Publicação
Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors
| Resumo: | Laser-induced graphene (LIG) is widely used to fabricate microsupercapacitors (MSCs) on various sustainable substrates, such as wood, cork, and lignin. However, the fabrication of MSCs, especially high energy density devices on paper, has rarely been reported. In this work, LIG electrodes are fabricated on wax-coated paper, followed by electrochemical deposition of manganese oxide (MnO2). The obtained LIG/MnO2 supercapacitors exhibit a maximum areal capacitance of 86.9 mF cm−2, while a device with pristine LIG electrodes exhibit a capacitance of 9.1 mF cm−2, both measured at a current density of 0.1 mA cm−2. In addition, the supercapacitor exhibits good cycling stability, retaining 80% of its initial capacitance after 1000 charge/discharge cycles at a current density of 1 mA cm−2. Notably, the LIG/MnO2 supercapacitor exhibits an exceptionally high energy density of 7.3 µWh cm−2 at a power density of 38.8 µW cm−2. In summary, a simple, fast, scalable, reproducible, and energy-efficient fabrication method is represented using electrochemical deposition of manganese oxide on paper-based laser-induced graphene, which are natural, abundant, and sustainable materials, paving the way for large-scale production of environmentally friendly supercapacitors. |
|---|---|
| Autores principais: | Klem, Maykel dos Santos |
| Outros Autores: | Abreu, Rodrigo; Pinheiro, Tomás; Coelho, João; Alves, Neri; Martins, Rodrigo |
| Assunto: | energy storage laser-induced-graphene paper electronics supercapacitor sustainable fabrication Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy |
| Ano: | 2024 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Universidade Nova de Lisboa |
| Idioma: | inglês |
| Origem: | Repositório Institucional da UNL |
| _version_ | 1868983547636744192 |
|---|---|
| author | Klem, Maykel dos Santos |
| author2 | Abreu, Rodrigo Pinheiro, Tomás Coelho, João Alves, Neri Martins, Rodrigo |
| author2_role | author author author author author |
| author_facet | Klem, Maykel dos Santos Abreu, Rodrigo Pinheiro, Tomás Coelho, João Alves, Neri Martins, Rodrigo |
| author_role | author |
| contributor_name_str_mv | CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N) UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias DCM - Departamento de Ciência dos Materiais John Wiley and Sons Inc. RUN |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Klem, Maykel dos Santos\"},{\"Person.name\":\"Abreu, Rodrigo\"},{\"Person.name\":\"Pinheiro, Tomás\"},{\"Person.name\":\"Coelho, João\"},{\"Person.name\":\"Alves, Neri\"},{\"Person.name\":\"Martins, Rodrigo\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N) UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias DCM - Departamento de Ciência dos Materiais John Wiley and Sons Inc. RUN |
| datacite.creators.creator.creatorName.fl_str_mv | Klem, Maykel dos Santos Abreu, Rodrigo Pinheiro, Tomás Coelho, João Alves, Neri Martins, Rodrigo |
| datacite.date.Accepted.fl_str_mv | 2024-12-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2025-02-07T21:14:37Z |
| datacite.date.embargoed.fl_str_mv | 2025-02-07T21:14:37Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | energy storage laser-induced-graphene paper electronics supercapacitor sustainable fabrication Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy |
| datacite.titles.title.fl_str_mv | Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors |
| dc.contributor.none.fl_str_mv | CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N) UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias DCM - Departamento de Ciência dos Materiais John Wiley and Sons Inc. RUN |
| dc.creator.none.fl_str_mv | Klem, Maykel dos Santos Abreu, Rodrigo Pinheiro, Tomás Coelho, João Alves, Neri Martins, Rodrigo |
| dc.date.Accepted.fl_str_mv | 2024-12-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2025-02-07T21:14:37Z |
| dc.date.embargoed.fl_str_mv | 2025-02-07T21:14:37Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/10362/178641 |
| dc.language.none.fl_str_mv | eng |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.subject.none.fl_str_mv | energy storage laser-induced-graphene paper electronics supercapacitor sustainable fabrication Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy |
| dc.title.fl_str_mv | Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Laser-induced graphene (LIG) is widely used to fabricate microsupercapacitors (MSCs) on various sustainable substrates, such as wood, cork, and lignin. However, the fabrication of MSCs, especially high energy density devices on paper, has rarely been reported. In this work, LIG electrodes are fabricated on wax-coated paper, followed by electrochemical deposition of manganese oxide (MnO2). The obtained LIG/MnO2 supercapacitors exhibit a maximum areal capacitance of 86.9 mF cm−2, while a device with pristine LIG electrodes exhibit a capacitance of 9.1 mF cm−2, both measured at a current density of 0.1 mA cm−2. In addition, the supercapacitor exhibits good cycling stability, retaining 80% of its initial capacitance after 1000 charge/discharge cycles at a current density of 1 mA cm−2. Notably, the LIG/MnO2 supercapacitor exhibits an exceptionally high energy density of 7.3 µWh cm−2 at a power density of 38.8 µW cm−2. In summary, a simple, fast, scalable, reproducible, and energy-efficient fabrication method is represented using electrochemical deposition of manganese oxide on paper-based laser-induced graphene, which are natural, abundant, and sustainable materials, paving the way for large-scale production of environmentally friendly supercapacitors. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| fulltext.url.fl_str_mv | https://run.unl.pt/bitstreams/a9d64370-aba4-4244-b202-073612fd35e5/download |
