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Investigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloy

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Resumo:This investigation examined the efficacy of Nb₂O₅-based coatings, deposited by using the reactive sputtering technique, on the corrosion and corrosion-fatigue behaviour of 2198-T8 aluminium alloy used as aircraft material. Global corrosion behaviour was accessed by Open Circuit Potential (OCP), Potentiodynamic Polarization curves (PPc) and Electrochemical Impedance Spectroscopy (EIS) techniques in 0.6 mol L⁻1 NaCl solution. Fatigue crack growth (FCG) tests were conducted under controlled loading conditions in both air and saline environments. Comprehensive structural and morphological characterisations were performed using advanced microscopy and spectroscopy techniques, including Atomic Force Microscopy (AFM), Scanning Electron Microscopy/Energy Dispersive X-ray Spectroscopy (SEM/EDX), Raman spectroscopy, Fourier Transform Infrared Spectroscopy (FTIR), and Electron Backscatter Diffraction (EBSD). The results unequivocally demonstrated the protective nature of the coating, significantly enhancing the alloy's durability as evidenced by corrosion and fatigue-corrosion tests. These findings underscore the substantial potential of Nb₂O₅ coatings in extending the service life of 2198-T8 aluminium alloy when subjected to aggressive environments, thereby providing invaluable data for aerospace engineering applications.
Autores principais:Rangel, Uriel Darhê Oudinot Dias
Outros Autores:Ferreira, Murilo Oliveira Alves; Slade, Natália Bueno Leite; Gelamo, Rogério Valentim; Baptista, Carlos Antônio Reis Pereira; Pinto, Haroldo Cavalcanti; Mota, Igor; Koga, Guilherme Yuuki; Águas, Hugo Manuel Brito; Wolf, Witor; Moreto, Jéferson Aparecido
Assunto:Aluminium alloys Corrosion-fatigue Fatigue crack growth rate Niobium coatings Pitting corrosion Reactive sputtering General Materials Science Condensed Matter Physics Mechanics of Materials Mechanical Engineering
Ano:2025
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Universidade Nova de Lisboa
Idioma:inglês
Origem:Repositório Institucional da UNL
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author Rangel, Uriel Darhê Oudinot Dias
author2 Ferreira, Murilo Oliveira Alves
Slade, Natália Bueno Leite
Gelamo, Rogério Valentim
Baptista, Carlos Antônio Reis Pereira
Pinto, Haroldo Cavalcanti
Mota, Igor
Koga, Guilherme Yuuki
Águas, Hugo Manuel Brito
Wolf, Witor
Moreto, Jéferson Aparecido
author2_role author
author
author
author
author
author
author
author
author
author
author_facet Rangel, Uriel Darhê Oudinot Dias
Ferreira, Murilo Oliveira Alves
Slade, Natália Bueno Leite
Gelamo, Rogério Valentim
Baptista, Carlos Antônio Reis Pereira
Pinto, Haroldo Cavalcanti
Mota, Igor
Koga, Guilherme Yuuki
Águas, Hugo Manuel Brito
Wolf, Witor
Moreto, Jéferson Aparecido
author_role author
contributor_name_str_mv DCM - Departamento de Ciência dos Materiais
UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias
CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
Cambridge University Press
RUN
country_str PT
creators_json_txt [{\"Person.name\":\"Rangel, Uriel Darhê Oudinot Dias\"},{\"Person.name\":\"Ferreira, Murilo Oliveira Alves\"},{\"Person.name\":\"Slade, Natália Bueno Leite\"},{\"Person.name\":\"Gelamo, Rogério Valentim\"},{\"Person.name\":\"Baptista, Carlos Antônio Reis Pereira\"},{\"Person.name\":\"Pinto, Haroldo Cavalcanti\"},{\"Person.name\":\"Mota, Igor\"},{\"Person.name\":\"Koga, Guilherme Yuuki\"},{\"Person.name\":\"Águas, Hugo Manuel Brito\"},{\"Person.name\":\"Wolf, Witor\"},{\"Person.name\":\"Moreto, Jéferson Aparecido\"}]
