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Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties

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Resumo:The synthesis and the evaluation of solvatochromic and electrochemical properties of new donor-acceptor-substituted thienylpyrrole azo dyes 3 are described. These derivatives exhibit dramatic changes in both their electronic and redox properties in comparison with thienylpyrroles 1. In agreement with the solvatochromic and electrochemical studies of push-pull derivatives 3 the new compounds prepared, may find application in the manufacture of new materials with notable non-linear optical properties.
Autores principais:Raposo, M. Manuela M.
Outros Autores:Sousa, Ana M. R. C.; Fonseca, A. Maurício C.; Kirsch, G.
Assunto:Thiophene Pyrrole Donor-acceptor thienylpyrrole Azo dyes Heterocycles Synthesis Solvatochromism Electrochemistry Nonlinear optics (NLO) UV-visible spectroscopy donor-acceptor thienylpyrroles UV-vis spectroscopy chromophores
Ano:2005
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Universidade do Minho
Idioma:inglês
Origem:RepositóriUM - Universidade do Minho
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author Raposo, M. Manuela M.
author2 Sousa, Ana M. R. C.
Fonseca, A. Maurício C.
Kirsch, G.
author2_role author
author
author
author_facet Raposo, M. Manuela M.
Sousa, Ana M. R. C.
Fonseca, A. Maurício C.
Kirsch, G.
author_role author
contributor_name_str_mv RepositóriUM - Universidade do Minho
country_str PT
creators_json_txt [{\"Person.name\":\"Raposo, M. Manuela M.\"},{\"Person.name\":\"Sousa, Ana M. R. C.\"},{\"Person.name\":\"Fonseca, A. Maurício C.\"},{\"Person.name\":\"Kirsch, G.\"}]
datacite.contributors.contributor.contributorName.fl_str_mv RepositóriUM - Universidade do Minho
datacite.creators.creator.creatorName.fl_str_mv Raposo, M. Manuela M.
Sousa, Ana M. R. C.
Fonseca, A. Maurício C.
Kirsch, G.
datacite.date.Accepted.fl_str_mv 2005-01-01T00:00:00Z
datacite.date.available.fl_str_mv 2008-05-21T14:10:55Z
datacite.date.embargoed.fl_str_mv 2008-05-21T14:10:55Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv Thiophene
Pyrrole
Donor-acceptor thienylpyrrole
Azo dyes
Heterocycles
Synthesis
Solvatochromism
Electrochemistry
Nonlinear optics (NLO)
UV-visible spectroscopy
donor-acceptor thienylpyrroles
UV-vis spectroscopy
chromophores
datacite.titles.title.fl_str_mv Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties
dc.contributor.none.fl_str_mv RepositóriUM - Universidade do Minho
dc.creator.none.fl_str_mv Raposo, M. Manuela M.
Sousa, Ana M. R. C.
Fonseca, A. Maurício C.
Kirsch, G.
dc.date.Accepted.fl_str_mv 2005-01-01T00:00:00Z
dc.date.available.fl_str_mv 2008-05-21T14:10:55Z
dc.date.embargoed.fl_str_mv 2008-05-21T14:10:55Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv https://hdl.handle.net/1822/7838
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Elsevier
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.subject.none.fl_str_mv Thiophene
Pyrrole
Donor-acceptor thienylpyrrole
Azo dyes
Heterocycles
Synthesis
Solvatochromism
Electrochemistry
Nonlinear optics (NLO)
UV-visible spectroscopy
donor-acceptor thienylpyrroles
UV-vis spectroscopy
chromophores
dc.title.fl_str_mv Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description The synthesis and the evaluation of solvatochromic and electrochemical properties of new donor-acceptor-substituted thienylpyrrole azo dyes 3 are described. These derivatives exhibit dramatic changes in both their electronic and redox properties in comparison with thienylpyrroles 1. In agreement with the solvatochromic and electrochemical studies of push-pull derivatives 3 the new compounds prepared, may find application in the manufacture of new materials with notable non-linear optical properties.
