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Uranium spatio-temporal variability in groundwater : an environmental risk assessment case study

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Resumo:Uranium in the environment results from natural geochemical processes and human actions. The discharges of uranium and associated radionuclides as well as metals and metalloids from waste and tailing dumps in uranium mining areas and processing sites expose the target area to risk of contamination, concerning surface and groundwater. Uranium is one of the most widespread contaminant in mining areas. Uranium and associated trace elements spatial distribution patterns, in groundwater, within the transboundary watershed of the Águeda River (Portugal-Spain) is the main purpose of the herein work. Uranium minerals and associated sulphides occur distributed along the all area and are a potential source of contamination. These mineral resources were exploited in the past and were abandoned without any monitoring or remediation processes. Seventy-five groundwater samples were selected, georeferenced and collected during June of 2012. Each water point was analysed each water point were analysed “in situ” parameters such as: temperature, pH, electrical conductivity, Eh, dissolved oxygen. Trace elements contents such as uranium, were determined by inductively coupled plasma coupled mass (ICP-MS). Groundwater’s Uranium distribution was obtained thorough a spatial statistics approach were simulated scenario, for Uranium spatial distribution (Sequential Gaussian Simulation) were discussed and considering the average map and the associated spatial uncertainty, for each was determined the standard deviation of a hundred simulations. In a second step Local G clustering was performed in order to obtain Uranium’s hot-spots distribution. Uranium hot spots are located preferentially in the central area of the Águeda watershed and clearly associated with the proximity to the mineralization and overlapping the old mine site. In the northern and southern regions it is possible to identify clusters of moderate to high Uranium contents. High spatial uncertainty of associated though, which indicates the need of future detailed monitoring. The obtained results demonstrate that the old U-mining activities are nevertheless a serious environmental risk factor in the survey region. Finally, intrinsic vulnerability of groundwater was assessed by the calculation of the DRASTIC index. The results allow the identification of the areas with higher risk of contamination and works as a tool for the definition of effective groundwater systems’ management and exploitation policies.
Autores principais:Albuquerque, M.T.D.
Outros Autores:Antunes, I.M.H.R.
Assunto:Uranium mines Groundwater Sequential Gaussian Simulation Spatial uncertainty Local G clustering DRASTIC Risk maps
Ano:2015
País:Portugal
Tipo de documento:capítulo de livro
Tipo de acesso:acesso aberto
Instituição associada:Instituto Politécnico de Castelo Branco
Idioma:inglês
Origem:Repositório Científico do Instituto Politécnico de Castelo Branco
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author Albuquerque, M.T.D.
author2 Antunes, I.M.H.R.
author2_role author
author_facet Albuquerque, M.T.D.
Antunes, I.M.H.R.
author_role author
contributor_name_str_mv Repositório Científico do Instituto Politécnico de Castelo Branco
country_str PT
creators_json_txt [{\"Person.name\":\"Albuquerque, M.T.D.\",\"Person.identifier.orcid\":\"0000-0002-8782-6133\"},{\"Person.name\":\"Antunes, I.M.H.R.\",\"Person.identifier.orcid\":\"0000-0003-3456-5926\"}]
datacite.contributors.contributor.contributorName.fl_str_mv Repositório Científico do Instituto Politécnico de Castelo Branco
datacite.creators.creator.creatorName.fl_str_mv Albuquerque, M.T.D.
Antunes, I.M.H.R.
datacite.date.Accepted.fl_str_mv 2015-01-01T00:00:00Z
datacite.date.available.fl_str_mv 2015-11-16T13:46:49Z
datacite.date.embargoed.fl_str_mv 2015-11-16T13:46:49Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv Uranium mines
Groundwater
Sequential Gaussian Simulation
Spatial uncertainty
Local G clustering
DRASTIC
Risk maps
datacite.titles.title.fl_str_mv Uranium spatio-temporal variability in groundwater : an environmental risk assessment case study
dc.contributor.none.fl_str_mv Repositório Científico do Instituto Politécnico de Castelo Branco
dc.creator.none.fl_str_mv Albuquerque, M.T.D.
