Publicação
Nickel-catalyzed electrochemical carboxylation of allylic acetates and carbonates
| Resumo: | The electrochemical carboxylation of a series of allylic acetates and carbonates was carried out in the presence of CO2 under atmospheric pressure, with a catalytic amount of nickel-bipyridine complex, to afford the corresponding beta,gama-unsaturated carboxylic acids. In the absence of nickel catalyst, alcohols were obtained. |
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| Autores principais: | Medeiros, Maria José |
| Outros Autores: | Pintaric, C.; Olivero, S.; Duñach, E. |
| Assunto: | Carboxylation Allylic acetates Carboxylic acids Carbon dioxide Electrosynthesis |
| Ano: | 2011 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso restrito |
| Instituição associada: | Universidade do Minho |
| Idioma: | inglês |
| Origem: | RepositóriUM - Universidade do Minho |
| Resumo: | The electrochemical carboxylation of a series of allylic acetates and carbonates was carried out in the presence of CO2 under atmospheric pressure, with a catalytic amount of nickel-bipyridine complex, to afford the corresponding beta,gama-unsaturated carboxylic acids. In the absence of nickel catalyst, alcohols were obtained. |
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