| funder_facet_str_mv | FCT{{{_:::_}}}Fundação para a Ciência e a Tecnologia FCT{{{_:::_}}}Fundação para a Ciência e a Tecnologia FCT{{{_:::_}}}Fundação para a Ciência e a Tecnologia |
| funding.funder.alternateName_str_mv | FCT FCT FCT |
| funding.funder.identifier_str_mv | http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 |
| funding.funder.name_str_mv | Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia |
| funding.name_str_mv | 6817 - DCRRNI ID 6817 - DCRRNI ID CEEC IND 2018 |
| id | run_5301ac3ef3be8bc8dddc420a57177aa1 |
| identifier.url.fl_str_mv | http://hdl.handle.net/10362/178641 |
| inst_facet_str | urn:organizationAcronym:unl{{{_:::_}}}Universidade Nova de Lisboa |
| instacron_str | unl |
| institution | Universidade Nova de Lisboa |
| instname_str | Universidade Nova de Lisboa |
| language | eng |
| network_acronym_str | run |
| network_name_str | Repositório Institucional da UNL |
| oai_identifier_str | oai:run.unl.pt:10362/178641 |
| organization_str_mv | urn:organizationAcronym:unl |
| person_str_mv | Klem, Maykel dos Santos Abreu, Rodrigo Pinheiro, Tomás Coelho, João Alves, Neri Martins, Rodrigo |
| publishDate | 2024 |
| repo_facet_str | urn:repositoryAcronym:run{{{_:::_}}}Repositório Institucional da UNL |
| reponame_str | Repositório Institucional da UNL |
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| spelling | engenLaser-induced graphene (LIG) is widely used to fabricate microsupercapacitors (MSCs) on various sustainable substrates, such as wood, cork, and lignin. However, the fabrication of MSCs, especially high energy density devices on paper, has rarely been reported. In this work, LIG electrodes are fabricated on wax-coated paper, followed by electrochemical deposition of manganese oxide (MnO2). The obtained LIG/MnO2 supercapacitors exhibit a maximum areal capacitance of 86.9 mF cm−2, while a device with pristine LIG electrodes exhibit a capacitance of 9.1 mF cm−2, both measured at a current density of 0.1 mA cm−2. In addition, the supercapacitor exhibits good cycling stability, retaining 80% of its initial capacitance after 1000 charge/discharge cycles at a current density of 1 mA cm−2. Notably, the LIG/MnO2 supercapacitor exhibits an exceptionally high energy density of 7.3 µWh cm−2 at a power density of 38.8 µW cm−2. In summary, a simple, fast, scalable, reproducible, and energy-efficient fabrication method is represented using electrochemical deposition of manganese oxide on paper-based laser-induced graphene, which are natural, abundant, and sustainable materials, paving the way for large-scale production of environmentally friendly supercapacitors.application/pdfenElectrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density SupercapacitorsKlem, Maykel dos SantosAbreu, RodrigoPinheiro, TomásCoelho, JoãoAlves, NeriMartins, RodrigoCENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)UNINOVA-Instituto de Desenvolvimento de Novas TecnologiasDCM - Departamento de Ciência dos MateriaisJohn Wiley and Sons Inc.HostingInstitutionOrganizationalRUNe-mailmailto:run@unl.ptrun@unl.ptISSNIsPartOf2366-7486URNIsPartOfPURE: 106986003URNIsPartOfPURE UUID: 4664635a-92a2-4abe-9b06-78afe3577576URNIsPartOfScopus: 85199360563URNIsPartOfWOS: 001275290200001DOIIsPartOf10.1002/adsu.2024002542025-02-07T21:14:37Z2024-122024-12-01T00:00:00ZHandlehttp://hdl.handle.net/10362/178641http://purl.org/coar/access_right/c_abf2open accessenergy storagelaser-induced-graphenepaper electronicssupercapacitorsustainable fabricationRenewable Energy, Sustainability and the EnvironmentGeneral Environmental ScienceSDG 7 - Affordable and Clean Energy3458447 bytesFundação para a Ciência e a TecnologiaInstitute of Nanostructures, Nanomodelling and Nanofabrication6817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaInstitute of Nanostructures, Nanomodelling and Nanofabrication6817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaNot AvailableCEEC IND 2018Crossref Funder IDhttp://doi.org/10.13039/501100001871literaturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://run.unl.pt/bitstreams/a9d64370-aba4-4244-b202-073612fd35e5/download |
| spellingShingle | Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors Klem, Maykel dos Santos energy storage laser-induced-graphene paper electronics supercapacitor sustainable fabrication Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy |
| status | SINGLETON |
| subject.fl_str_mv | energy storage laser-induced-graphene paper electronics supercapacitor sustainable fabrication Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy |
| title | Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors |
| title_full | Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors |
| title_fullStr | Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors |
| title_full_unstemmed | Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors |
| title_short | Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors |
| title_sort | Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors |
| topic | energy storage laser-induced-graphene paper electronics supercapacitor sustainable fabrication Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy |
| topic_facet | energy storage laser-induced-graphene paper electronics supercapacitor sustainable fabrication Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy |
| url | http://hdl.handle.net/10362/178641 |
| visible | 1 |