dirty 0
eu_rights_str_mv openAccess
format article
fulltext.url.fl_str_mv https://repositorium.uminho.pt/bitstreams/cbea3f1d-862f-4187-b981-f5afbb310443/download
id rum_ccd920fa3008a3945f748fd2dddf2d27
identifier.url.fl_str_mv https://hdl.handle.net/1822/7838
instacron_str repositorium
institution Universidade do Minho
instname_str Universidade do Minho
language eng
network_acronym_str rum
network_name_str RepositóriUM - Universidade do Minho
oai_identifier_str oai:repositorium.uminho.pt:1822/7838
organization_str_mv urn:organizationAcronym:repositorium
person_str_mv Raposo, M. Manuela M.
Sousa, Ana M. R. C.
Fonseca, A. Maurício C.
Kirsch, G.
publishDate 2005
publisher.none.fl_str_mv Elsevier
reponame_str RepositóriUM - Universidade do Minho
repository_id_str urn:repositoryAcronym:rum
service_str_mv urn:repositoryAcronym:rum
spelling engElsevierengThe synthesis and the evaluation of solvatochromic and electrochemical properties of new donor-acceptor-substituted thienylpyrrole azo dyes 3 are described. These derivatives exhibit dramatic changes in both their electronic and redox properties in comparison with thienylpyrroles 1. In agreement with the solvatochromic and electrochemical studies of push-pull derivatives 3 the new compounds prepared, may find application in the manufacture of new materials with notable non-linear optical properties.application/pdfengThienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical propertiesRaposo, M. Manuela M.Sousa, Ana M. R. C.Fonseca, A. Maurício C.Kirsch, G.HostingInstitutionOrganizationalRepositóriUM - Universidade do Minhoe-mailmailto:repositorium@usdb.uminho.ptrepositorium@usdb.uminho.ptCITATION"Tetrahedron". ISSN 0040-4020. 61:34 (2005) 8249-8256.ISSNIsPartOf0040-4020DOIIsPartOf10.1016/j.tet.2005.06.0392008-05-21T14:10:55Z200520052005-01-01T00:00:00ZHandlehttps://hdl.handle.net/1822/7838http://purl.org/coar/access_right/c_abf2open accessThiophenePyrroleDonor-acceptor thienylpyrroleAzo dyesHeterocyclesSynthesisSolvatochromismElectrochemistryNonlinear optics (NLO)UV-visible spectroscopydonor-acceptor thienylpyrrolesUV-vis spectroscopychromophores141114 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://repositorium.uminho.pt/bitstreams/cbea3f1d-862f-4187-b981-f5afbb310443/download
spellingShingle Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties
Raposo, M. Manuela M.
Thiophene
Pyrrole
Donor-acceptor thienylpyrrole
Azo dyes
Heterocycles
Synthesis
Solvatochromism
Electrochemistry
Nonlinear optics (NLO)
UV-visible spectroscopy
donor-acceptor thienylpyrroles
UV-vis spectroscopy
chromophores
status SINGLETON
subject.fl_str_mv Thiophene
Pyrrole
Donor-acceptor thienylpyrrole
Azo dyes
Heterocycles
Synthesis
Solvatochromism
Electrochemistry
Nonlinear optics (NLO)
UV-visible spectroscopy
donor-acceptor thienylpyrroles
UV-vis spectroscopy
chromophores
title Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties
title_full Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties
title_fullStr Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties
title_full_unstemmed Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties
title_short Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties
title_sort Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties
topic Thiophene
Pyrrole
Donor-acceptor thienylpyrrole
Azo dyes
Heterocycles
Synthesis
Solvatochromism
Electrochemistry
Nonlinear optics (NLO)
UV-visible spectroscopy
donor-acceptor thienylpyrroles
UV-vis spectroscopy
chromophores
topic_facet Thiophene
Pyrrole
Donor-acceptor thienylpyrrole
Azo dyes
Heterocycles
Synthesis
Solvatochromism
Electrochemistry
Nonlinear optics (NLO)
UV-visible spectroscopy
donor-acceptor thienylpyrroles
UV-vis spectroscopy
chromophores
url https://hdl.handle.net/1822/7838
visible 1