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Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HCl

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Resumo:A few 1-aryl-2,5-dithiohydrazodicarbonamides and their triphenyltin and dibutyltin complexes have been studied as corrosion inhibitors for mild steel in dimethyl sulphoxide containing HCl at 25 ºC using electrochemical polarisation technique. Among dithiohydrazodicarbonamides, ethoxyphenyl derivative exhibited maximum inhibition efficiency (IE) followed by benzyl and phenyl analogues. The same order of IE was observed in their corresponding organotin complexes; however, IE of a complex was found to be significantly higher than that of the constituents ligand. All organotin complexes behaved predominantly as cathodic inhibitors. Triphenyltin complexes proved to be better corrosion inhibitors than their dibutyltin analogues.
Autores principais:Rastogi,R.B.
Outros Autores:Singh,M.M.; Singh,K.; Yadav,M.
Assunto:Organotin dithiohydrazodicarbonamides corrosion inhibitors mild steel-DMSO HCl
Ano:2005
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Fundação para a Ciência e Tecnologia
Idioma:inglês
Origem:SciELO Portugal
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author Rastogi,R.B.
author2 Singh,M.M.
Singh,K.
Yadav,M.
author2_role author
author
author
author_facet Rastogi,R.B.
Singh,M.M.
Singh,K.
Yadav,M.
author_role author
country_str PT
creators_json_txt [{\"Person.name\":\"Rastogi,R.B.\"},{\"Person.name\":\"Singh,M.M.\"},{\"Person.name\":\"Singh,K.\"},{\"Person.name\":\"Yadav,M.\"}]
datacite.creators.creator.creatorName.fl_str_mv Rastogi,R.B.
Singh,M.M.
Singh,K.
Yadav,M.
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv Organotin dithiohydrazodicarbonamides
corrosion inhibitors
mild steel-DMSO
HCl
datacite.titles.title.fl_str_mv Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HCl
dc.creator.none.fl_str_mv Rastogi,R.B.
Singh,M.M.
Singh,K.
Yadav,M.
dc.format.none.fl_str_mv text/html
dc.identifier.none.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042005000200008
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.source.none.fl_str_mv Portugaliae Electrochimica Acta v.23 n.2 2005
dc.subject.none.fl_str_mv Organotin dithiohydrazodicarbonamides
corrosion inhibitors
mild steel-DMSO
HCl
dc.title.fl_str_mv Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HCl
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description A few 1-aryl-2,5-dithiohydrazodicarbonamides and their triphenyltin and dibutyltin complexes have been studied as corrosion inhibitors for mild steel in dimethyl sulphoxide containing HCl at 25 ºC using electrochemical polarisation technique. Among dithiohydrazodicarbonamides, ethoxyphenyl derivative exhibited maximum inhibition efficiency (IE) followed by benzyl and phenyl analogues. The same order of IE was observed in their corresponding organotin complexes; however, IE of a complex was found to be significantly higher than that of the constituents ligand. All organotin complexes behaved predominantly as cathodic inhibitors. Triphenyltin complexes proved to be better corrosion inhibitors than their dibutyltin analogues.
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person_str_mv Rastogi,R.B.
Singh,M.M.
Singh,K.
Yadav,M.
publishDate 2005
publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
reponame_str SciELO Portugal
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spelling Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HClRastogi,R.B.Singh,M.M.Singh,K.Yadav,M.Organotin dithiohydrazodicarbonamidescorrosion inhibitorsmild steel-DMSOHClopen accesshttp://purl.org/coar/access_right/c_abf2http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042005000200008URLhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042005000200008URLHasVersion2005-01-01A few 1-aryl-2,5-dithiohydrazodicarbonamides and their triphenyltin and dibutyltin complexes have been studied as corrosion inhibitors for mild steel in dimethyl sulphoxide containing HCl at 25 ºC using electrochemical polarisation technique. Among dithiohydrazodicarbonamides, ethoxyphenyl derivative exhibited maximum inhibition efficiency (IE) followed by benzyl and phenyl analogues. The same order of IE was observed in their corresponding organotin complexes; however, IE of a complex was found to be significantly higher than that of the constituents ligand. All organotin complexes behaved predominantly as cathodic inhibitors. Triphenyltin complexes proved to be better corrosion inhibitors than their dibutyltin analogues.Sociedade Portuguesa de ElectroquímicaPortugaliae Electrochimica Acta v.23 n.2 2005text/htmlengjournal articlehttp://purl.org/coar/resource_type/c_6501literature
spellingShingle Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HCl
Rastogi,R.B.
Organotin dithiohydrazodicarbonamides
corrosion inhibitors
mild steel-DMSO
HCl
status SINGLETON
subject.fl_str_mv Organotin dithiohydrazodicarbonamides
corrosion inhibitors
mild steel-DMSO
HCl
title Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HCl
title_full Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HCl
title_fullStr Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HCl
title_full_unstemmed Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HCl
title_short Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HCl
title_sort Organotin Dithiohydrazodicarbonamides as Corrosion Inhibitors for Mild Steel-Dimethyl Sulphoxide Containing HCl
topic Organotin dithiohydrazodicarbonamides
corrosion inhibitors
mild steel-DMSO
HCl
topic_facet Organotin dithiohydrazodicarbonamides
corrosion inhibitors
mild steel-DMSO
HCl
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042005000200008
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