Publicação
Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by Electroplating
| Resumo: | Abstract This work presents a set of electrochemical techniques applied to investigate the effect of Zn baths with additives on steel surfaces coating by EP. The form and intensity of the reduction in I were analyzed as a function of the applied E, using LSV. In this way, different stages of the EP process involved in Zn deposition on steel surfaces, and the effect of each additive, were identified. First, commercial additives produced by a local company, with highly complex compositions, were studied to understand their Ct effects on the different stages of steel coating in Zn baths by the EP process. Based on the ability to replicate those results, C7H6O2 and Triton X-100, previously reported as brightener and leveler, respectively, were proposed as a simple additive mix. Very strong synergetic effects were present, even in this simplified bath. The effect of different additives Ct on the steel coatings grain size or morphology was also evaluated using SEM images, in the final stage. A correspondence between optimal Ct of the commercial additives and the proposed bath (1 x 10-2 M Triton X-100 and 3 x 10-9 M C7H6O2) was found. Finally, EIS experiments were carried out for the different bath compositions, with this simplified additive mix. The results were interpreted through an equivalent electrical circuit represented by Rct, with two parallel CPE, which evidenced Zn deposits inhomogeneities. |
|---|---|
| Autores principais: | Costa,Cecilia Daniela |
| Outros Autores: | Diz,Virginia E.; González,Graciela Alicia |
| Assunto: | additives in ED C7H6O2 commercial mix chemical speciation EIS EP process LSV SEM Triton X-100 Zn coating |
| Ano: | 2024 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Fundação para a Ciência e Tecnologia |
| Idioma: | inglês |
| Origem: | SciELO Portugal |
| _version_ | 1868442015834832896 |
|---|---|
| author | Costa,Cecilia Daniela |
| author2 | Diz,Virginia E. González,Graciela Alicia |
| author2_role | author author |
| author_facet | Costa,Cecilia Daniela Diz,Virginia E. González,Graciela Alicia |
| author_role | author |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Costa,Cecilia Daniela\"},{\"Person.name\":\"Diz,Virginia E.\"},{\"Person.name\":\"González,Graciela Alicia\"}] |
| datacite.creators.creator.creatorName.fl_str_mv | Costa,Cecilia Daniela Diz,Virginia E. González,Graciela Alicia |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | additives in ED C7H6O2 commercial mix chemical speciation EIS EP process LSV SEM Triton X-100 Zn coating |
| datacite.titles.title.fl_str_mv | Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by Electroplating |
| dc.creator.none.fl_str_mv | Costa,Cecilia Daniela Diz,Virginia E. González,Graciela Alicia |
| dc.format.none.fl_str_mv | text/html |
| dc.identifier.none.fl_str_mv | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042024000400255 |
| dc.language.none.fl_str_mv | eng |
| dc.publisher.none.fl_str_mv | Sociedade Portuguesa de Electroquímica |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.source.none.fl_str_mv | Portugaliae Electrochimica Acta v.42 n.4 2024 |
| dc.subject.none.fl_str_mv | additives in ED C7H6O2 commercial mix chemical speciation EIS EP process LSV SEM Triton X-100 Zn coating |
| dc.title.fl_str_mv | Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by Electroplating |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Abstract This work presents a set of electrochemical techniques applied to investigate the effect of Zn baths with additives on steel surfaces coating by EP. The form and intensity of the reduction in I were analyzed as a function of the applied E, using LSV. In this way, different stages of the EP process involved in Zn deposition on steel surfaces, and the effect of each additive, were identified. First, commercial additives produced by a local company, with highly complex compositions, were studied to understand their Ct effects on the different stages of steel coating in Zn baths by the EP process. Based on the ability to replicate those results, C7H6O2 and Triton X-100, previously reported as brightener and leveler, respectively, were proposed as a simple additive mix. Very strong synergetic effects were present, even in this simplified bath. The effect of different additives Ct on the steel coatings grain size or morphology was also evaluated using SEM images, in the final stage. A correspondence between optimal Ct of the commercial additives and the proposed bath (1 x 10-2 M Triton X-100 and 3 x 10-9 M C7H6O2) was found. Finally, EIS experiments were carried out for the different bath compositions, with this simplified additive mix. The results were interpreted through an equivalent electrical circuit represented by Rct, with two parallel CPE, which evidenced Zn deposits inhomogeneities. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| id | scielopt_9c387fa982e01acbd485041f8ab05824 |
