Publicação
Greener solvent-based processing of magnetoelectric nanocomposites
| Resumo: | Polymer-based magnetoelectric (ME) nanocomposites are an enabling material technology for a wide range of applications in the area of digitalization strategies. Due to its highest piezoelectric response among polymers, poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE) is the piezoelectric matrix most used in polymer-based ME materials with over 80% of the total reports, with the resulting composites typically processed from solutions with N,N-dimethylformamide (DMF), a toxic solvent. Nevertheless, environmentally friendlier approaches and sustainable technologies are increasingly being required. This work demonstrates that P(VDF-TrFE)/Co2Fe2O4 nanocomposites can be successfully prepared from solution using three different environmentally friendlier solvents: dimethyl sulfoxide (DMSO), N,N′-dimethylpropyleneurea (DMPU), and triethyl phosphate (TEP) with different dipole moments. It is shown that the prepared composite films, with a maximum ME voltage coefficient of 35 mV cm–1 Oe–1 and a maximum sensitivity of 2.2 mV T–1, are suitable for applications, highlighting the path for a new generation of more sustainable ME sensors. |
|---|---|
| Autores principais: | Lima, A. C. |
| Outros Autores: | Pereira, N.; Ribeiro, Clarisse Marta Oliveira; Lanceros-Méndez, S.; Martins, Pedro Libânio Abreu |
| Assunto: | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| Ano: | 2022 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso restrito |
| Instituição associada: | Universidade do Minho |
| Idioma: | inglês |
| Origem: | RepositóriUM - Universidade do Minho |
| _version_ | 1866875834393952256 |
|---|---|
| author | Lima, A. C. |
| author2 | Pereira, N. Ribeiro, Clarisse Marta Oliveira Lanceros-Méndez, S. Martins, Pedro Libânio Abreu |
| author2_role | author author author author |
| author_facet | Lima, A. C. Pereira, N. Ribeiro, Clarisse Marta Oliveira Lanceros-Méndez, S. Martins, Pedro Libânio Abreu |
| author_role | author |
| contributor_name_str_mv | Universidade do Minho |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Lima, A. C.\"},{\"Person.name\":\"Pereira, N.\"},{\"Person.name\":\"Ribeiro, Clarisse Marta Oliveira\"},{\"Person.name\":\"Lanceros-Méndez, S.\"},{\"Person.name\":\"Martins, Pedro Libânio Abreu\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | Universidade do Minho |
| datacite.creators.creator.creatorName.fl_str_mv | Lima, A. C. Pereira, N. Ribeiro, Clarisse Marta Oliveira Lanceros-Méndez, S. Martins, Pedro Libânio Abreu |
| datacite.date.Accepted.fl_str_mv | 2022-04-04T00:00:00Z |
| datacite.date.embargoed.fl_str_mv | 10000-01-01T00:00:00Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_16ec |
| datacite.subjects.subject.fl_str_mv | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| datacite.titles.title.fl_str_mv | Greener solvent-based processing of magnetoelectric nanocomposites |
| dc.contributor.none.fl_str_mv | Universidade do Minho |
| dc.creator.none.fl_str_mv | Lima, A. C. Pereira, N. Ribeiro, Clarisse Marta Oliveira Lanceros-Méndez, S. Martins, Pedro Libânio Abreu |
| dc.date.Accepted.fl_str_mv | 2022-04-04T00:00:00Z |
| dc.date.embargoed.fl_str_mv | 10000-01-01T00:00:00Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | https://hdl.handle.net/1822/77024 |
| dc.language.none.fl_str_mv | eng |
| dc.publisher.none.fl_str_mv | American Chemical Society |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_16ec |
| dc.subject.none.fl_str_mv | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| dc.title.fl_str_mv | Greener solvent-based processing of magnetoelectric nanocomposites |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Polymer-based magnetoelectric (ME) nanocomposites are an enabling material technology for a wide range of applications in the area of digitalization strategies. Due to its highest piezoelectric response among polymers, poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE) is the piezoelectric matrix most used in polymer-based ME materials with over 80% of the total reports, with the resulting composites typically processed from solutions with N,N-dimethylformamide (DMF), a toxic solvent. Nevertheless, environmentally friendlier approaches and sustainable technologies are increasingly being required. This work demonstrates that P(VDF-TrFE)/Co2Fe2O4 nanocomposites can be successfully prepared from solution using three different environmentally friendlier solvents: dimethyl sulfoxide (DMSO), N,N′-dimethylpropyleneurea (DMPU), and triethyl phosphate (TEP) with different dipole moments. It is shown that the prepared composite films, with a maximum ME voltage coefficient of 35 mV cm–1 Oe–1 and a maximum sensitivity of 2.2 mV T–1, are suitable for applications, highlighting the path for a new generation of more sustainable ME sensors. |
