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Re-crystallization of MNA under a strong dc electric field

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Detalhes bibliográficos
Resumo:Crystals of 2-methyl-4-nitroaniline were grown from solution while subjected to a dc electric field of 9.8×10[exponent4] Vm−1. This resulted in an alteration of the unit cell lattice parameters while the space group was modified from Cc to one of its subgroups Pc. The modified crystals display an increased second harmonic generation efficiency accompanied by a decrease in the dielectric permittivity as well as changes in the internal and external vibrational modes.
Autores principais:Nogueira, Elisabete Maria da Silva Marques
Outros Autores:Gomes, E. Matos; Belsley, M.; Lanceros-Méndez, S.; Cunha, José Maria Cerqueira; Criado Vega, Alberto; Mano, J. F.
Assunto:Organic compounds Crystal growth Nonlinear optical materials
Ano:2001
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso restrito
Instituição associada:Universidade do Minho
Idioma:inglês
Origem:RepositóriUM - Universidade do Minho
Descrição
Resumo:Crystals of 2-methyl-4-nitroaniline were grown from solution while subjected to a dc electric field of 9.8×10[exponent4] Vm−1. This resulted in an alteration of the unit cell lattice parameters while the space group was modified from Cc to one of its subgroups Pc. The modified crystals display an increased second harmonic generation efficiency accompanied by a decrease in the dielectric permittivity as well as changes in the internal and external vibrational modes.