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Optimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowers

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Resumo:Hibiscus sabdariffa L. is an herbaceous medicinal plantused as infusion for the treatment of several disorders, namely, fever and high blood pressure, gastrointestinal and hepatic diseases. In addition to those health benefits, the calyces area potential source of natural pigments, due to its high content in anthocyanins. This work aimed to optimize the experimental conditions of anthocyanins’extraction from dried calyces of H. sabdariffa, comparing two methodologies, maceration and ultrasound assisted extraction, in order to develop a natural colorant. To obtain the conditions that maximize anthocyanins’ extraction, a response surface methodology (RSM) was applied using the circumscribed central composite design of three variables with five levels. Time, temperature and ethanol - water proportion - in the case of maceration, were the relevant independent variables, while for ultrasound assisted extraction, the ultrasonic power was used instead of temperature which was kept constant. Two anthocyanin compounds were identified by HPLC-DAD-ESI/MS: delphinidin3-sambubioside and cyanidin-3-sambubioside. The responses used as criteria were the quantification of the identified anthocyanins and the extraction yield of the final residue. Ultrasound assisted extraction proved to be the most effective method: 43 min, 390 W and 46 % of ethanol. At these optimal conditions, the extraction yield was 61.2%, with a total anthocyanins’ content of 23.1 mg/g dried plant, and 47.5 mg/g extract. Additionally, the response values were slightly improved by studying the solid/liquid ratio effect using the optimal conditions in dose-response format (5 to 200 g/L), showing continuously decreasing values as the solid/liquid ratio increases. Overall, the obtained results showed the possibility of using H. sabdariffa flowers as a source of anthocyanin compounds for industrial applications.
Autores principais:Jabeur, Inès
Outros Autores:Pereira, Eliana; Prieto Lage, Miguel A.; Antonio, Amilcar L.; Barros, Lillian; Ferreira, Isabel C.F.R.
Assunto:Hibiscus sabdariffa L. flowers Anthocyanins Heat and ultrasound assisted extractions Response surface methodology
Ano:2018
País:Portugal
Tipo de documento:documento de conferência
Tipo de acesso:acesso aberto
Instituição associada:Instituto Politécnico de Bragança
Idioma:inglês
Origem:Biblioteca Digital do IPB
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author Jabeur, Inès
author2 Pereira, Eliana
Prieto Lage, Miguel A.
Antonio, Amilcar L.
Barros, Lillian
Ferreira, Isabel C.F.R.
author2_role author
author
author
author
author
author_facet Jabeur, Inès
Pereira, Eliana
Prieto Lage, Miguel A.
Antonio, Amilcar L.
Barros, Lillian
Ferreira, Isabel C.F.R.
author_role author
contributor_name_str_mv Biblioteca Digital do IPB
country_str PT
creators_json_txt [{\"Person.name\":\"Jabeur, Inès\",\"Person.identifier.orcid\":\"0000-0002-7485-3554\"},{\"Person.name\":\"Pereira, Eliana\",\"Person.identifier.orcid\":\"0000-0003-2854-6745\"},{\"Person.name\":\"Prieto Lage, Miguel A.\",\"Person.identifier.orcid\":\"0000-0002-3513-0054\"},{\"Person.name\":\"Antonio, Amilcar L.\",\"Person.identifier.orcid\":\"0000-0001-8271-9964\"},{\"Person.name\":\"Barros, Lillian\",\"Person.identifier.orcid\":\"0000-0002-9050-5189\"},{\"Person.name\":\"Ferreira, Isabel C.F.R.\",\"Person.identifier.orcid\":\"0000-0003-4910-4882\"}]
datacite.contributors.contributor.contributorName.fl_str_mv Biblioteca Digital do IPB
datacite.creators.creator.creatorName.fl_str_mv Jabeur, Inès
Pereira, Eliana
Prieto Lage, Miguel A.
Antonio, Amilcar L.
Barros, Lillian
Ferreira, Isabel C.F.R.
datacite.date.Accepted.fl_str_mv 2018-01-01T00:00:00Z
datacite.date.available.fl_str_mv 2018-10-17T15:37:03Z
datacite.date.embargoed.fl_str_mv 2018-10-17T15:37:03Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv Hibiscus sabdariffa L. flowers
Anthocyanins
Heat and ultrasound assisted extractions
Response surface methodology
datacite.titles.title.fl_str_mv Optimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowers
dc.contributor.none.fl_str_mv Biblioteca Digital do IPB
dc.creator.none.fl_str_mv Jabeur, Inès
Pereira, Eliana
Prieto Lage, Miguel A.
Antonio, Amilcar L.
