Detalhes bibliográficos
| Resumo: | Poly(oxyethylene)(POE/siloxane-based materials incorporating magnesium triflate were prepared by the sol-gel process. The host Class II hybrid matrix (di-ureasil) employed was composed of a siliceous framework to which short POE chains were covalently bonded through urea linkages. Ormolytes with salt composition ranging from 500 to 1 were characterised. The nanohybrid with n = 20, thermally stable up to 360ºC, exhibited the highest ionic conductivity. The electrochemical stability of this material was found to span -3 to +2 volts. |
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| Autores principais: | Nunes, Sílvia |
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| Outros Autores: | Zea Bermudez, V. de; Silva, Maria Manuela; Barros, Sandra Cerqueira; Smith, Michael John; Morales, Enrique; Rocha, João; Carlos, Luís |
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| Assunto: | Di-ureasil Complex impedance Cyclic voltammetry Sol-gel Magnesium triflate |
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| Ano: | 2005 |
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| País: | Portugal |
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| Tipo de documento: | artigo |
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| Tipo de acesso: | acesso aberto |
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| Instituição associada: | Universidade do Minho |
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| Idioma: | inglês |
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| Origem: | RepositóriUM - Universidade do Minho |
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