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Effect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extruders

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Resumo:This work investigates the effect of the operating conditions (set temperature and prescribed throughput) on the evolution of the MA grafted content on high density polyethylene along a co-rotating twin screw extruder. Samples were quickly removed from the extruder at relevant axial locations, quenched and subsequently characterized off-line. While grafting was monitored by FTIR, the residual peroxide was determined by gas chromatography. The results show a good correlation between residual peroxide and MA grafted content.
Autores principais:Machado, A. V.
Outros Autores:Covas, J. A.
Assunto:Polyethylene Grafting modification maleic anhydride
Ano:2004
País:Portugal
Tipo de documento:comunicação em conferência
Tipo de acesso:acesso restrito
Instituição associada:Universidade do Minho
Idioma:inglês
Origem:RepositóriUM - Universidade do Minho
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author Machado, A. V.
author2 Covas, J. A.
author2_role author
author_facet Machado, A. V.
Covas, J. A.
author_role author
contributor_name_str_mv Universidade do Minho
country_str PT
creators_json_txt [{\"Person.name\":\"Machado, A. V.\"},{\"Person.name\":\"Covas, J. A.\"}]
datacite.contributors.contributor.contributorName.fl_str_mv Universidade do Minho
datacite.creators.creator.creatorName.fl_str_mv Machado, A. V.
Covas, J. A.
datacite.date.Accepted.fl_str_mv 2004-01-01T00:00:00Z
datacite.date.available.fl_str_mv 2012-04-24T16:01:24Z
datacite.date.embargoed.fl_str_mv 2012-04-24T16:01:24Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_16ec
datacite.subjects.subject.fl_str_mv Polyethylene
Grafting
modification
maleic anhydride
datacite.titles.title.fl_str_mv Effect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extruders
dc.contributor.none.fl_str_mv Universidade do Minho
dc.creator.none.fl_str_mv Machado, A. V.
Covas, J. A.
dc.date.Accepted.fl_str_mv 2004-01-01T00:00:00Z
dc.date.available.fl_str_mv 2012-04-24T16:01:24Z
dc.date.embargoed.fl_str_mv 2012-04-24T16:01:24Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv https://hdl.handle.net/1822/18884
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Trans Tech Publications
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_16ec
dc.subject.none.fl_str_mv Polyethylene
Grafting
modification
maleic anhydride
dc.title.fl_str_mv Effect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extruders
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_5794
description This work investigates the effect of the operating conditions (set temperature and prescribed throughput) on the evolution of the MA grafted content on high density polyethylene along a co-rotating twin screw extruder. Samples were quickly removed from the extruder at relevant axial locations, quenched and subsequently characterized off-line. While grafting was monitored by FTIR, the residual peroxide was determined by gas chromatography. The results show a good correlation between residual peroxide and MA grafted content.
dirty 0
eu_rights_str_mv restrictedAccess
format conferencePaper
fulltext.url.fl_str_mv https://prod-dspace.uminho.pt/bitstreams/73ac3639-b3fe-43b7-968d-12bb6fd94b26/download
id rum_15d97b9bf063b122fcdbb5c2d4df2c8a
identifier.url.fl_str_mv https://hdl.handle.net/1822/18884
instacron_str repositorium
institution Universidade do Minho
instname_str Universidade do Minho
language eng
network_acronym_str rum
network_name_str RepositóriUM - Universidade do Minho
oai_identifier_str oai:repositorium.uminho.pt:1822/18884
organization_str_mv urn:organizationAcronym:repositorium
person_str_mv Machado, A. V.
Covas, J. A.
publishDate 2004
publisher.none.fl_str_mv Trans Tech Publications
reponame_str RepositóriUM - Universidade do Minho
repository_id_str urn:repositoryAcronym:rum
service_str_mv urn:repositoryAcronym:rum
spelling engTrans Tech PublicationsporThis work investigates the effect of the operating conditions (set temperature and prescribed throughput) on the evolution of the MA grafted content on high density polyethylene along a co-rotating twin screw extruder. Samples were quickly removed from the extruder at relevant axial locations, quenched and subsequently characterized off-line. While grafting was monitored by FTIR, the residual peroxide was determined by gas chromatography. The results show a good correlation between residual peroxide and MA grafted content.application/pdfporEffect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extrudersMachado, A. V.Covas, J. A.HostingInstitutionOrganizationalUniversidade do Minhoe-mailmailto:repositorium@usdb.uminho.ptrepositorium@usdb.uminho.ptISBNIsPartOf0878499415ISSNIsPartOf0255-5476DOIIsPartOf10.4028/www.scientific.net/msf.455-456.4802012-04-24T16:01:24Z20042004-01-01T00:00:00ZHandlehttps://hdl.handle.net/1822/18884http://purl.org/coar/access_right/c_16ecrestricted accessPolyethyleneGraftingmodificationmaleic anhydride161106 bytesother research producthttp://purl.org/coar/resource_type/c_5794conference paperhttp://purl.org/coar/access_right/c_16ecapplication/pdffulltexthttps://prod-dspace.uminho.pt/bitstreams/73ac3639-b3fe-43b7-968d-12bb6fd94b26/download
spellingShingle Effect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extruders
Machado, A. V.
Polyethylene
Grafting
modification
maleic anhydride
status SINGLETON
subject.fl_str_mv Polyethylene
Grafting
modification
maleic anhydride
title Effect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extruders
title_full Effect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extruders
title_fullStr Effect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extruders
title_full_unstemmed Effect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extruders
title_short Effect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extruders
title_sort Effect of experimental conditions on the grafting of maleic anhydride onto polyethylene in extruders
topic Polyethylene
Grafting
modification
maleic anhydride
topic_facet Polyethylene
Grafting
modification
maleic anhydride
url https://hdl.handle.net/1822/18884
visible 1