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Mechanical performance of double gated injected metallic looking polypropylene parts

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Resumo:The metallic effect obtained by incorporation of metal particles in polymers by injection molding has the advantage of eliminating post-processing techniques reducing production cost and time. Nevertheless, undesired defects in the final appearance of parts are common. In this work PP/aluminum pigments were obtained by direct injection molding and the influence of metallic particles on the aesthetic, morphological and mechanical properties of the parts was assessed. Aesthetic aspects could be improved by manipulating processing conditions: high melt temperatures diminished differential shrinkage and made weld lines less noticeable. Also at high melt temperatures Al particles increased thermal conductivity of PP generating a thicker skin, which combined with an inherent gradient temperature and typical shear stresses developed during injection molding, induced the formation of beta-PP phase. Mechanical performance of parts showed to be dependent on PP morphology. Distinct deformation behaviors were seen according to the presence of PP polymorph, beta-PP counteracting the detrimental effect of not bonded Al flakes, and making PP-Al moldings to have similar toughness as PP moldings with the added value of metallic looking.
Autores principais:Costantino, M. A.
Outros Autores:Pettarin, V.; Pontes, A. J.; Frontini, P. M.
Assunto:Polymer composites Processing technologies Mechanical properties Fracture Morphology-performance relationship Olymer composites
Ano:2015
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso restrito
Instituição associada:Universidade do Minho
Idioma:inglês
Origem:RepositóriUM - Universidade do Minho
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author Costantino, M. A.
author2 Pettarin, V.
Pontes, A. J.
Frontini, P. M.
author2_role author
author
author
author_facet Costantino, M. A.
Pettarin, V.
Pontes, A. J.
Frontini, P. M.
author_role author
contributor_name_str_mv RepositóriUM - Universidade do Minho
country_str PT
creators_json_txt [{\"Person.name\":\"Costantino, M. A.\"},{\"Person.name\":\"Pettarin, V.\"},{\"Person.name\":\"Pontes, A. J.\"},{\"Person.name\":\"Frontini, P. M.\"}]
datacite.contributors.contributor.contributorName.fl_str_mv RepositóriUM - Universidade do Minho
datacite.creators.creator.creatorName.fl_str_mv Costantino, M. A.
Pettarin, V.
Pontes, A. J.
Frontini, P. M.
datacite.date.Accepted.fl_str_mv 2015-11-01T00:00:00Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_16ec
datacite.subjects.subject.fl_str_mv Polymer composites
Processing technologies
Mechanical properties
Fracture
Morphology-performance relationship
Olymer composites
datacite.titles.title.fl_str_mv Mechanical performance of double gated injected metallic looking polypropylene parts
dc.contributor.none.fl_str_mv RepositóriUM - Universidade do Minho
dc.creator.none.fl_str_mv Costantino, M. A.
Pettarin, V.
Pontes, A. J.
Frontini, P. M.
dc.date.Accepted.fl_str_mv 2015-11-01T00:00:00Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv https://hdl.handle.net/1822/53073
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Budapest University of Technology and Economics. Faculty of Civil Engineering
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_16ec
dc.subject.none.fl_str_mv Polymer composites
Processing technologies
Mechanical properties
Fracture
Morphology-performance relationship
Olymer composites
dc.title.fl_str_mv Mechanical performance of double gated injected metallic looking polypropylene parts
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description The metallic effect obtained by incorporation of metal particles in polymers by injection molding has the advantage of eliminating post-processing techniques reducing production cost and time. Nevertheless, undesired defects in the final appearance of parts are common. In this work PP/aluminum pigments were obtained by direct injection molding and the influence of metallic particles on the aesthetic, morphological and mechanical properties of the parts was assessed. Aesthetic aspects could be improved by manipulating processing conditions: high melt temperatures diminished differential shrinkage and made weld lines less noticeable. Also at high melt temperatures Al particles increased thermal conductivity of PP generating a thicker skin, which combined with an inherent gradient temperature and typical shear stresses developed during injection molding, induced the formation of beta-PP phase. Mechanical performance of parts showed to be dependent on PP morphology. Distinct deformation behaviors were seen according to the presence of PP polymorph, beta-PP counteracting the detrimental effect of not bonded Al flakes, and making PP-Al moldings to have similar toughness as PP moldings with the added value of metallic looking.
