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Viscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanol
| Resumo: | In this study, the viscosity behavior of two mixtures of Ethaline (1 ChCl:2 ethylene glycol) with either methanol or ethanol were investigated over the temperature range of 283.15–333.15 K at atmospheric pressure. The measured viscosities of neat Ethaline, methanol, and ethanol showed reliable agreement with the corresponding reported literature values. The mixture viscosities were modeled by an Arrhenius-like model to determine the behavior of viscosity with respect to temperature. The data were also modeled by the four well-known mixture viscosity models of Grunberg–Nissan, Jouyban–Acree, McAllister, and Preferential Solvation. All of the model results were reliable, with the Jouyban–Acree and Preferential Solvation models showing the most accurate agreement with the experimental measurements. The Jones–Dole viscosity model was also investigated for the measured viscosities, and by analyzing the results of this model, strong interactions among Ethaline and the alcohol molecules were proposed for both systems. As a final analysis, viscosity deviations of the investigated systems were calculated to study the deviations of the viscosity behaviors with respect to ideal behavior. Both systems showed negative viscosity deviations at all of the investigated temperatures, with the negative values tending towards zero, and hence more ideal behavior, with increasing temperatures. Moreover, in order to correlate the calculated viscosity deviations, the Redlich–Kister model was successfully used for both systems and at each investigated temperature. |
|---|---|
| Autores principais: | Haghbakhsh, Reza |
| Outros Autores: | Duarte, Ana Rita C.; Raeissi, Sona |
| Assunto: | Alcohol Alkanol Deep Eutectic Solvent Eutectic mixture Excess property Green solvent Physical property Thermodynamic modeling Viscosity deviation Analytical Chemistry Chemistry (miscellaneous) Molecular Medicine Pharmaceutical Science Drug Discovery Physical and Theoretical Chemistry Organic Chemistry |
| Ano: | 2021 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Universidade Nova de Lisboa |
| Idioma: | inglês |
| Origem: | Repositório Institucional da UNL |
| _version_ | 1868983810370043904 |
|---|---|
| author | Haghbakhsh, Reza |
| author2 | Duarte, Ana Rita C. Raeissi, Sona |
| author2_role | author author |
| author_facet | Haghbakhsh, Reza Duarte, Ana Rita C. Raeissi, Sona |
| author_role | author |
| contributor_name_str_mv | LAQV@REQUIMTE DQ - Departamento de Química MDPI - Multidisciplinary Digital Publishing Institute RUN |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Haghbakhsh, Reza\"},{\"Person.name\":\"Duarte, Ana Rita C.\"},{\"Person.name\":\"Raeissi, Sona\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | LAQV@REQUIMTE DQ - Departamento de Química MDPI - Multidisciplinary Digital Publishing Institute RUN |
| datacite.creators.creator.creatorName.fl_str_mv | Haghbakhsh, Reza Duarte, Ana Rita C. Raeissi, Sona |
| datacite.date.Accepted.fl_str_mv | 2021-09-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2022-10-10T22:14:55Z |
| datacite.date.embargoed.fl_str_mv | 2022-10-10T22:14:55Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | Alcohol Alkanol Deep Eutectic Solvent Eutectic mixture Excess property Green solvent Physical property Thermodynamic modeling Viscosity deviation Analytical Chemistry Chemistry (miscellaneous) Molecular Medicine Pharmaceutical Science Drug Discovery Physical and Theoretical Chemistry Organic Chemistry |
| datacite.titles.title.fl_str_mv | Viscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanol |
| dc.contributor.none.fl_str_mv | LAQV@REQUIMTE DQ - Departamento de Química MDPI - Multidisciplinary Digital Publishing Institute RUN |
| dc.creator.none.fl_str_mv | Haghbakhsh, Reza Duarte, Ana Rita C. Raeissi, Sona |
| dc.date.Accepted.fl_str_mv | 2021-09-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2022-10-10T22:14:55Z |
| dc.date.embargoed.fl_str_mv | 2022-10-10T22:14:55Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/10362/144572 |
