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Influence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium films

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Resumo:Titanium films were DC sputtered with a particle flux incidence angle of 80 degrees, using the Glancing Angle Deposition (GLAD) technique with increasing sputtering pressures from 0.2 to 1.5 Pa. This range of pressures is typically implemented for the deposition of thin films by the magnetron sputtering process. The main objective of this work was to study the anisotropic electrical resistivity behaviour of the different thin film nanostructures that were obtained. It is shown that low sputtering pressures (0.2-0.5 Pa) promote higher column angles beta with respect to the substrate normal (15 degrees <= beta <= 40 degrees), as well as better defined porous structures. On the other hand, intermediate and high pressures (0.6-0.8 Pa) originate secondary growth effects on the columnar structures perpendicular to the substrate normal (beta = 0 degrees). No defined columns can be seen when the films are sputtered using the highest pressure (1.5 Pa). The electrical resistivity is significantly affected by the differences in the columnar microstructure. Porous films exhibit higher room temperature (RT) resistivity values (0.95-1.5 x 10-5 Omega m), when compared to the more compact ones (0.6-0.9 x 10(-5) Omega m). When a temperature cycle of RT(25)-300-RT(25)degrees C was applied, a more significant oxidation is evidenced in the more porous structures, as well as a higher resistivity anisotropy (maximum of 1.6) than in the more compact ones (minimum of 1.25).
Autores principais:Pedrosa, Paulo Eduardo Teixeira Baptista
Outros Autores:Ferreira, Armando José Barros; Cote, Jean-Marc; Martin, Nicolas; Yazdi, Mohammad Arab Pour; Billard, Alain; Lanceros-Méndez, S.; Vaz, F.
Assunto:Glancing angle deposition Titanium Nanostructured films Anisotropy Electrical resistivity
Ano:2017
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso restrito
Instituição associada:Universidade do Minho
Idioma:inglês
Origem:RepositóriUM - Universidade do Minho
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author Pedrosa, Paulo Eduardo Teixeira Baptista
author2 Ferreira, Armando José Barros
Cote, Jean-Marc
Martin, Nicolas
Yazdi, Mohammad Arab Pour
Billard, Alain
Lanceros-Méndez, S.
Vaz, F.
author2_role author
author
author
author
author
author
author
author_facet Pedrosa, Paulo Eduardo Teixeira Baptista
Ferreira, Armando José Barros
Cote, Jean-Marc
Martin, Nicolas
Yazdi, Mohammad Arab Pour
Billard, Alain
Lanceros-Méndez, S.
Vaz, F.
author_role author
contributor_name_str_mv Universidade do Minho
country_str PT
creators_json_txt [{\"Person.name\":\"Pedrosa, Paulo Eduardo Teixeira Baptista\"},{\"Person.name\":\"Ferreira, Armando José Barros\"},{\"Person.name\":\"Cote, Jean-Marc\"},{\"Person.name\":\"Martin, Nicolas\"},{\"Person.name\":\"Yazdi, Mohammad Arab Pour\"},{\"Person.name\":\"Billard, Alain\"},{\"Person.name\":\"Lanceros-Méndez, S.\"},{\"Person.name\":\"Vaz, F.\"}]
datacite.contributors.contributor.contributorName.fl_str_mv Universidade do Minho
datacite.creators.creator.creatorName.fl_str_mv Pedrosa, Paulo Eduardo Teixeira Baptista
Ferreira, Armando José Barros
Cote, Jean-Marc
Martin, Nicolas
Yazdi, Mohammad Arab Pour
Billard, Alain
Lanceros-Méndez, S.
Vaz, F.
datacite.date.Accepted.fl_str_mv 2017-01-01T00:00:00Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_16ec
datacite.subjects.subject.fl_str_mv Glancing angle deposition
Titanium
Nanostructured films
Anisotropy
Electrical resistivity
datacite.titles.title.fl_str_mv Influence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium films
dc.contributor.none.fl_str_mv Universidade do Minho
dc.creator.none.fl_str_mv Pedrosa, Paulo Eduardo Teixeira Baptista
Ferreira, Armando José Barros
Cote, Jean-Marc
Martin, Nicolas
Yazdi, Mohammad Arab Pour
Billard, Alain
Lanceros-Méndez, S.
Vaz, F.
dc.date.Accepted.fl_str_mv 2017-01-01T00:00:00Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv https://hdl.handle.net/1822/52580
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Elsevier Science
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_16ec
dc.subject.none.fl_str_mv Glancing angle deposition
Titanium
Nanostructured films
Anisotropy
Electrical resistivity
dc.title.fl_str_mv Influence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium films
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description Titanium films were DC sputtered with a particle flux incidence angle of 80 degrees, using the Glancing Angle Deposition (GLAD) technique with increasing sputtering pressures from 0.2 to 1.5 Pa. This range of pressures is typically implemented for the deposition of thin films by the magnetron sputtering process. The main objective of this work was to study the anisotropic electrical resistivity behaviour of the different thin film nanostructures that were obtained. It is shown that low sputtering pressures (0.2-0.5 Pa) promote higher column angles beta with respect to the substrate normal (15 degrees <= beta <= 40 degrees), as well as better defined porous structures. On the other hand, intermediate and high pressures (0.6-0.8 Pa) originate secondary growth effects on the columnar structures perpendicular to the substrate normal (beta = 0 degrees). No defined columns can be seen when the films are sputtered using the highest pressure (1.5 Pa). The electrical resistivity is significantly affected by the differences in the columnar microstructure. Porous films exhibit higher room temperature (RT) resistivity values (0.95-1.5 x 10-5 Omega m), when compared to the more compact ones (0.6-0.9 x 10(-5) Omega m). When a temperature cycle of RT(25)-300-RT(25)degrees C was applied, a more significant oxidation is evidenced in the more porous structures, as well as a higher resistivity anisotropy (maximum of 1.6) than in the more compact ones (minimum of 1.25).
