Publicação
A First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from Turkey
| Resumo: | For the first time, Eriolobus trilobatus bark from Turkey has been characterized in terms of its chemical, extractive, fuel, and ash characteristics using SEM–EDS, wet chemical analysis, phenolic analysis, FT-IR, TGA, XRF, XRD, BET surface area measurement, proximate analysis, and ash fusion temperature (AFT) determination. The results showed that the bark contains 13% ash, dominated by calcium oxalate, and 15% extractives, largely composed of polar phenolic compounds with moderate radical-scavenging potential. Thermal decomposition of bark proceeds in four distinct stages, associated with the sequential degradation of extractives/hemicelluloses, cellulose, lignin/suberin, and inorganic fractions. The higher calorific value of 14.9 MJ/kg indicates moderate fuel quality compared with conventional woody biomass. Ash is mesoporous with a CaO-rich structure highly suitable for catalytic applications in biodiesel production and biomass gasification. Ash fusion analysis revealed a high flow temperature (1452 °C), indicating a very low slagging risk during thermochemical conversion. Overall, E. trilobatus bark is a promising material for value-added biorefinery pathways, enabling processes for the production of biochars, CaO-based catalysts, phenolic extracts, and sustainable energy. The valorization of E. trilobatus bark not only enhances the economic potential of forestry residues but also provides environmental co-benefits through carbon soil amendment and landscape applications. |
|---|---|
| Autores principais: | Șen, Umut |
| Outros Autores: | Yücedağ, Cengiz; Balcı, Büşra; Arıcı, Şefik; Koçar, Günnur; Şat, Beyza; Viegas, Catarina; Gonçalves, Margarida; Miranda, Isabel; Pereira, Helena |
| Assunto: | AFT Bark BET Biodiesel CaO Gasification HCV TGA XRD XRF Bioengineering Chemical Engineering (miscellaneous) Process Chemistry and Technology |
| Ano: | 2025 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Universidade Nova de Lisboa |
| Idioma: | inglês |
| Origem: | Repositório Institucional da UNL |
| _version_ | 1868984213641887744 |
|---|---|
| author | Șen, Umut |
| author2 | Yücedağ, Cengiz Balcı, Büşra Arıcı, Şefik Koçar, Günnur Şat, Beyza Viegas, Catarina Gonçalves, Margarida Miranda, Isabel Pereira, Helena |
| author2_role | author author author author author author author author author |
| author_facet | Șen, Umut Yücedağ, Cengiz Balcı, Büşra Arıcı, Şefik Koçar, Günnur Şat, Beyza Viegas, Catarina Gonçalves, Margarida Miranda, Isabel Pereira, Helena |
| author_role | author |
| contributor_name_str_mv | DCTB - Departamento de Ciências e Tecnologia da Biomassa (ex-GDEH) MEtRICS - Centro de Engenharia Mecânica e Sustentabilidade de Recursos MDPI - Multidisciplinary Digital Publishing Institute RUN |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Șen, Umut\"},{\"Person.name\":\"Yücedağ, Cengiz\"},{\"Person.name\":\"Balcı, Büşra\"},{\"Person.name\":\"Arıcı, Şefik\"},{\"Person.name\":\"Koçar, Günnur\"},{\"Person.name\":\"Şat, Beyza\"},{\"Person.name\":\"Viegas, Catarina\"},{\"Person.name\":\"Gonçalves, Margarida\"},{\"Person.name\":\"Miranda, Isabel\"},{\"Person.name\":\"Pereira, Helena\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | DCTB - Departamento de Ciências e Tecnologia da Biomassa (ex-GDEH) MEtRICS - Centro de Engenharia Mecânica e Sustentabilidade de Recursos MDPI - Multidisciplinary Digital Publishing Institute RUN |
| datacite.creators.creator.creatorName.fl_str_mv | Șen, Umut Yücedağ, Cengiz Balcı, Büşra Arıcı, Şefik Koçar, Günnur Şat, Beyza Viegas, Catarina Gonçalves, Margarida Miranda, Isabel Pereira, Helena |
| datacite.date.Accepted.fl_str_mv | 2025-12-06T00:00:00Z |
| datacite.date.available.fl_str_mv | 2026-02-11T17:07:02Z |
| datacite.date.embargoed.fl_str_mv | 2026-02-11T17:07:02Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | AFT Bark BET Biodiesel CaO Gasification HCV TGA XRD XRF Bioengineering Chemical Engineering (miscellaneous) Process Chemistry and Technology |