Barros, Lillian
Ferreira, Isabel C.F.R.
dc.date.Accepted.fl_str_mv 2018-01-01T00:00:00Z
dc.date.available.fl_str_mv 2018-10-17T15:37:03Z
dc.date.embargoed.fl_str_mv 2018-10-17T15:37:03Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv http://hdl.handle.net/10198/18088
dc.language.none.fl_str_mv eng
dc.rights.cclincense.fl_str_mv http://creativecommons.org/licenses/by/4.0/
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.subject.none.fl_str_mv Hibiscus sabdariffa L. flowers
Anthocyanins
Heat and ultrasound assisted extractions
Response surface methodology
dc.title.fl_str_mv Optimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowers
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_c94f
description Hibiscus sabdariffa L. is an herbaceous medicinal plantused as infusion for the treatment of several disorders, namely, fever and high blood pressure, gastrointestinal and hepatic diseases. In addition to those health benefits, the calyces area potential source of natural pigments, due to its high content in anthocyanins. This work aimed to optimize the experimental conditions of anthocyanins’extraction from dried calyces of H. sabdariffa, comparing two methodologies, maceration and ultrasound assisted extraction, in order to develop a natural colorant. To obtain the conditions that maximize anthocyanins’ extraction, a response surface methodology (RSM) was applied using the circumscribed central composite design of three variables with five levels. Time, temperature and ethanol - water proportion - in the case of maceration, were the relevant independent variables, while for ultrasound assisted extraction, the ultrasonic power was used instead of temperature which was kept constant. Two anthocyanin compounds were identified by HPLC-DAD-ESI/MS: delphinidin3-sambubioside and cyanidin-3-sambubioside. The responses used as criteria were the quantification of the identified anthocyanins and the extraction yield of the final residue. Ultrasound assisted extraction proved to be the most effective method: 43 min, 390 W and 46 % of ethanol. At these optimal conditions, the extraction yield was 61.2%, with a total anthocyanins’ content of 23.1 mg/g dried plant, and 47.5 mg/g extract. Additionally, the response values were slightly improved by studying the solid/liquid ratio effect using the optimal conditions in dose-response format (5 to 200 g/L), showing continuously decreasing values as the solid/liquid ratio increases. Overall, the obtained results showed the possibility of using H. sabdariffa flowers as a source of anthocyanin compounds for industrial applications.
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person_str_mv Jabeur, Inès
Jabeur, Inès
http://orcid.org/0000-0002-7485-3554
0000-0002-7485-3554
Pereira, Eliana
Pereira, Eliana
https://www.ciencia-id.pt/BE17-462D-9A75
BE17-462D-9A75
http://orcid.org/0000-0003-2854-6745
0000-0003-2854-6745
Prieto Lage, Miguel A.
Prieto Lage, Miguel A.
https://www.ciencia-id.pt/221E-1E00-AB74
221E-1E00-AB74
http://orcid.org/0000-0002-3513-0054
0000-0002-3513-0054
Antonio, Amilcar L.
Antonio, Amilcar L.
https://www.ciencia-id.pt/1014-5259-DE86
1014-5259-DE86
http://orcid.org/0000-0001-8271-9964
0000-0001-8271-9964
Barros, Lillian
Barros, Lillian
https://www.ciencia-id.pt/9616-35CB-D001
9616-35CB-D001
http://orcid.org/0000-0002-9050-5189
0000-0002-9050-5189
Ferreira, Isabel C.F.R.
Ferreira, Isabel C.F.R.
https://www.ciencia-id.pt/9418-CF95-9919
9418-CF95-9919
http://orcid.org/0000-0003-4910-4882
0000-0003-4910-4882
publishDate 2018
reponame_str Biblioteca Digital do IPB
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spelling engpt_PTHibiscus sabdariffa L. is an herbaceous medicinal plantused as infusion for the treatment of several disorders, namely, fever and high blood pressure, gastrointestinal and hepatic diseases. In addition to those health benefits, the calyces area potential source of natural pigments, due to its high content in anthocyanins. This work aimed to optimize the experimental conditions of anthocyanins’extraction from dried calyces of H. sabdariffa, comparing two methodologies, maceration and ultrasound assisted extraction, in order to develop a natural colorant. To obtain the conditions that maximize anthocyanins’ extraction, a response surface methodology (RSM) was applied using the circumscribed central composite design of three variables with five levels. Time, temperature and ethanol - water proportion - in the case of maceration, were the relevant independent variables, while for ultrasound assisted extraction, the ultrasonic power was used instead of temperature which was kept constant. Two anthocyanin compounds were identified by HPLC-DAD-ESI/MS: delphinidin3-sambubioside and cyanidin-3-sambubioside. The responses used as criteria were the quantification of the identified anthocyanins and the extraction