| dc.language.none.fl_str_mv | eng |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.subject.none.fl_str_mv | Alcohol Alkanol Deep Eutectic Solvent Eutectic mixture Excess property Green solvent Physical property Thermodynamic modeling Viscosity deviation Analytical Chemistry Chemistry (miscellaneous) Molecular Medicine Pharmaceutical Science Drug Discovery Physical and Theoretical Chemistry Organic Chemistry |
| dc.title.fl_str_mv | Viscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanol |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | In this study, the viscosity behavior of two mixtures of Ethaline (1 ChCl:2 ethylene glycol) with either methanol or ethanol were investigated over the temperature range of 283.15–333.15 K at atmospheric pressure. The measured viscosities of neat Ethaline, methanol, and ethanol showed reliable agreement with the corresponding reported literature values. The mixture viscosities were modeled by an Arrhenius-like model to determine the behavior of viscosity with respect to temperature. The data were also modeled by the four well-known mixture viscosity models of Grunberg–Nissan, Jouyban–Acree, McAllister, and Preferential Solvation. All of the model results were reliable, with the Jouyban–Acree and Preferential Solvation models showing the most accurate agreement with the experimental measurements. The Jones–Dole viscosity model was also investigated for the measured viscosities, and by analyzing the results of this model, strong interactions among Ethaline and the alcohol molecules were proposed for both systems. As a final analysis, viscosity deviations of the investigated systems were calculated to study the deviations of the viscosity behaviors with respect to ideal behavior. Both systems showed negative viscosity deviations at all of the investigated temperatures, with the negative values tending towards zero, and hence more ideal behavior, with increasing temperatures. Moreover, in order to correlate the calculated viscosity deviations, the Redlich–Kister model was successfully used for both systems and at each investigated temperature. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| fulltext.url.fl_str_mv | https://run.unl.pt/bitstreams/31606d2a-0cf3-46a8-8144-daa729c40adb/download |
| funder_facet_str_mv | FCT{{{_:::_}}}Fundação para a Ciência e a Tecnologia |
| funding.funder.alternateName_str_mv | FCT |
| funding.funder.identifier_str_mv | http://doi.org/10.13039/501100001871 |
| funding.funder.name_str_mv | Fundação para a Ciência e a Tecnologia |
| funding.name_str_mv | 6817 - DCRRNI ID |
| id | run_4a427dad19caa0dae9db232fbb8166dd |
| identifier.url.fl_str_mv | http://hdl.handle.net/10362/144572 |
| inst_facet_str | urn:organizationAcronym:unl{{{_:::_}}}Universidade Nova de Lisboa |
| instacron_str | unl |
| institution | Universidade Nova de Lisboa |
| instname_str | Universidade Nova de Lisboa |
| language | eng |
| network_acronym_str | run |
| network_name_str | Repositório Institucional da UNL |
| oai_identifier_str | oai:run.unl.pt:10362/144572 |
| organization_str_mv | urn:organizationAcronym:unl |
| person_str_mv | Haghbakhsh, Reza Duarte, Ana Rita C. Raeissi, Sona |
| publishDate | 2021 |
| repo_facet_str | urn:repositoryAcronym:run{{{_:::_}}}Repositório Institucional da UNL |
| reponame_str | Repositório Institucional da UNL |
| repository_id_str | urn:repositoryAcronym:run |
| service_str_mv | urn:repositoryAcronym:run |
| spelling | engenIn this study, the viscosity behavior of two mixtures of Ethaline (1 ChCl:2 ethylene glycol) with either methanol or ethanol were investigated over the temperature range of 283.15–333.15 K at atmospheric pressure. The measured viscosities of neat Ethaline, methanol, and ethanol showed reliable agreement with the corresponding reported literature values. The mixture viscosities were modeled by an Arrhenius-like model to determine the behavior of viscosity with respect to temperature. The data were also modeled by the four well-known mixture viscosity models of Grunberg–Nissan, Jouyban–Acree, McAllister, and Preferential Solvation. All of the model results were reliable, with the Jouyban–Acree and