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eu_rights_str_mv restrictedAccess
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fulltext.url.fl_str_mv https://prod-dspace.uminho.pt/bitstreams/2f4fe456-020d-4de3-b139-1c6cde990968/download
id rum_fe9c4e4b0f95ab72ba2c68cf0a5a7ef1
identifier.url.fl_str_mv https://hdl.handle.net/1822/52580
instacron_str repositorium
institution Universidade do Minho
instname_str Universidade do Minho
language eng
network_acronym_str rum
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oai_identifier_str oai:repositorium.uminho.pt:1822/52580
organization_str_mv urn:organizationAcronym:repositorium
person_str_mv Pedrosa, Paulo Eduardo Teixeira Baptista
Ferreira, Armando José Barros
Cote, Jean-Marc
Martin, Nicolas
Yazdi, Mohammad Arab Pour
Billard, Alain
Lanceros-Méndez, S.
Vaz, F.
publishDate 2017
publisher.none.fl_str_mv Elsevier Science
reponame_str RepositóriUM - Universidade do Minho
repository_id_str urn:repositoryAcronym:rum
service_str_mv urn:repositoryAcronym:rum
spelling engElsevier ScienceporTitanium films were DC sputtered with a particle flux incidence angle of 80 degrees, using the Glancing Angle Deposition (GLAD) technique with increasing sputtering pressures from 0.2 to 1.5 Pa. This range of pressures is typically implemented for the deposition of thin films by the magnetron sputtering process. The main objective of this work was to study the anisotropic electrical resistivity behaviour of the different thin film nanostructures that were obtained. It is shown that low sputtering pressures (0.2-0.5 Pa) promote higher column angles beta with respect to the substrate normal (15 degrees <= beta <= 40 degrees), as well as better defined porous structures. On the other hand, intermediate and high pressures (0.6-0.8 Pa) originate secondary growth effects on the columnar structures perpendicular to the substrate normal (beta = 0 degrees). No defined columns can be seen when the films are sputtered using the highest pressure (1.5 Pa). The electrical resistivity is significantly affected by the differences in the columnar microstructure. Porous films exhibit higher room temperature (RT) resistivity values (0.95-1.5 x 10-5 Omega m), when compared to the more compact ones (0.6-0.9 x 10(-5) Omega m). When a temperature cycle of RT(25)-300-RT(25)degrees C was applied, a more significant oxidation is evidenced in the more porous structures, as well as a higher resistivity anisotropy (maximum of 1.6) than in the more compact ones (minimum of 1.25).application/pdfporInfluence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium filmsPedrosa, Paulo Eduardo Teixeira BaptistaFerreira, Armando José BarrosCote, Jean-MarcMartin, NicolasYazdi, Mohammad Arab PourBillard, AlainLanceros-Méndez, S.Vaz, F.HostingInstitutionOrganizationalUniversidade do Minhoe-mailmailto:repositorium@usdb.uminho.ptrepositorium@usdb.uminho.ptISSNIsPartOf0169-4332DOIIsPartOf10.1016/j.apsusc.2017.05.17520172018-03-13T10:43:38Z2017-01-01T00:00:00ZHandlehttps://hdl.handle.net/1822/52580http://purl.org/coar/access_right/c_16ecrestricted accessGlancing angle depositionTitaniumNanostructured filmsAnisotropyElectrical resistivity4707128 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_16ecapplication/pdffulltexthttps://prod-dspace.uminho.pt/bitstreams/2f4fe456-020d-4de3-b139-1c6cde990968/download
spellingShingle Influence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium films
Pedrosa, Paulo Eduardo Teixeira Baptista
Glancing angle deposition
Titanium
Nanostructured films
Anisotropy
Electrical resistivity
status SINGLETON
subject.fl_str_mv Glancing angle deposition
Titanium
Nanostructured films
Anisotropy
Electrical resistivity
title Influence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium films
title_full Influence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium films
title_fullStr Influence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium films
title_full_unstemmed Influence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium films
title_short Influence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium films
title_sort Influence of the sputtering pressure on the morphological features and electrical resistivity anisotropy of nanostructured titanium films
topic Glancing angle deposition
Titanium
Nanostructured films
Anisotropy
Electrical resistivity
topic_facet Glancing angle deposition
Titanium
Nanostructured films
Anisotropy
Electrical resistivity
url https://hdl.handle.net/1822/52580
visible 1