Detalhes bibliográficos
| Resumo: | This work reports the utilization of a multi-detector size chromatography for the characterization of poly(vinyl chloride) (PVC) resins prepared by suspension polymerization in the range of temperatures between 21 and 75 °C. The chromatography equipment offers the possibility of analyzing the samples in terms of their absolute molecular mass using a combination of three detectors (TriSEC): right angle light scattering (RALLS), a differential viscometer (DV) and refractive index (RI). The PVC resins were fully characterized concerning the molecular weight distribution (MWD), its dependence with intrinsic viscosity ([eta]) and molecular sizes (radius of gyration, Rg and hydrodynamic radius, Rh). Additionally, it is also presented the characterization of polystyrene narrow standards serving as reference polymers. |
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| Autores principais: | Coelho, Jorge F. J. |
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| Outros Autores: | Coelho, Jorge; Coelho, Jorge; Coelho, Jorge; Coelho, Jorge Fernando Jordão; Coelho, Jorge F. J.; CEMMPRE - Centre for Mechanical Engineering, Materials and Processes; CEMMPRE - Centre for Mechanical Engineering, Materials and Processes; research; jcoelho@eq.uc.pt; 0000-0001-9351-1704; 7101841069; staff; Gonçalves, Pedro M. F. O.; Gonçalves, Pedro M. O. F; Miranda, Dionísio; Miranda, Dionísio; Gil, M. H.; Gil, Maria Helena |
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| Assunto: | Multi-detector size exclusion chromatography |
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| Ano: | 2006 |
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| País: | Portugal |
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| Tipo de documento: | artigo |
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| Tipo de acesso: | acesso aberto |
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| Instituição associada: | Universidade de Coimbra |
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| Idioma: | inglês |
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| Origem: | Estudo Geral - Universidade de Coimbra |
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