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Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluids

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Resumo:The dental amalgam is a metallic alloy commonly utilized as a restorative material. In this study, Electrochemical Impedance Spectroscopy, polarisation curves and Mott-Schottky analysis were used to evaluate the physical characteristics of the passive film formed on amalgam surface; X-Ray and UV spectrophotometric analyses were also used to determine the alloy phases and possible soluble corrosion products, respectively. This study was done with Duxalloy® and Tytin® Plus samples in four different electrolytes: Phosphate Buffer Saline, Hank Solution, Artificial Saliva and NaCl 0.9%. In general, the longer the immersion time, the smaller the resistance, possibly due to film breakage; Duxalloy® presented, at the end of 168 h of immersion, a higher resistance when compared to Tytin® Plus. X-Ray analysis showed differences between the two studied brands. UV spectrophotometric analysis demonstrated a small absorption band at ~276 nm. These films kept their protective properties after 168 h of immersion
Autores principais:Alves,V. A.
Outros Autores:Souza,D. G.; Reis,R. Q.; Silva,L. A. da; Rossi,A.
Assunto:Dental amalgams Electrochemical Impedance Spectroscopy Corrosion, Mott-Schottky Polarisation Curves
Ano:2009
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Fundação para a Ciência e Tecnologia
Idioma:inglês
Origem:SciELO Portugal
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author Alves,V. A.
author2 Souza,D. G.
Reis,R. Q.
Silva,L. A. da
Rossi,A.
author2_role author
author
author
author
author_facet Alves,V. A.
Souza,D. G.
Reis,R. Q.
Silva,L. A. da
Rossi,A.
author_role author
country_str PT
creators_json_txt [{\"Person.name\":\"Alves,V. A.\"},{\"Person.name\":\"Souza,D. G.\"},{\"Person.name\":\"Reis,R. Q.\"},{\"Person.name\":\"Silva,L. A. da\"},{\"Person.name\":\"Rossi,A.\"}]
datacite.creators.creator.creatorName.fl_str_mv Alves,V. A.
Souza,D. G.
Reis,R. Q.
Silva,L. A. da
Rossi,A.
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv Dental amalgams
Electrochemical Impedance Spectroscopy
Corrosion, Mott-Schottky
Polarisation Curves
datacite.titles.title.fl_str_mv Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluids
dc.creator.none.fl_str_mv Alves,V. A.
Souza,D. G.
Reis,R. Q.
Silva,L. A. da
Rossi,A.
dc.format.none.fl_str_mv text/html
dc.identifier.none.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0870-83122009000200007
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Sociedade Portuguesa de Materiais
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.source.none.fl_str_mv Ciência & Tecnologia dos Materiais v.21 n.3-4 2009
dc.subject.none.fl_str_mv Dental amalgams
Electrochemical Impedance Spectroscopy
Corrosion, Mott-Schottky
Polarisation Curves
dc.title.fl_str_mv Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluids
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description The dental amalgam is a metallic alloy commonly utilized as a restorative material. In this study, Electrochemical Impedance Spectroscopy, polarisation curves and Mott-Schottky analysis were used to evaluate the physical characteristics of the passive film formed on amalgam surface; X-Ray and UV spectrophotometric analyses were also used to determine the alloy phases and possible soluble corrosion products, respectively. This study was done with Duxalloy® and Tytin® Plus samples in four different electrolytes: Phosphate Buffer Saline, Hank Solution, Artificial Saliva and NaCl 0.9%. In general, the longer the immersion time, the smaller the resistance, possibly due to film breakage; Duxalloy® presented, at the end of 168 h of immersion, a higher resistance when compared to Tytin® Plus. X-Ray analysis showed differences between the two studied brands. UV spectrophotometric analysis demonstrated a small absorption band at ~276 nm. These films kept their protective properties after 168 h of immersion
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person_str_mv Alves,V. A.
Souza,D. G.
Reis,R. Q.
Silva,L. A. da
Rossi,A.
publishDate 2009
publisher.none.fl_str_mv Sociedade Portuguesa de Materiais
reponame_str SciELO Portugal
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spelling Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluidsAlves,V. A.Souza,D. G.Reis,R. Q.Silva,L. A. daRossi,A.Dental amalgamsElectrochemical Impedance SpectroscopyCorrosion, Mott-SchottkyPolarisation Curvesopen accesshttp://purl.org/coar/access_right/c_abf2http://scielo.pt/scielo.php?script=sci_arttext&pid=S0870-83122009000200007URLhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0870-83122009000200007URLHasVersion2009-07-01The dental amalgam is a metallic alloy commonly utilized as a restorative material. In this study, Electrochemical Impedance Spectroscopy, polarisation curves and Mott-Schottky analysis were used to evaluate the physical characteristics of the passive film formed on amalgam surface; X-Ray and UV spectrophotometric analyses were also used to determine the alloy phases and possible soluble corrosion products, respectively. This study was done with Duxalloy® and Tytin® Plus samples in four different electrolytes: Phosphate Buffer Saline, Hank Solution, Artificial Saliva and NaCl 0.9%. In general, the longer the immersion time, the smaller the resistance, possibly due to film breakage; Duxalloy® presented, at the end of 168 h of immersion, a higher resistance when compared to Tytin® Plus. X-Ray analysis showed differences between the two studied brands. UV spectrophotometric analysis demonstrated a small absorption band at ~276 nm. These films kept their protective properties after 168 h of immersionSociedade Portuguesa de MateriaisCiência & Tecnologia dos Materiais v.21 n.3-4 2009text/htmlengjournal articlehttp://purl.org/coar/resource_type/c_6501literature
spellingShingle Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluids
Alves,V. A.
Dental amalgams
Electrochemical Impedance Spectroscopy
Corrosion, Mott-Schottky
Polarisation Curves
status SINGLETON
subject.fl_str_mv Dental amalgams
Electrochemical Impedance Spectroscopy
Corrosion, Mott-Schottky
Polarisation Curves
title Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluids
title_full Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluids
title_fullStr Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluids
title_full_unstemmed Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluids
title_short Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluids
title_sort Electrochemical impedance applied to the corrosion behavior of dental amalgams in synthetic physiological fluids
topic Dental amalgams
Electrochemical Impedance Spectroscopy
Corrosion, Mott-Schottky
Polarisation Curves
topic_facet Dental amalgams
Electrochemical Impedance Spectroscopy
Corrosion, Mott-Schottky
Polarisation Curves
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0870-83122009000200007
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