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Determination of Half-wave Potentials of Selected Chlorophenols

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Resumo:Cyclic voltammetry was used in cetyltrimethylammonium bromide (CTAB) micellar solution to determine the half-wave potentials of selected chlorophenols, CPs. It is observed that all the electrochemical parameters of the studied CPs decrease with an increase in the number of chlorine atom(s) attached to the parent compound. The mathematical relationship between the obtained E1/2 and the number of chlorine atoms in the parent compound is given. The formal potentials, E0', of the CPs are approximated from the obtained half-wave potentials.
Autores principais:Iwunze,M.O.
Outros Autores:Abel,B.
Assunto:cyclic voltammetry half-wave potential formal chlorophenols electrochemical parameters
Ano:2012
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Fundação para a Ciência e Tecnologia
Idioma:inglês
Origem:SciELO Portugal
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author Iwunze,M.O.
author2 Abel,B.
author2_role author
author_facet Iwunze,M.O.
Abel,B.
author_role author
country_str PT
creators_json_txt [{\"Person.name\":\"Iwunze,M.O.\"},{\"Person.name\":\"Abel,B.\"}]
datacite.creators.creator.creatorName.fl_str_mv Iwunze,M.O.
Abel,B.
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv cyclic voltammetry
half-wave
potential
formal
chlorophenols
electrochemical
parameters
datacite.titles.title.fl_str_mv Determination of Half-wave Potentials of Selected Chlorophenols
dc.creator.none.fl_str_mv Iwunze,M.O.
Abel,B.
dc.format.none.fl_str_mv text/html
dc.identifier.none.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042012000500003
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.source.none.fl_str_mv Portugaliae Electrochimica Acta v.30 n.5 2012
dc.subject.none.fl_str_mv cyclic voltammetry
half-wave
potential
formal
chlorophenols
electrochemical
parameters
dc.title.fl_str_mv Determination of Half-wave Potentials of Selected Chlorophenols
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description Cyclic voltammetry was used in cetyltrimethylammonium bromide (CTAB) micellar solution to determine the half-wave potentials of selected chlorophenols, CPs. It is observed that all the electrochemical parameters of the studied CPs decrease with an increase in the number of chlorine atom(s) attached to the parent compound. The mathematical relationship between the obtained E1/2 and the number of chlorine atoms in the parent compound is given. The formal potentials, E0', of the CPs are approximated from the obtained half-wave potentials.
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person_str_mv Iwunze,M.O.
Abel,B.
publishDate 2012
publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
reponame_str SciELO Portugal
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spelling Determination of Half-wave Potentials of Selected ChlorophenolsIwunze,M.O.Abel,B.cyclic voltammetryhalf-wavepotentialformalchlorophenolselectrochemicalparametersopen accesshttp://purl.org/coar/access_right/c_abf2http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042012000500003URLhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042012000500003URLHasVersion2012-09-01Cyclic voltammetry was used in cetyltrimethylammonium bromide (CTAB) micellar solution to determine the half-wave potentials of selected chlorophenols, CPs. It is observed that all the electrochemical parameters of the studied CPs decrease with an increase in the number of chlorine atom(s) attached to the parent compound. The mathematical relationship between the obtained E1/2 and the number of chlorine atoms in the parent compound is given. The formal potentials, E0', of the CPs are approximated from the obtained half-wave potentials.Sociedade Portuguesa de ElectroquímicaPortugaliae Electrochimica Acta v.30 n.5 2012text/htmlengjournal articlehttp://purl.org/coar/resource_type/c_6501literature
spellingShingle Determination of Half-wave Potentials of Selected Chlorophenols
Iwunze,M.O.
cyclic voltammetry
half-wave
potential
formal
chlorophenols
electrochemical
parameters
status SINGLETON
subject.fl_str_mv cyclic voltammetry
half-wave
potential
formal
chlorophenols
electrochemical
parameters
title Determination of Half-wave Potentials of Selected Chlorophenols
title_full Determination of Half-wave Potentials of Selected Chlorophenols
title_fullStr Determination of Half-wave Potentials of Selected Chlorophenols
title_full_unstemmed Determination of Half-wave Potentials of Selected Chlorophenols
title_short Determination of Half-wave Potentials of Selected Chlorophenols
title_sort Determination of Half-wave Potentials of Selected Chlorophenols
topic cyclic voltammetry
half-wave
potential
formal
chlorophenols
electrochemical
parameters
topic_facet cyclic voltammetry
half-wave
potential
formal
chlorophenols
electrochemical
parameters
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042012000500003
visible 1