Publicação
Shape-controlled monolayer MoSe2 flakes by chemical vapor deposition towards tuning the photoluminescence emission
| Resumo: | In this study, we report on the controllable chemical vapor deposition (CVD) synthesis of monolayer MoSe2 flakes with different shapes such as hexagons, triangles, sawtooth hexagons, dendrites and fractals deposited on SiO2/Si substrates. This broad range of morphologies is due to the change in the vapor composition resulting from the confinement of the MoO3 and Se vapor and to the variation in the growth rate of the variable shaped MoSe2 crystals. It is also revealed that the photoluminescence (PL) response of the MoSe2 flakes is strongly affected by their shape and size. Our findings will open new avenues towards achieving morphology-controlled monolayer MoSe2 flakes for optoelectronic and energy harvesting systems. |
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| Autores principais: | González, C. |
| Outros Autores: | Silva, José Pedro Basto; Viana, A. S.; Gwozdz, K.; Conde, O. |
| Assunto: | Transition metal dichalcogenides Chemical vapor deposition MoSe2 monolayer Morphology control MoSe monolayer 2 |
| Ano: | 2022 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Universidade do Minho |
| Idioma: | inglês |
| Origem: | RepositóriUM - Universidade do Minho |
| Resumo: | In this study, we report on the controllable chemical vapor deposition (CVD) synthesis of monolayer MoSe2 flakes with different shapes such as hexagons, triangles, sawtooth hexagons, dendrites and fractals deposited on SiO2/Si substrates. This broad range of morphologies is due to the change in the vapor composition resulting from the confinement of the MoO3 and Se vapor and to the variation in the growth rate of the variable shaped MoSe2 crystals. It is also revealed that the photoluminescence (PL) response of the MoSe2 flakes is strongly affected by their shape and size. Our findings will open new avenues towards achieving morphology-controlled monolayer MoSe2 flakes for optoelectronic and energy harvesting systems. |
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