| dirty | 0 |
| eu_rights_str_mv | restrictedAccess |
| format | article |
| fulltext.url.fl_str_mv | https://prod-dspace.uminho.pt/bitstreams/a0c1e440-82c8-4290-9776-f200636b1c7e/download |
| id | rum_2af0af9aa657e5debd3d12e39bcd3525 |
| identifier.url.fl_str_mv | https://hdl.handle.net/1822/77024 |
| instacron_str | repositorium |
| institution | Universidade do Minho |
| instname_str | Universidade do Minho |
| language | eng |
| network_acronym_str | rum |
| network_name_str | RepositóriUM - Universidade do Minho |
| oai_identifier_str | oai:repositorium.uminho.pt:1822/77024 |
| organization_str_mv | urn:organizationAcronym:repositorium |
| person_str_mv | Lima, A. C. Pereira, N. Ribeiro, Clarisse Marta Oliveira Lanceros-Méndez, S. Martins, Pedro Libânio Abreu |
| publishDate | 2022 |
| publisher.none.fl_str_mv | American Chemical Society |
| reponame_str | RepositóriUM - Universidade do Minho |
| repository_id_str | urn:repositoryAcronym:rum |
| service_str_mv | urn:repositoryAcronym:rum |
| spelling | engAmerican Chemical SocietyporPolymer-based magnetoelectric (ME) nanocomposites are an enabling material technology for a wide range of applications in the area of digitalization strategies. Due to its highest piezoelectric response among polymers, poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE) is the piezoelectric matrix most used in polymer-based ME materials with over 80% of the total reports, with the resulting composites typically processed from solutions with N,N-dimethylformamide (DMF), a toxic solvent. Nevertheless, environmentally friendlier approaches and sustainable technologies are increasingly being required. This work demonstrates that P(VDF-TrFE)/Co2Fe2O4 nanocomposites can be successfully prepared from solution using three different environmentally friendlier solvents: dimethyl sulfoxide (DMSO), N,N′-dimethylpropyleneurea (DMPU), and triethyl phosphate (TEP) with different dipole moments. It is shown that the prepared composite films, with a maximum ME voltage coefficient of 35 mV cm–1 Oe–1 and a maximum sensitivity of 2.2 mV T–1, are suitable for applications, highlighting the path for a new generation of more sustainable ME sensors.application/pdfporGreener solvent-based processing of magnetoelectric nanocompositesLima, A. C.Pereira, N.Ribeiro, Clarisse Marta OliveiraLanceros-Méndez, S.Martins, Pedro Libânio AbreuHostingInstitutionOrganizationalUniversidade do Minhoe-mailmailto:repositorium@usdb.uminho.ptrepositorium@usdb.uminho.ptISSNIsPartOf2168-0485DOIIsPartOf10.1021/acssuschemeng.1c069672022-04-042022-04-07T21:45:24Z10000-01-01T00:00:00Z2022-04-04T00:00:00ZHandlehttps://hdl.handle.net/1822/77024http://purl.org/coar/access_right/c_16ecrestricted accessCompositesPiezoelectricsNanoparticlesSolventsPolaritygreen manufacturing and engineeringnanoscience and nanotechnologygreen solventssustainable materialsmagnetoelectric791225 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_f1cfapplication/pdffulltexthttps://prod-dspace.uminho.pt/bitstreams/a0c1e440-82c8-4290-9776-f200636b1c7e/download |
| spellingShingle | Greener solvent-based processing of magnetoelectric nanocomposites Lima, A. C. Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| status | SINGLETON |
| subject.fl_str_mv | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| title | Greener solvent-based processing of magnetoelectric nanocomposites |
| title_full | Greener solvent-based processing of magnetoelectric nanocomposites |
| title_fullStr | Greener solvent-based processing of magnetoelectric nanocomposites |
| title_full_unstemmed | Greener solvent-based processing of magnetoelectric nanocomposites |
| title_short | Greener solvent-based processing of magnetoelectric nanocomposites |
| title_sort | Greener solvent-based processing of magnetoelectric nanocomposites |
| topic | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| topic_facet | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| url | https://hdl.handle.net/1822/77024 |
| visible | 1 |