datacite.contributors.contributor.contributorName.fl_str_mv DCM - Departamento de Ciência dos Materiais
UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias
CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
Cambridge University Press
RUN
datacite.creators.creator.creatorName.fl_str_mv Rangel, Uriel Darhê Oudinot Dias
Ferreira, Murilo Oliveira Alves
Slade, Natália Bueno Leite
Gelamo, Rogério Valentim
Baptista, Carlos Antônio Reis Pereira
Pinto, Haroldo Cavalcanti
Mota, Igor
Koga, Guilherme Yuuki
Águas, Hugo Manuel Brito
Wolf, Witor
Moreto, Jéferson Aparecido
datacite.date.Accepted.fl_str_mv 2025-07-31T00:00:00Z
datacite.date.available.fl_str_mv 2025-09-04T21:49:42Z
datacite.date.embargoed.fl_str_mv 2025-09-04T21:49:42Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv Aluminium alloys
Corrosion-fatigue
Fatigue crack growth rate
Niobium coatings
Pitting corrosion
Reactive sputtering
General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
datacite.titles.title.fl_str_mv Investigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloy
dc.contributor.none.fl_str_mv DCM - Departamento de Ciência dos Materiais
UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias
CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
Cambridge University Press
RUN
dc.creator.none.fl_str_mv Rangel, Uriel Darhê Oudinot Dias
Ferreira, Murilo Oliveira Alves
Slade, Natália Bueno Leite
Gelamo, Rogério Valentim
Baptista, Carlos Antônio Reis Pereira
Pinto, Haroldo Cavalcanti
Mota, Igor
Koga, Guilherme Yuuki
Águas, Hugo Manuel Brito
Wolf, Witor
Moreto, Jéferson Aparecido
dc.date.Accepted.fl_str_mv 2025-07-31T00:00:00Z
dc.date.available.fl_str_mv 2025-09-04T21:49:42Z
dc.date.embargoed.fl_str_mv 2025-09-04T21:49:42Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv http://hdl.handle.net/10362/187541
dc.language.none.fl_str_mv eng
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.subject.none.fl_str_mv Aluminium alloys
Corrosion-fatigue
Fatigue crack growth rate
Niobium coatings
Pitting corrosion
Reactive sputtering
General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
dc.title.fl_str_mv Investigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloy
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description This investigation examined the efficacy of Nb₂O₅-based coatings, deposited by using the reactive sputtering technique, on the corrosion and corrosion-fatigue behaviour of 2198-T8 aluminium alloy used as aircraft material. Global corrosion behaviour was accessed by Open Circuit Potential (OCP), Potentiodynamic Polarization curves (PPc) and Electrochemical Impedance Spectroscopy (EIS) techniques in 0.6 mol L⁻1 NaCl solution. Fatigue crack growth (FCG) tests were conducted under controlled loading conditions in both air and saline environments. Comprehensive structural and morphological characterisations were performed using advanced microscopy and spectroscopy techniques, including Atomic Force Microscopy (AFM), Scanning Electron Microscopy/Energy Dispersive X-ray Spectroscopy (SEM/EDX), Raman spectroscopy, Fourier Transform Infrared Spectroscopy (FTIR), and Electron Backscatter Diffraction (EBSD). The results unequivocally demonstrated the protective nature of the coating, significantly enhancing the alloy's durability as evidenced by corrosion and fatigue-corrosion tests. These findings underscore the substantial potential of Nb₂O₅ coatings in extending the service life of 2198-T8 aluminium alloy when subjected to aggressive environments, thereby providing invaluable data for aerospace engineering applications.
