Publicação
Radical-type reactions in protic and aprotic media : comparisons in nickel-catalysed electrochemical reductive cyclisations
| Resumo: | The electrochemical reductive cyclisation of unsaturated organic halides in the presence of Ni(II) complexes as catalysts was examined in aprotic solvents such as DMF and in protic solvents such as ethanol, butanol or ethanolewater mixtures. The presence of the alcohol media enhanced the rate of recycling of the catalytic species. |
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| Autores principais: | Dunach, E. |
| Outros Autores: | Esteves, Ana Paula; Medeiros, Maria José; Neves, C. S. S.; Olivero, S. |
| Assunto: | Electrosynthesis Ethanol Cyclisation Radical Nickel Tetrahydrofuran |
| Ano: | 2009 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Universidade do Minho |
| Idioma: | inglês |
| Origem: | RepositóriUM - Universidade do Minho |
| Resumo: | The electrochemical reductive cyclisation of unsaturated organic halides in the presence of Ni(II) complexes as catalysts was examined in aprotic solvents such as DMF and in protic solvents such as ethanol, butanol or ethanolewater mixtures. The presence of the alcohol media enhanced the rate of recycling of the catalytic species. |
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