yield of the final residue. Ultrasound assisted extraction proved to be the most effective method: 43 min, 390 W and 46 % of ethanol. At these optimal conditions, the extraction yield was 61.2%, with a total anthocyanins’ content of 23.1 mg/g dried plant, and 47.5 mg/g extract. Additionally, the response values were slightly improved by studying the solid/liquid ratio effect using the optimal conditions in dose-response format (5 to 200 g/L), showing continuously decreasing values as the solid/liquid ratio increases. Overall, the obtained results showed the possibility of using H. sabdariffa flowers as a source of anthocyanin compounds for industrial applications.application/pdfpt_PTOptimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowersPersonalJabeur, InèsDSpacehttp://dspace.org/items/f3e4dc3b-31d6-4c54-9161-7236ea5c8dceDSpacehttp://dspace.org/items/f3e4dc3b-31d6-4c54-9161-7236ea5c8dceJabeurInèsORCIDhttp://orcid.org0000-0002-7485-3554PersonalPereira, ElianaDSpacehttp://dspace.org/items/dda60cdc-0a2a-4c10-863e-eaef1e6f1fb9DSpacehttp://dspace.org/items/dda60cdc-0a2a-4c10-863e-eaef1e6f1fb9PereiraElianaCiência IDhttps://www.ciencia-id.ptBE17-462D-9A75ORCIDhttp://orcid.org0000-0003-2854-6745Researcher IDhttps://www.researcherid.comQ-8017-2018Scopus Author IDhttps://www.scopus.com55938912300PersonalPrieto Lage, Miguel A.DSpacehttp://dspace.org/items/13260615-fd28-4b8b-9dd4-8a8466007579DSpacehttp://dspace.org/items/13260615-fd28-4b8b-9dd4-8a8466007579PrietoMiguel A.Ciência IDhttps://www.ciencia-id.pt221E-1E00-AB74ORCIDhttp://orcid.org0000-0002-3513-0054Researcher IDhttps://www.researcherid.comG-4516-2011Scopus Author IDhttps://www.scopus.com35937495700Scopus Author IDhttps://www.scopus.com57207755963PersonalAntonio, Amilcar L.DSpacehttp://dspace.org/items/4b23e496-8d11-4ff5-a8ec-e1c2235e5a28DSpacehttp://dspace.org/items/4b23e496-8d11-4ff5-a8ec-e1c2235e5a28AntonioAmilcar L.Ciência IDhttps://www.ciencia-id.pt1014-5259-DE86ORCIDhttp://orcid.org0000-0001-8271-9964Researcher IDhttps://www.researcherid.comJ-1960-2014Scopus Author IDhttps://www.scopus.com44560921900PersonalBarros, LillianDSpacehttp://dspace.org/items/3af07ffe-f914-48ba-a5d5-efcf70fdce01DSpacehttp://dspace.org/items/3af07ffe-f914-48ba-a5d5-efcf70fdce01BarrosLillianCiência IDhttps://www.ciencia-id.pt9616-35CB-D001ORCIDhttp://orcid.org0000-0002-9050-5189Researcher IDhttps://www.researcherid.comJ-3600-2013Researcher IDhttps://www.researcherid.comJ-3600-2013Scopus Author IDhttps://www.scopus.com35236343600Scopus Author IDhttps://www.scopus.com57194900801PersonalFerreira, Isabel C.F.R.DSpacehttp://dspace.org/items/bd0d1537-2e03-41fb-b27a-140af9c35db8DSpacehttp://dspace.org/items/bd0d1537-2e03-41fb-b27a-140af9c35db8FerreiraIsabel C.F.R.Ciência IDhttps://www.ciencia-id.pt9418-CF95-9919ORCIDhttp://orcid.org0000-0003-4910-4882Researcher IDhttps://www.researcherid.comE-8500-2013Scopus Author IDhttps://www.scopus.com36868826600HostingInstitutionOrganizationalBiblioteca Digital do IPBe-mailmailto:dspace@ipb.ptdspace@ipb.ptISBNIsPartOf978-99976-718-5-12018-10-17T15:37:03Z20182018-01-01T00:00:00ZHandlehttp://hdl.handle.net/10198/18088http://purl.org/coar/access_right/c_abf2open accessHibiscus sabdariffa L. flowersAnthocyaninsHeat and ultrasound assisted extractionsResponse surface methodology933653 bytesother research producthttp://purl.org/coar/resource_type/c_c94fconference object2018http://creativecommons.org/licenses/by/4.0/http://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://bibliotecadigital.ipb.pt/bitstreams/829e583e-fa5f-4ee7-b0f0-4dfd298926e3/downloadIX International Scientific Agriculture Symposium “AGROSYM 2018”11771177Bósnia-Herzegovina
spellingShingle Optimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowers
Jabeur, Inès
Hibiscus sabdariffa L. flowers
Anthocyanins
Heat and ultrasound assisted extractions
Response surface methodology
status SINGLETON
subject.fl_str_mv Hibiscus sabdariffa L. flowers
Anthocyanins
Heat and ultrasound assisted extractions
Response surface methodology
title Optimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowers
title_full Optimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowers
title_fullStr Optimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowers
title_full_unstemmed Optimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowers
title_short Optimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowers
title_sort Optimization and comparison of maceration and ultrassound assisted extraction systems for the production of a colorant extract from Hibiscus sabdariffa L. flowers
topic Hibiscus sabdariffa L. flowers
Anthocyanins
Heat and ultrasound assisted extractions
Response surface methodology
topic_facet Hibiscus sabdariffa L. flowers
Anthocyanins
Heat and ultrasound assisted extractions
Response surface methodology
url http://hdl.handle.net/10198/18088
visible 1