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eu_rights_str_mv openAccess
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fulltext.url.fl_str_mv https://run.unl.pt/bitstreams/27dd9a2b-649b-429a-8497-e9c2295f5153/download
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identifier.url.fl_str_mv http://hdl.handle.net/10362/187541
inst_facet_str urn:organizationAcronym:unl{{{_:::_}}}Universidade Nova de Lisboa
instacron_str unl
institution Universidade Nova de Lisboa
instname_str Universidade Nova de Lisboa
language eng
network_acronym_str run
network_name_str Repositório Institucional da UNL
oai_identifier_str oai:run.unl.pt:10362/187541
organization_str_mv urn:organizationAcronym:unl
person_str_mv Rangel, Uriel Darhê Oudinot Dias
Ferreira, Murilo Oliveira Alves
Slade, Natália Bueno Leite
Gelamo, Rogério Valentim
Baptista, Carlos Antônio Reis Pereira
Pinto, Haroldo Cavalcanti
Mota, Igor
Koga, Guilherme Yuuki
Águas, Hugo Manuel Brito
Wolf, Witor
Moreto, Jéferson Aparecido
publishDate 2025
repo_facet_str urn:repositoryAcronym:run{{{_:::_}}}Repositório Institucional da UNL
reponame_str Repositório Institucional da UNL
repository_id_str urn:repositoryAcronym:run
service_str_mv urn:repositoryAcronym:run
spelling engenThis investigation examined the efficacy of Nb₂O₅-based coatings, deposited by using the reactive sputtering technique, on the corrosion and corrosion-fatigue behaviour of 2198-T8 aluminium alloy used as aircraft material. Global corrosion behaviour was accessed by Open Circuit Potential (OCP), Potentiodynamic Polarization curves (PPc) and Electrochemical Impedance Spectroscopy (EIS) techniques in 0.6 mol L⁻1 NaCl solution. Fatigue crack growth (FCG) tests were conducted under controlled loading conditions in both air and saline environments. Comprehensive structural and morphological characterisations were performed using advanced microscopy and spectroscopy techniques, including Atomic Force Microscopy (AFM), Scanning Electron Microscopy/Energy Dispersive X-ray Spectroscopy (SEM/EDX), Raman spectroscopy, Fourier Transform Infrared Spectroscopy (FTIR), and Electron Backscatter Diffraction (EBSD). The results unequivocally demonstrated the protective nature of the coating, significantly enhancing the alloy's durability as evidenced by corrosion and fatigue-corrosion tests. These findings underscore the substantial potential of Nb₂O₅ coatings in extending the service life of 2198-T8 aluminium alloy when subjected to aggressive environments, thereby providing invaluable data for aerospace engineering applications.application/pdfenInvestigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloyRangel, Uriel Darhê Oudinot DiasFerreira, Murilo Oliveira AlvesSlade, Natália Bueno LeiteGelamo, Rogério ValentimBaptista, Carlos Antônio Reis PereiraPinto, Haroldo CavalcantiMota, IgorKoga, Guilherme YuukiÁguas, Hugo Manuel BritoWolf, WitorMoreto, Jéferson AparecidoDCM - Departamento de Ciência dos MateriaisUNINOVA-Instituto de Desenvolvimento de Novas TecnologiasCENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)Cambridge University PressHostingInstitutionOrganizationalRUNe-mailmailto:run@unl.ptrun@unl.ptISSNIsPartOf0884-2914URNIsPartOfPURE: 126779611URNIsPartOfPURE UUID: eb9e06b0-06c6-45a1-9e64-56227514de0cURNIsPartOfScopus: 105012256360DOIIsPartOf10.1557/s43578-025-01631-62025-09-04T21:49:42Z2025-07-312025-07-31T00:00:00ZHandlehttp://hdl.handle.net/10362/187541http://purl.org/coar/access_right/c_abf2open accessAluminium alloysCorrosion-fatigueFatigue crack growth rateNiobium coatingsPitting corrosionReactive sputteringGeneral Materials ScienceCondensed Matter PhysicsMechanics of MaterialsMechanical Engineering10341976 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://run.unl.pt/bitstreams/27dd9a2b-649b-429a-8497-e9c2295f5153/download
spellingShingle Investigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloy
Rangel, Uriel Darhê Oudinot Dias
Aluminium alloys
Corrosion-fatigue
Fatigue crack growth rate
Niobium coatings
Pitting corrosion
Reactive sputtering
General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
status SINGLETON
subject.fl_str_mv Aluminium alloys
Corrosion-fatigue
Fatigue crack growth rate
Niobium coatings
Pitting corrosion
Reactive sputtering
General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
title Investigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloy
title_full Investigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloy
title_fullStr Investigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloy
title_full_unstemmed Investigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloy
title_short Investigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloy
title_sort Investigating the impact of nanostructured Nb2O5-based coating on the corrosion and corrosion-fatigue resistance of 2198-T8 aluminium alloy
topic Aluminium alloys
Corrosion-fatigue
Fatigue crack growth rate
Niobium coatings
Pitting corrosion
Reactive sputtering
General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
topic_facet Aluminium alloys
Corrosion-fatigue
Fatigue crack growth rate
Niobium coatings
Pitting corrosion
Reactive sputtering
General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
url http://hdl.handle.net/10362/187541
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