Antunes, I.M.H.R.
dc.date.Accepted.fl_str_mv 2015-01-01T00:00:00Z
dc.date.available.fl_str_mv 2015-11-16T13:46:49Z
dc.date.embargoed.fl_str_mv 2015-11-16T13:46:49Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv http://hdl.handle.net/10400.11/3068
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv NOVA
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.subject.none.fl_str_mv Uranium mines
Groundwater
Sequential Gaussian Simulation
Spatial uncertainty
Local G clustering
DRASTIC
Risk maps
dc.title.fl_str_mv Uranium spatio-temporal variability in groundwater : an environmental risk assessment case study
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_3248
description Uranium in the environment results from natural geochemical processes and human actions. The discharges of uranium and associated radionuclides as well as metals and metalloids from waste and tailing dumps in uranium mining areas and processing sites expose the target area to risk of contamination, concerning surface and groundwater. Uranium is one of the most widespread contaminant in mining areas. Uranium and associated trace elements spatial distribution patterns, in groundwater, within the transboundary watershed of the Águeda River (Portugal-Spain) is the main purpose of the herein work. Uranium minerals and associated sulphides occur distributed along the all area and are a potential source of contamination. These mineral resources were exploited in the past and were abandoned without any monitoring or remediation processes. Seventy-five groundwater samples were selected, georeferenced and collected during June of 2012. Each water point was analysed each water point were analysed “in situ” parameters such as: temperature, pH, electrical conductivity, Eh, dissolved oxygen. Trace elements contents such as uranium, were determined by inductively coupled plasma coupled mass (ICP-MS). Groundwater’s Uranium distribution was obtained thorough a spatial statistics approach were simulated scenario, for Uranium spatial distribution (Sequential Gaussian Simulation) were discussed and considering the average map and the associated spatial uncertainty, for each was determined the standard deviation of a hundred simulations. In a second step Local G clustering was performed in order to obtain Uranium’s hot-spots distribution. Uranium hot spots are located preferentially in the central area of the Águeda watershed and clearly associated with the proximity to the mineralization and overlapping the old mine site. In the northern and southern regions it is possible to identify clusters of moderate to high Uranium contents. High spatial uncertainty of associated though, which indicates the need of future detailed monitoring. The obtained results demonstrate that the old U-mining activities are nevertheless a serious environmental risk factor in the survey region. Finally, intrinsic vulnerability of groundwater was assessed by the calculation of the DRASTIC index. The results allow the identification of the areas with higher risk of contamination and works as a tool for the definition of effective groundwater systems’ management and exploitation policies.
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organization_str_mv urn:organizationAcronym:ipcb
person_str_mv Albuquerque, M.T.D.
Albuquerque, M.T.D.
https://www.ciencia-id.pt/5A1C-8956-4C0A
5A1C-8956-4C0A
http://orcid.org/0000-0002-8782-6133
0000-0002-8782-6133
Antunes, I.M.H.R.
Antunes, I.M.H.R.
https://www.ciencia-id.pt/CB1E-FAD2-37D6
CB1E-FAD2-37D6
http://orcid.org/0000-0003-3456-5926
0000-0003-3456-5926
publishDate 2015
publisher.none.fl_str_mv NOVA
reponame_str Repositório Científico do Instituto Politécnico de Castelo Branco
repository_id_str urn:repositoryAcronym:ripcb
service_str_mv urn:repositoryAcronym:ripcb
spelling engNOVApt_PTUranium in the environment results from natural geochemical processes and human actions. The discharges of uranium and associated radionuclides as well as metals and metalloids from waste and tailing dumps in uranium mining areas and processing sites expose the target area to risk of contamination, concerning surface and groundwater. Uranium is one of the most widespread contaminant in mining areas. Uranium and associated trace elements spatial distribution patterns, in groundwater, within the transboundary watershed of the Águeda River (Portugal-Spain) is the main purpose of the herein work. Uranium minerals and associated sulphides occur distributed along the all area and are a potential source of contamination. These mineral resources were exploited in the past and