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Artificial and natural weathering of ABS

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Resumo:Acrylonitrile-butadiene-styrene (ABS) is a complex copolymer with exceptional importance in technological applications. However, ABS is known to present a high susceptibility to weathering when exposed to UV radiation in the presence of oxygen. In this work, photodegradation of ABS was studied under natural and accelerated conditions. Exposed samples were removed periodically and characterized by several analytical techniques. During both types of weathering chemical modifications occurs mainly at the surface, which affects considerable the optical, mechanical, and rheological properties. The results obtained evidence that during accelerated weathering the formation rate of photodegradation products is higher when compared to natural weathering results. However, chain scission occurs mainly along natural conditions.
Autores principais:Santos, R. M.
Outros Autores:Botelho, Gabriela; Machado, A. V.
Assunto:ABS Photodegradation Yellowness Mechanical properties
Ano:2010
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso restrito
Instituição associada:Universidade do Minho
Idioma:inglês
Origem:RepositóriUM - Universidade do Minho
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author Santos, R. M.
author2 Botelho, Gabriela
Machado, A. V.
author2_role author
author
author_facet Santos, R. M.
Botelho, Gabriela
Machado, A. V.
author_role author
contributor_name_str_mv Universidade do Minho
country_str PT
creators_json_txt [{\"Person.name\":\"Santos, R. M.\"},{\"Person.name\":\"Botelho, Gabriela\"},{\"Person.name\":\"Machado, A. V.\"}]
datacite.contributors.contributor.contributorName.fl_str_mv Universidade do Minho
datacite.creators.creator.creatorName.fl_str_mv Santos, R. M.
Botelho, Gabriela
Machado, A. V.
datacite.date.Accepted.fl_str_mv 2010-05-01T00:00:00Z
datacite.date.available.fl_str_mv 2011-08-02T15:27:25Z
datacite.date.embargoed.fl_str_mv 2011-08-02T15:27:25Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_16ec
datacite.subjects.subject.fl_str_mv ABS
Photodegradation
Yellowness
Mechanical properties
datacite.titles.title.fl_str_mv Artificial and natural weathering of ABS
dc.contributor.none.fl_str_mv Universidade do Minho
dc.creator.none.fl_str_mv Santos, R. M.
Botelho, Gabriela
Machado, A. V.
dc.date.Accepted.fl_str_mv 2010-05-01T00:00:00Z
dc.date.available.fl_str_mv 2011-08-02T15:27:25Z
dc.date.embargoed.fl_str_mv 2011-08-02T15:27:25Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv https://hdl.handle.net/1822/13260
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Wiley
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_16ec
dc.subject.none.fl_str_mv ABS
Photodegradation
Yellowness
Mechanical properties
dc.title.fl_str_mv Artificial and natural weathering of ABS
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description Acrylonitrile-butadiene-styrene (ABS) is a complex copolymer with exceptional importance in technological applications. However, ABS is known to present a high susceptibility to weathering when exposed to UV radiation in the presence of oxygen. In this work, photodegradation of ABS was studied under natural and accelerated conditions. Exposed samples were removed periodically and characterized by several analytical techniques. During both types of weathering chemical modifications occurs mainly at the surface, which affects considerable the optical, mechanical, and rheological properties. The results obtained evidence that during accelerated weathering the formation rate of photodegradation products is higher when compared to natural weathering results. However, chain scission occurs mainly along natural conditions.
dirty 0
eu_rights_str_mv restrictedAccess
format article
fulltext.url.fl_str_mv https://prod-dspace.uminho.pt/bitstreams/f22b7bd0-f200-4776-88bc-959d55ff55d7/download
id rum_87f1361fa614939d4b06d70abcda7f4b
identifier.url.fl_str_mv https://hdl.handle.net/1822/13260
instacron_str repositorium
institution Universidade do Minho
instname_str Universidade do Minho
language eng
network_acronym_str rum
network_name_str RepositóriUM - Universidade do Minho
oai_identifier_str oai:repositorium.uminho.pt:1822/13260
organization_str_mv urn:organizationAcronym:repositorium
person_str_mv Santos, R. M.
Botelho, Gabriela
Machado, A. V.
publishDate 2010
publisher.none.fl_str_mv Wiley
reponame_str RepositóriUM - Universidade do Minho
repository_id_str urn:repositoryAcronym:rum
service_str_mv urn:repositoryAcronym:rum
spelling engWileyporAcrylonitrile-butadiene-styrene (ABS) is a complex copolymer with exceptional importance in technological applications. However, ABS is known to present a high susceptibility to weathering when exposed to UV radiation in the presence of oxygen. In this work, photodegradation of ABS was studied under natural and accelerated conditions. Exposed samples were removed periodically and characterized by several analytical techniques. During both types of weathering chemical modifications occurs mainly at the surface, which affects considerable the optical, mechanical, and rheological properties. The results obtained evidence that during accelerated weathering the formation rate of photodegradation products is higher when compared to natural weathering results. However, chain scission occurs mainly along natural conditions.application/pdfporArtificial and natural weathering of ABSSantos, R. M.Botelho, GabrielaMachado, A. V.HostingInstitutionOrganizationalUniversidade do Minhoe-mailmailto:repositorium@usdb.uminho.ptrepositorium@usdb.uminho.ptISSNIsPartOf0021-8995ISSNIsPartOf1097-4628DOIIsPartOf10.1002/app.316632011-08-02T15:27:25Z2010-052010-05-01T00:00:00ZHandlehttps://hdl.handle.net/1822/13260http://purl.org/coar/access_right/c_16ecrestricted accessABSPhotodegradationYellownessMechanical properties743071 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_16ecapplication/pdffulltexthttps://prod-dspace.uminho.pt/bitstreams/f22b7bd0-f200-4776-88bc-959d55ff55d7/download
spellingShingle Artificial and natural weathering of ABS
Santos, R. M.
ABS
Photodegradation
Yellowness
Mechanical properties
status SINGLETON
subject.fl_str_mv ABS
Photodegradation
Yellowness
Mechanical properties
title Artificial and natural weathering of ABS
title_full Artificial and natural weathering of ABS
title_fullStr Artificial and natural weathering of ABS
title_full_unstemmed Artificial and natural weathering of ABS
title_short Artificial and natural weathering of ABS
title_sort Artificial and natural weathering of ABS
topic ABS
Photodegradation
Yellowness
Mechanical properties
topic_facet ABS
Photodegradation
Yellowness
Mechanical properties
url https://hdl.handle.net/1822/13260
visible 1