| datacite.titles.title.fl_str_mv | A First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from Turkey Chemical, Morphological and Energy Properties |
| dc.contributor.none.fl_str_mv | DCTB - Departamento de Ciências e Tecnologia da Biomassa (ex-GDEH) MEtRICS - Centro de Engenharia Mecânica e Sustentabilidade de Recursos MDPI - Multidisciplinary Digital Publishing Institute RUN |
| dc.creator.none.fl_str_mv | Șen, Umut Yücedağ, Cengiz Balcı, Büşra Arıcı, Şefik Koçar, Günnur Şat, Beyza Viegas, Catarina Gonçalves, Margarida Miranda, Isabel Pereira, Helena |
| dc.date.Accepted.fl_str_mv | 2025-12-06T00:00:00Z |
| dc.date.available.fl_str_mv | 2026-02-11T17:07:02Z |
| dc.date.embargoed.fl_str_mv | 2026-02-11T17:07:02Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/10362/200303 |
| dc.language.none.fl_str_mv | eng |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.subject.none.fl_str_mv | AFT Bark BET Biodiesel CaO Gasification HCV TGA XRD XRF Bioengineering Chemical Engineering (miscellaneous) Process Chemistry and Technology |
| dc.title.fl_str_mv | A First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from Turkey Chemical, Morphological and Energy Properties |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | For the first time, Eriolobus trilobatus bark from Turkey has been characterized in terms of its chemical, extractive, fuel, and ash characteristics using SEM–EDS, wet chemical analysis, phenolic analysis, FT-IR, TGA, XRF, XRD, BET surface area measurement, proximate analysis, and ash fusion temperature (AFT) determination. The results showed that the bark contains 13% ash, dominated by calcium oxalate, and 15% extractives, largely composed of polar phenolic compounds with moderate radical-scavenging potential. Thermal decomposition of bark proceeds in four distinct stages, associated with the sequential degradation of extractives/hemicelluloses, cellulose, lignin/suberin, and inorganic fractions. The higher calorific value of 14.9 MJ/kg indicates moderate fuel quality compared with conventional woody biomass. Ash is mesoporous with a CaO-rich structure highly suitable for catalytic applications in biodiesel production and biomass gasification. Ash fusion analysis revealed a high flow temperature (1452 °C), indicating a very low slagging risk during thermochemical conversion. Overall, E. trilobatus bark is a promising material for value-added biorefinery pathways, enabling processes for the production of biochars, CaO-based catalysts, phenolic extracts, and sustainable energy. The valorization of E. trilobatus bark not only enhances the economic potential of forestry residues but also provides environmental co-benefits through carbon soil amendment and landscape applications. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| fulltext.url.fl_str_mv | https://run.unl.pt/bitstreams/33fa073b-15ce-426f-b7a6-f3fda21610d5/download |
| id | run_4faececcb694698c0dfe346a9e8caeea |
| identifier.url.fl_str_mv | http://hdl.handle.net/10362/200303 |
| inst_facet_str | urn:organizationAcronym:unl{{{_:::_}}}Universidade Nova de Lisboa |
| instacron_str | unl |
| institution | Universidade Nova de Lisboa |
| instname_str | Universidade Nova de Lisboa |
| language | eng |
| network_acronym_str | run |
| network_name_str | Repositório Institucional da UNL |
| oai_identifier_str | oai:run.unl.pt:10362/200303 |
| organization_str_mv | urn:organizationAcronym:unl |
| person_str_mv | Șen, Umut Yücedağ, Cengiz Balcı, Büşra Arıcı, Şefik Koçar, Günnur Şat, Beyza Viegas, Catarina Gonçalves, Margarida Miranda, Isabel Pereira, Helena |
| publishDate | 2025 |
| repo_facet_str | urn:repositoryAcronym:run{{{_:::_}}}Repositório Institucional da UNL |
| reponame_str | Repositório Institucional da UNL |
| repository_id_str | urn:repositoryAcronym:run |
| service_str_mv | urn:repositoryAcronym:run |