were abandoned without any monitoring or remediation processes. Seventy-five groundwater samples were selected, georeferenced and collected during June of 2012. Each water point was analysed each water point were analysed “in situ” parameters such as: temperature, pH, electrical conductivity, Eh, dissolved oxygen. Trace elements contents such as uranium, were determined by inductively coupled plasma coupled mass (ICP-MS). Groundwater’s Uranium distribution was obtained thorough a spatial statistics approach were simulated scenario, for Uranium spatial distribution (Sequential Gaussian Simulation) were discussed and considering the average map and the associated spatial uncertainty, for each was determined the standard deviation of a hundred simulations. In a second step Local G clustering was performed in order to obtain Uranium’s hot-spots distribution. Uranium hot spots are located preferentially in the central area of the Águeda watershed and clearly associated with the proximity to the mineralization and overlapping the old mine site. In the northern and southern regions it is possible to identify clusters of moderate to high Uranium contents. High spatial uncertainty of associated though, which indicates the need of future detailed monitoring. The obtained results demonstrate that the old U-mining activities are nevertheless a serious environmental risk factor in the survey region. Finally, intrinsic vulnerability of groundwater was assessed by the calculation of the DRASTIC index. The results allow the identification of the areas with higher risk of contamination and works as a tool for the definition of effective groundwater systems’ management and exploitation policies.application/pdfpt_PTUranium spatio-temporal variability in groundwater : an environmental risk assessment case studyPersonalAlbuquerque, M.T.D.DSpacehttp://dspace.org/items/e2c2d171-e148-4c23-9cf8-0eb6d810c15eDSpacehttp://dspace.org/items/e2c2d171-e148-4c23-9cf8-0eb6d810c15eAlbuquerqueMaria TeresaCiência IDhttps://www.ciencia-id.pt5A1C-8956-4C0AORCIDhttp://orcid.org0000-0002-8782-6133Researcher IDhttps://www.researcherid.comB-1536-2013Scopus Author IDhttps://www.scopus.com55507421600PersonalAntunes, I.M.H.R.DSpacehttp://dspace.org/items/1db83c95-f80c-41bb-b5c6-437ab32d9683DSpacehttp://dspace.org/items/1db83c95-f80c-41bb-b5c6-437ab32d9683antunesIsabel MargaridaCiência IDhttps://www.ciencia-id.ptCB1E-FAD2-37D6ORCIDhttp://orcid.org0000-0003-3456-5926Researcher IDhttps://www.researcherid.comM-1043-2013Scopus Author IDhttps://www.scopus.com6701817085HostingInstitutionOrganizationalRepositório Científico do Instituto Politécnico de Castelo Brancoe-mailmailto:repositorio@ipcb.ptrepositorio@ipcb.ptISBNIsPartOf978-1- 63482-866-62015-11-16T13:46:49Z20152015-01-01T00:00:00ZHandlehttp://hdl.handle.net/10400.11/3068http://purl.org/coar/access_right/c_abf2open accessUranium minesGroundwaterSequential Gaussian SimulationSpatial uncertaintyLocal G clusteringDRASTICRisk maps181997 bytesliteraturehttp://purl.org/coar/resource_type/c_3248book parthttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://repositorio.ipcb.pt/bitstreams/e5371e28-0b16-40c4-833e-987042f85770/downloadUranium : sources, exposure and environmental effects145157New York
spellingShingle Uranium spatio-temporal variability in groundwater : an environmental risk assessment case study
Albuquerque, M.T.D.
Uranium mines
Groundwater
Sequential Gaussian Simulation
Spatial uncertainty
Local G clustering
DRASTIC
Risk maps
status SINGLETON
subject.fl_str_mv Uranium mines
Groundwater
Sequential Gaussian Simulation
Spatial uncertainty
Local G clustering
DRASTIC
Risk maps
title Uranium spatio-temporal variability in groundwater : an environmental risk assessment case study
title_full Uranium spatio-temporal variability in groundwater : an environmental risk assessment case study
title_fullStr Uranium spatio-temporal variability in groundwater : an environmental risk assessment case study
title_full_unstemmed Uranium spatio-temporal variability in groundwater : an environmental risk assessment case study
title_short Uranium spatio-temporal variability in groundwater : an environmental risk assessment case study
title_sort Uranium spatio-temporal variability in groundwater : an environmental risk assessment case study
topic Uranium mines
Groundwater
Sequential Gaussian Simulation
Spatial uncertainty
Local G clustering
DRASTIC
Risk maps
topic_facet Uranium mines
Groundwater
Sequential Gaussian Simulation
Spatial uncertainty
Local G clustering
DRASTIC
Risk maps
url http://hdl.handle.net/10400.11/3068
visible 1