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eu_rights_str_mv restrictedAccess
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fulltext.url.fl_str_mv https://repositorium.uminho.pt/bitstreams/44e29164-a78a-4c12-bbef-1ab8aaf05825/download
id rum_fd2acb7c4e18bcb21d7c52dd67b2d5da
identifier.url.fl_str_mv https://hdl.handle.net/1822/53073
instacron_str repositorium
institution Universidade do Minho
instname_str Universidade do Minho
language eng
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network_name_str RepositóriUM - Universidade do Minho
oai_identifier_str oai:repositorium.uminho.pt:1822/53073
organization_str_mv urn:organizationAcronym:repositorium
person_str_mv Costantino, M. A.
Pettarin, V.
Pontes, A. J.
Frontini, P. M.
publishDate 2015
publisher.none.fl_str_mv Budapest University of Technology and Economics. Faculty of Civil Engineering
reponame_str RepositóriUM - Universidade do Minho
repository_id_str urn:repositoryAcronym:rum
service_str_mv urn:repositoryAcronym:rum
spelling engBudapest University of Technology and Economics. Faculty of Civil EngineeringporThe metallic effect obtained by incorporation of metal particles in polymers by injection molding has the advantage of eliminating post-processing techniques reducing production cost and time. Nevertheless, undesired defects in the final appearance of parts are common. In this work PP/aluminum pigments were obtained by direct injection molding and the influence of metallic particles on the aesthetic, morphological and mechanical properties of the parts was assessed. Aesthetic aspects could be improved by manipulating processing conditions: high melt temperatures diminished differential shrinkage and made weld lines less noticeable. Also at high melt temperatures Al particles increased thermal conductivity of PP generating a thicker skin, which combined with an inherent gradient temperature and typical shear stresses developed during injection molding, induced the formation of beta-PP phase. Mechanical performance of parts showed to be dependent on PP morphology. Distinct deformation behaviors were seen according to the presence of PP polymorph, beta-PP counteracting the detrimental effect of not bonded Al flakes, and making PP-Al moldings to have similar toughness as PP moldings with the added value of metallic looking.application/pdfporMechanical performance of double gated injected metallic looking polypropylene partsCostantino, M. A.Pettarin, V.Pontes, A. J.Frontini, P. M.HostingInstitutionOrganizationalRepositóriUM - Universidade do Minhoe-mailmailto:repositorium@usdb.uminho.ptrepositorium@usdb.uminho.ptISSNIsPartOf1788-618XDOIIsPartOf10.3144/expresspolymlett.2015.932015-112018-03-21T06:47:44Z2015-11-01T00:00:00ZHandlehttps://hdl.handle.net/1822/53073http://purl.org/coar/access_right/c_16ecrestricted accessPolymer compositesProcessing technologiesMechanical propertiesFractureMorphology-performance relationshipOlymer composites1267124 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_16ecapplication/pdffulltexthttps://repositorium.uminho.pt/bitstreams/44e29164-a78a-4c12-bbef-1ab8aaf05825/download
spellingShingle Mechanical performance of double gated injected metallic looking polypropylene parts
Costantino, M. A.
Polymer composites
Processing technologies
Mechanical properties
Fracture
Morphology-performance relationship
Olymer composites
status SINGLETON
subject.fl_str_mv Polymer composites
Processing technologies
Mechanical properties
Fracture
Morphology-performance relationship
Olymer composites
title Mechanical performance of double gated injected metallic looking polypropylene parts
title_full Mechanical performance of double gated injected metallic looking polypropylene parts
title_fullStr Mechanical performance of double gated injected metallic looking polypropylene parts
title_full_unstemmed Mechanical performance of double gated injected metallic looking polypropylene parts
title_short Mechanical performance of double gated injected metallic looking polypropylene parts
title_sort Mechanical performance of double gated injected metallic looking polypropylene parts
topic Polymer composites
Processing technologies
Mechanical properties
Fracture
Morphology-performance relationship
Olymer composites
topic_facet Polymer composites
Processing technologies
Mechanical properties
Fracture
Morphology-performance relationship
Olymer composites
url https://hdl.handle.net/1822/53073
visible 1