Publicação
Tailoring the electrical response of polyvinylidene fluoride nanocomposites with electrically conductive and dielectric fillers
| Resumo: | Polymer-based composites combining the flexibility, low density, and processability of the matrix with the tailored functional performance provided by the fillers are also particularly suitable for large area, flexible, and printable applications. Herein, polyvinylidene fluoride (PVDF) composites with conductive graphene nanoplatelets (G-NPL) and high-dielectric constant ceramics, including barium and strontium titanate (BT and SrT), have been developed to achieve electrically conductive and high-dielectric response materials, respectively. Flexible composites reinforced with 45 wt% ceramic content lead to a dielectric constant of ε´ = 33 and 25 for BT and SrT, respectively, 6 and 4 times higher than for pristine PVDF. Further, the inclusion of G-NPL allows for the development of highly conductive composites with a maximum conductivity of 5.5 × 10−2 (Ω.m)−1 for a 5 wt% filler content, 10 orders of magnitude larger than PVDF. The G-NPL and ceramic in optimized contents in PVDF tricomposites do not enhance the dielectric properties compared to PVDF-ceramic composites. Theoretical analysis has been used to determine the critical percolation threshold of the PVDF/G-NPL, which occurs at (Formula presented.) 0.6 wt% G-NPL content with a critical exponent of t = 2.49 and to describe the dielectric properties of the composites, allowing to further tailor materials responses for specific application needs. |
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| Autores principais: | Marinho, Tiago André Rodrigues |
| Outros Autores: | Tubio, Carmen Rial; Lanceros-Mendez, S.; Costa, Pedro Filipe Ribeiro |
| Assunto: | Dielectric materials Polymer composites Smart and functional materials Theoretical modeling |
| Ano: | 2024 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso restrito |
| Instituição associada: | Universidade do Minho |
| Idioma: | inglês |
| Origem: | RepositóriUM - Universidade do Minho |
| Resumo: | Polymer-based composites combining the flexibility, low density, and processability of the matrix with the tailored functional performance provided by the fillers are also particularly suitable for large area, flexible, and printable applications. Herein, polyvinylidene fluoride (PVDF) composites with conductive graphene nanoplatelets (G-NPL) and high-dielectric constant ceramics, including barium and strontium titanate (BT and SrT), have been developed to achieve electrically conductive and high-dielectric response materials, respectively. Flexible composites reinforced with 45 wt% ceramic content lead to a dielectric constant of ε´ = 33 and 25 for BT and SrT, respectively, 6 and 4 times higher than for pristine PVDF. Further, the inclusion of G-NPL allows for the development of highly conductive composites with a maximum conductivity of 5.5 × 10−2 (Ω.m)−1 for a 5 wt% filler content, 10 orders of magnitude larger than PVDF. The G-NPL and ceramic in optimized contents in PVDF tricomposites do not enhance the dielectric properties compared to PVDF-ceramic composites. Theoretical analysis has been used to determine the critical percolation threshold of the PVDF/G-NPL, which occurs at (Formula presented.) 0.6 wt% G-NPL content with a critical exponent of t = 2.49 and to describe the dielectric properties of the composites, allowing to further tailor materials responses for specific application needs. |
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