Phenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stages
title_full Phenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stages
title_fullStr Phenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stages
title_full_unstemmed Phenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stages
title_short Phenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stages
title_sort Phenolic composition and antioxidant, anti-inflammatory, cytotoxic, and antimicrobial activities of cardoon blades at different growth stages
topic Cardoon blades
Phenolic compounds
Phenological growth stage
Antioxidant activity
Tumor cell growth inhibition
Antibacterial/antifungal activity
Sustainable ingredients
topic_facet Cardoon blades
Phenolic compounds
Phenological growth stage
Antioxidant activity
Tumor cell growth inhibition
Antibacterial/antifungal activity
Sustainable ingredients
url http://hdl.handle.net/10198/22326
visible 1