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Performance of self-cleaning cotton textiles coated with TiO2, TiO2-SiO2 and TiO2-SiO2-HY in removing Rhodamine B and Reactive Red 120 dyes from aqueous solutions

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Detalhes bibliográficos
Resumo:In the present study composites based on TiO(2 )nanoparticles, SiO2 and HY zeolite were synthesized by using a standard sol-gel methodology and analyzed by Fourier-transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy-energy-dispersive X-ray spectroscopy techniques. The photocatalysts were impregnated on cotton textiles and their photocatalytic abilities were examined by degradation of Rhodamine B (RhB) and Reactive Red 120 (RR120) dyes in aqueous solution under similar solar irradiation. RhB removal efficiencies from cotton textiles were 87%, 72% and 50% for TiO2, TiO2-SiO2-HY zeolite and TiO2-SiO2 composites, respectively and achieved after 3 h of light irradiation. However, for the RR120 dye, the reached result was different as the photodegradation for this dye (65% efficiency) was only observed in bare TiO2 functionalized textile. In addition, for the treatment with TiO2-SiO2-HY zeolite, it was found that for initial alkaline conditions at pH of the RhB dye solution, the photodegradation rate decreased.
Autores principais:Landi Jr, Salmon
Outros Autores:Carneiro, Joaquim A. O.; Parpot, Pier; Soares, Olivia S. G. P.; Pereira, Manuel F. R.; Fonseca, António M.; Neves, Isabel C.
Assunto:TiO2 Photocatalysis Environmental remediation RhB dye Reactive Red 120 dye TiO TiO , Photocatalysis 2 TiO2, Photocatalysis Photocatalysis 2
Ano:2021
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso restrito
Instituição associada:Universidade do Minho
Idioma:inglês
Origem:RepositóriUM - Universidade do Minho
Descrição
Resumo:In the present study composites based on TiO(2 )nanoparticles, SiO2 and HY zeolite were synthesized by using a standard sol-gel methodology and analyzed by Fourier-transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy-energy-dispersive X-ray spectroscopy techniques. The photocatalysts were impregnated on cotton textiles and their photocatalytic abilities were examined by degradation of Rhodamine B (RhB) and Reactive Red 120 (RR120) dyes in aqueous solution under similar solar irradiation. RhB removal efficiencies from cotton textiles were 87%, 72% and 50% for TiO2, TiO2-SiO2-HY zeolite and TiO2-SiO2 composites, respectively and achieved after 3 h of light irradiation. However, for the RR120 dye, the reached result was different as the photodegradation for this dye (65% efficiency) was only observed in bare TiO2 functionalized textile. In addition, for the treatment with TiO2-SiO2-HY zeolite, it was found that for initial alkaline conditions at pH of the RhB dye solution, the photodegradation rate decreased.