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Poly(vinylidene fluoride-trifluoroethylene) (72/28) interconnected porous membranes obtained by crystallization from solution

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Resumo:Electroactive macroporous poly[(vinylidene fluoride)-co-trifluoroethylene] mambranes membranes have been processed by solvent evaporation at room temperature with different polymer/solvent concentrations. The pore architecture consists of on an interconnected spherical pores and this morphology is independent of the membrane thickness. The porosity of the produced membranes increases from 57% for the higher polymer concentration in the polymer/solvent solution (15/85), up to 83% for the lowest polymer amount in the polymer/solvent solution. Far infrared and differential scanning calorimetry measurements reveal that the polymer crystallizes in the ferroelectric phase and the polymer/solvent ratio does n’t not changes the Curie transition and the melting temperature of the polymer.
Autores principais:Ferreira, Armando José Barros
Outros Autores:Silva, Jaime; Sencadas, Vítor João Gomes Silva; Gómez Ribelles, J. L.; Lanceros-Méndez, S.
Assunto:Biomaterial Polymer Ferroelectric
Ano:2011
País:Portugal
Tipo de documento:comunicação em conferência
Tipo de acesso:acesso aberto
Instituição associada:Universidade do Minho
Idioma:inglês
Origem:RepositóriUM - Universidade do Minho
Descrição
Resumo:Electroactive macroporous poly[(vinylidene fluoride)-co-trifluoroethylene] mambranes membranes have been processed by solvent evaporation at room temperature with different polymer/solvent concentrations. The pore architecture consists of on an interconnected spherical pores and this morphology is independent of the membrane thickness. The porosity of the produced membranes increases from 57% for the higher polymer concentration in the polymer/solvent solution (15/85), up to 83% for the lowest polymer amount in the polymer/solvent solution. Far infrared and differential scanning calorimetry measurements reveal that the polymer crystallizes in the ferroelectric phase and the polymer/solvent ratio does n’t not changes the Curie transition and the melting temperature of the polymer.