Publicação
Improving the visible transmittance of low-e titanium nitride based coatings for solar thermal applications
| Resumo: | Low-emissivity (low-e) coatings on glass are nowadays extensively used for energy saving applications in architectural windows and on solar thermal collectors. In this work the feasibility of TiN-based layers as low-e coatings has been studied. TiN samples were deposited by reactive magnetron sputtering and, in order to improve their optical properties (transmission in the visible range, T and emissivity, ε), we have investigated the changes in optical response following three different approaches: (i) post-deposition annealing treatments up to 500 ◦C, (ii) doping the TiN layers with aluminium (target composition: Ti/Al = 90/10, 75/25 and 50/50) and (iii) deposition of antireflective coatings of TiO2 in multilayers structures. The crystalline structure and chemical composition of the multilayers were studied by X-Ray Diffraction and Rutherford Backscattering Spectroscopy, respectively. Spectroscopic Ellipsometry, Fourier Transform Infrared Spectroscopy and direct emissivity measurements were employed to determine the optical properties T and ε. We have concluded that the most noticeable improvement has been obtained by the deposition of multilayers structures increasing in a 30% the original transmittance of the single TiN coatings. |
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| Autores principais: | Yuste, M. |
| Outros Autores: | Galindo, R. Escobar; Carvalho, S.; Albella, J. M.; Sánchez, O. |
| Assunto: | Low-emissivity TiN Magnetron sputtering |
| Ano: | 2011 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Universidade do Minho |
| Idioma: | inglês |
| Origem: | RepositóriUM - Universidade do Minho |
| Resumo: | Low-emissivity (low-e) coatings on glass are nowadays extensively used for energy saving applications in architectural windows and on solar thermal collectors. In this work the feasibility of TiN-based layers as low-e coatings has been studied. TiN samples were deposited by reactive magnetron sputtering and, in order to improve their optical properties (transmission in the visible range, T and emissivity, ε), we have investigated the changes in optical response following three different approaches: (i) post-deposition annealing treatments up to 500 ◦C, (ii) doping the TiN layers with aluminium (target composition: Ti/Al = 90/10, 75/25 and 50/50) and (iii) deposition of antireflective coatings of TiO2 in multilayers structures. The crystalline structure and chemical composition of the multilayers were studied by X-Ray Diffraction and Rutherford Backscattering Spectroscopy, respectively. Spectroscopic Ellipsometry, Fourier Transform Infrared Spectroscopy and direct emissivity measurements were employed to determine the optical properties T and ε. We have concluded that the most noticeable improvement has been obtained by the deposition of multilayers structures increasing in a 30% the original transmittance of the single TiN coatings. |
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