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Synthesis and reactivity of photochromic 2H-chromenes based on 3-carboxylated coumarins

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Detalhes bibliográficos
Resumo:New photochromic 2H-chromenes including a 3-carboxylated coumarin nucleus were synthesised from hydroxycoumarins, and, in one case, the corrresponding trimethoxysilylcarboxamide was prepared. The photochromic behaviour was studied under flash photolysis conditions. The introduction of electron-withdrawing substituents in this position of the coumarin nucleus led to a global and significant bathochromic shift in the spectra of the open forms and to an interesting intensification in the colorability.
Autores principais:Cerqueira, N. M. F. S. A.
Outros Autores:Rodrigues, Lígia M.; Campos, Ana M. F. Oliveira; Carvalho, Luís H. Melo de; Coelho, Paulo J.; Dubest, Roger; Aubard, Jean; Samat, André; Guglielmetti, Robert J.
Assunto:Photochromic Carboxylated coumarins 2H-chromenes Benzopyrans
Ano:2003
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Universidade do Minho
Idioma:inglês
Origem:RepositóriUM - Universidade do Minho
Descrição
Resumo:New photochromic 2H-chromenes including a 3-carboxylated coumarin nucleus were synthesised from hydroxycoumarins, and, in one case, the corrresponding trimethoxysilylcarboxamide was prepared. The photochromic behaviour was studied under flash photolysis conditions. The introduction of electron-withdrawing substituents in this position of the coumarin nucleus led to a global and significant bathochromic shift in the spectra of the open forms and to an interesting intensification in the colorability.