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Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HCl

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Resumo:The influence of 2-[3-(2-oxo-2-phenylethylidene)-1,4-dihydroquinoxaline-2(1H)-ylidene]-1-phenylethanone (Qx1) and amino-2-aniline (Diam1) on the corrosion of steel in 1 M HCl solution has been investigated by weight loss measurements, potentiodynamic polarisation and impedance spectroscopy (EIS) methods. The inhibiting action increases with the concentration of Qx1 and Diam1. The highest efficiency (85%) is obtained at the 10-4 M Qx1. There is good agreement between gravimetric and electrochemical methods (potentiodynamic polarisation and EIS). Polarisation measurements also show that Qx1 and Diam1 act as mixed inhibitors. The cathodic curves indicate that the reduction of proton at the steel surface happens with an activating mechanism. Qx1 adsorbs on the steel surface according to Langmuir adsorption model. Effect of temperature is also studied between 308 and 353 K.
Autores principais:Elayyachy,M.
Outros Autores:Hammouti,B.; El Idrissi,A.; Aouniti,A.
Assunto:quinoxaline inhibition corrosion steel acid
Ano:2011
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Fundação para a Ciência e Tecnologia
Idioma:inglês
Origem:SciELO Portugal
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author Elayyachy,M.
author2 Hammouti,B.
El Idrissi,A.
Aouniti,A.
author2_role author
author
author
author_facet Elayyachy,M.
Hammouti,B.
El Idrissi,A.
Aouniti,A.
author_role author
country_str PT
creators_json_txt [{\"Person.name\":\"Elayyachy,M.\"},{\"Person.name\":\"Hammouti,B.\"},{\"Person.name\":\"El Idrissi,A.\"},{\"Person.name\":\"Aouniti,A.\"}]
datacite.creators.creator.creatorName.fl_str_mv Elayyachy,M.
Hammouti,B.
El Idrissi,A.
Aouniti,A.
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv quinoxaline
inhibition
corrosion
steel
acid
datacite.titles.title.fl_str_mv Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HCl
dc.creator.none.fl_str_mv Elayyachy,M.
Hammouti,B.
El Idrissi,A.
Aouniti,A.
dc.format.none.fl_str_mv text/html
dc.identifier.none.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042011000100006
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.source.none.fl_str_mv Portugaliae Electrochimica Acta v.29 n.1 2011
dc.subject.none.fl_str_mv quinoxaline
inhibition
corrosion
steel
acid
dc.title.fl_str_mv Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HCl
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description The influence of 2-[3-(2-oxo-2-phenylethylidene)-1,4-dihydroquinoxaline-2(1H)-ylidene]-1-phenylethanone (Qx1) and amino-2-aniline (Diam1) on the corrosion of steel in 1 M HCl solution has been investigated by weight loss measurements, potentiodynamic polarisation and impedance spectroscopy (EIS) methods. The inhibiting action increases with the concentration of Qx1 and Diam1. The highest efficiency (85%) is obtained at the 10-4 M Qx1. There is good agreement between gravimetric and electrochemical methods (potentiodynamic polarisation and EIS). Polarisation measurements also show that Qx1 and Diam1 act as mixed inhibitors. The cathodic curves indicate that the reduction of proton at the steel surface happens with an activating mechanism. Qx1 adsorbs on the steel surface according to Langmuir adsorption model. Effect of temperature is also studied between 308 and 353 K.
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identifier.url.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042011000100006
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oai_identifier_str oai:scielo:S0872-19042011000100006
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person_str_mv Elayyachy,M.
Hammouti,B.
El Idrissi,A.
Aouniti,A.
publishDate 2011
publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
reponame_str SciELO Portugal
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spelling Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HClElayyachy,M.Hammouti,B.El Idrissi,A.Aouniti,A.quinoxalineinhibitioncorrosionsteelacidopen accesshttp://purl.org/coar/access_right/c_abf2http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042011000100006URLhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042011000100006URLHasVersion2011-01-01The influence of 2-[3-(2-oxo-2-phenylethylidene)-1,4-dihydroquinoxaline-2(1H)-ylidene]-1-phenylethanone (Qx1) and amino-2-aniline (Diam1) on the corrosion of steel in 1 M HCl solution has been investigated by weight loss measurements, potentiodynamic polarisation and impedance spectroscopy (EIS) methods. The inhibiting action increases with the concentration of Qx1 and Diam1. The highest efficiency (85%) is obtained at the 10-4 M Qx1. There is good agreement between gravimetric and electrochemical methods (potentiodynamic polarisation and EIS). Polarisation measurements also show that Qx1 and Diam1 act as mixed inhibitors. The cathodic curves indicate that the reduction of proton at the steel surface happens with an activating mechanism. Qx1 adsorbs on the steel surface according to Langmuir adsorption model. Effect of temperature is also studied between 308 and 353 K.Sociedade Portuguesa de ElectroquímicaPortugaliae Electrochimica Acta v.29 n.1 2011text/htmlengjournal articlehttp://purl.org/coar/resource_type/c_6501literature
spellingShingle Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HCl
Elayyachy,M.
quinoxaline
inhibition
corrosion
steel
acid
status SINGLETON
subject.fl_str_mv quinoxaline
inhibition
corrosion
steel
acid
title Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HCl
title_full Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HCl
title_fullStr Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HCl
title_full_unstemmed Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HCl
title_short Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HCl
title_sort Adsorption and Corrosion Inhibition Behavior of C38 Steel by one Derivative of Quinoxaline in 1 M HCl
topic quinoxaline
inhibition
corrosion
steel
acid
topic_facet quinoxaline
inhibition
corrosion
steel
acid
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042011000100006
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