Preferential Solvation models showing the most accurate agreement with the experimental measurements. The Jones–Dole viscosity model was also investigated for the measured viscosities, and by analyzing the results of this model, strong interactions among Ethaline and the alcohol molecules were proposed for both systems. As a final analysis, viscosity deviations of the investigated systems were calculated to study the deviations of the viscosity behaviors with respect to ideal behavior. Both systems showed negative viscosity deviations at all of the investigated temperatures, with the negative values tending towards zero, and hence more ideal behavior, with increasing temperatures. Moreover, in order to correlate the calculated viscosity deviations, the Redlich–Kister model was successfully used for both systems and at each investigated temperature.application/pdfenViscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanolHaghbakhsh, RezaDuarte, Ana Rita C.Raeissi, SonaLAQV@REQUIMTEDQ - Departamento de QuímicaMDPI - Multidisciplinary Digital Publishing InstituteHostingInstitutionOrganizationalRUNe-mailmailto:run@unl.ptrun@unl.ptISSNIsPartOf1420-3049URNIsPartOfPURE: 45668907URNIsPartOfPURE UUID: c1fa108d-c9cc-4ecf-9cfb-8f512b759b92URNIsPartOfScopus: 85114953325URNIsPartOfPubMed: 34576980URNIsPartOfWOS: 000701918200001URNIsPartOfPubMedCentral: PMC8465307URNIsPartOfORCID: /0000-0003-0800-0112/work/116509161DOIIsPartOf10.3390/molecules261855132022-10-10T22:14:55Z2021-092021-09-01T00:00:00ZHandlehttp://hdl.handle.net/10362/144572http://purl.org/coar/access_right/c_abf2open accessAlcoholAlkanolDeep Eutectic SolventEutectic mixtureExcess propertyGreen solventPhysical propertyThermodynamic modelingViscosity deviationAnalytical ChemistryChemistry (miscellaneous)Molecular MedicinePharmaceutical ScienceDrug DiscoveryPhysical and Theoretical ChemistryOrganic Chemistry1291433 bytesFundação para a Ciência e a TecnologiaAssociated Laboratory for Green Chemistry - Clean Technologies and Processes6817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871literaturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://run.unl.pt/bitstreams/31606d2a-0cf3-46a8-8144-daa729c40adb/download |
| spellingShingle | Viscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanol Haghbakhsh, Reza Alcohol Alkanol Deep Eutectic Solvent Eutectic mixture Excess property Green solvent Physical property Thermodynamic modeling Viscosity deviation Analytical Chemistry Chemistry (miscellaneous) Molecular Medicine Pharmaceutical Science Drug Discovery Physical and Theoretical Chemistry Organic Chemistry |
| status | SINGLETON |
| subject.fl_str_mv | Alcohol Alkanol Deep Eutectic Solvent Eutectic mixture Excess property Green solvent Physical property Thermodynamic modeling Viscosity deviation Analytical Chemistry Chemistry (miscellaneous) Molecular Medicine Pharmaceutical Science Drug Discovery Physical and Theoretical Chemistry Organic Chemistry |
| title | Viscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanol |
| title_full | Viscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanol |
| title_fullStr | Viscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanol |
| title_full_unstemmed | Viscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanol |
| title_short | Viscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanol |
| title_sort | Viscosity investigations on the binary systems of (1 chcl:2 ethylene glycol) des and methanol or ethanol |
| topic | Alcohol Alkanol Deep Eutectic Solvent Eutectic mixture Excess property Green solvent Physical property Thermodynamic modeling Viscosity deviation Analytical Chemistry Chemistry (miscellaneous) Molecular Medicine Pharmaceutical Science Drug Discovery Physical and Theoretical Chemistry Organic Chemistry |
| topic_facet | Alcohol Alkanol Deep Eutectic Solvent Eutectic mixture Excess property Green solvent Physical property Thermodynamic modeling Viscosity deviation Analytical Chemistry Chemistry (miscellaneous) Molecular Medicine Pharmaceutical Science Drug Discovery Physical and Theoretical Chemistry Organic Chemistry |
| url | http://hdl.handle.net/10362/144572 |
| visible | 1 |