| identifier.url.fl_str_mv | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042024000400255 |
| instacron_str | SciELO |
| institution | Fundação para a Ciência e Tecnologia |
| instname_str | Fundação para a Ciência e Tecnologia |
| language | eng |
| network_acronym_str | scielopt |
| network_name_str | SciELO Portugal |
| oai_identifier_str | oai:scielo:S0872-19042024000400255 |
| organization_str_mv | urn:organizationAcronym:scielo |
| person_str_mv | Costa,Cecilia Daniela Diz,Virginia E. González,Graciela Alicia |
| publishDate | 2024 |
| publisher.none.fl_str_mv | Sociedade Portuguesa de Electroquímica |
| reponame_str | SciELO Portugal |
| repository_id_str | urn:repositoryAcronym:scielopt |
| service_str_mv | urn:repositoryAcronym:scielopt |
| spelling | Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by ElectroplatingCosta,Cecilia DanielaDiz,Virginia E.González,Graciela Aliciaadditives in EDC7H6O2 commercial mixchemical speciationEISEP processLSVSEMTriton X-100Zn coatingopen accesshttp://purl.org/coar/access_right/c_abf2http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042024000400255URLhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042024000400255URLHasVersion2024-08-01Abstract This work presents a set of electrochemical techniques applied to investigate the effect of Zn baths with additives on steel surfaces coating by EP. The form and intensity of the reduction in I were analyzed as a function of the applied E, using LSV. In this way, different stages of the EP process involved in Zn deposition on steel surfaces, and the effect of each additive, were identified. First, commercial additives produced by a local company, with highly complex compositions, were studied to understand their Ct effects on the different stages of steel coating in Zn baths by the EP process. Based on the ability to replicate those results, C7H6O2 and Triton X-100, previously reported as brightener and leveler, respectively, were proposed as a simple additive mix. Very strong synergetic effects were present, even in this simplified bath. The effect of different additives Ct on the steel coatings grain size or morphology was also evaluated using SEM images, in the final stage. A correspondence between optimal Ct of the commercial additives and the proposed bath (1 x 10-2 M Triton X-100 and 3 x 10-9 M C7H6O2) was found. Finally, EIS experiments were carried out for the different bath compositions, with this simplified additive mix. The results were interpreted through an equivalent electrical circuit represented by Rct, with two parallel CPE, which evidenced Zn deposits inhomogeneities.Sociedade Portuguesa de ElectroquímicaPortugaliae Electrochimica Acta v.42 n.4 2024text/htmlengjournal articlehttp://purl.org/coar/resource_type/c_6501literature |
| spellingShingle | Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by Electroplating Costa,Cecilia Daniela additives in ED C7H6O2 commercial mix chemical speciation EIS EP process LSV SEM Triton X-100 Zn coating |
| status | SINGLETON |
| subject.fl_str_mv | additives in ED C7H6O2 commercial mix chemical speciation EIS EP process LSV SEM Triton X-100 Zn coating |
| title | Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by Electroplating |
| title_full | Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by Electroplating |
| title_fullStr | Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by Electroplating |
| title_full_unstemmed | Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by Electroplating |
| title_short | Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by Electroplating |
| title_sort | Electrochemical Study of the Effect of Zinc Baths with Additives on Steel Surfaces Coating by Electroplating |
| topic | additives in ED C7H6O2 commercial mix chemical speciation EIS EP process LSV SEM Triton X-100 Zn coating |
| topic_facet | additives in ED C7H6O2 commercial mix chemical speciation EIS EP process LSV SEM Triton X-100 Zn coating |
| url | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042024000400255 |
| visible | 1 |