| spelling | engenFor the first time, Eriolobus trilobatus bark from Turkey has been characterized in terms of its chemical, extractive, fuel, and ash characteristics using SEM–EDS, wet chemical analysis, phenolic analysis, FT-IR, TGA, XRF, XRD, BET surface area measurement, proximate analysis, and ash fusion temperature (AFT) determination. The results showed that the bark contains 13% ash, dominated by calcium oxalate, and 15% extractives, largely composed of polar phenolic compounds with moderate radical-scavenging potential. Thermal decomposition of bark proceeds in four distinct stages, associated with the sequential degradation of extractives/hemicelluloses, cellulose, lignin/suberin, and inorganic fractions. The higher calorific value of 14.9 MJ/kg indicates moderate fuel quality compared with conventional woody biomass. Ash is mesoporous with a CaO-rich structure highly suitable for catalytic applications in biodiesel production and biomass gasification. Ash fusion analysis revealed a high flow temperature (1452 °C), indicating a very low slagging risk during thermochemical conversion. Overall, E. trilobatus bark is a promising material for value-added biorefinery pathways, enabling processes for the production of biochars, CaO-based catalysts, phenolic extracts, and sustainable energy. The valorization of E. trilobatus bark not only enhances the economic potential of forestry residues but also provides environmental co-benefits through carbon soil amendment and landscape applications.application/pdfenA First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from TurkeySubtitleenChemical, Morphological and Energy PropertiesȘen, UmutYücedağ, CengizBalcı, BüşraArıcı, ŞefikKoçar, GünnurŞat, BeyzaViegas, CatarinaGonçalves, MargaridaMiranda, IsabelPereira, HelenaDCTB - Departamento de Ciências e Tecnologia da Biomassa (ex-GDEH)MEtRICS - Centro de Engenharia Mecânica e Sustentabilidade de RecursosMDPI - Multidisciplinary Digital Publishing InstituteHostingInstitutionOrganizationalRUNe-mailmailto:run@unl.ptrun@unl.ptISSNIsPartOf2227-9717URNIsPartOfPURE: 152888302URNIsPartOfPURE UUID: a187eae7-9fb4-44b4-bf3f-9cbab75aa16cURNIsPartOfScopus: 105025936078URNIsPartOfWOS: 001646565600001URNIsPartOfORCID: /0000-0002-0940-519X/work/205460159DOIIsPartOf10.3390/pr131239462026-02-11T17:07:02Z2025-12-062025-12-06T00:00:00ZHandlehttp://hdl.handle.net/10362/200303http://purl.org/coar/access_right/c_abf2open accessAFTBarkBETBiodieselCaOGasificationHCVTGAXRDXRFBioengineeringChemical Engineering (miscellaneous)Process Chemistry and Technology1777521 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://run.unl.pt/bitstreams/33fa073b-15ce-426f-b7a6-f3fda21610d5/download |
| spellingShingle | A First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from Turkey Șen, Umut AFT Bark BET Biodiesel CaO Gasification HCV TGA XRD XRF Bioengineering Chemical Engineering (miscellaneous) Process Chemistry and Technology |
| status | SINGLETON |
| subject.fl_str_mv | AFT Bark BET Biodiesel CaO Gasification HCV TGA XRD XRF Bioengineering Chemical Engineering (miscellaneous) Process Chemistry and Technology |
| title | A First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from Turkey |
| title_full | A First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from Turkey |
| title_fullStr | A First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from Turkey |
| title_full_unstemmed | A First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from Turkey |
| title_short | A First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from Turkey |
| title_sort | A First Process-Oriented Characterization of Eriolobus trilobatus (Labill. ex Poiret) Bark from Turkey |
| topic | AFT Bark BET Biodiesel CaO Gasification HCV TGA XRD XRF Bioengineering Chemical Engineering (miscellaneous) Process Chemistry and Technology |
| topic_facet | AFT Bark BET Biodiesel CaO Gasification HCV TGA XRD XRF Bioengineering Chemical Engineering (miscellaneous) Process Chemistry and Technology |
| url | http://hdl.handle.net/10362/200303 |
| visible | 1 |