Detalhes bibliográficos
| Resumo: | Biogas upgrading is a key operation for transforming raw biogas into valuable biomethane that can be used as fuel or transported through pipelines. Pressure swing adsorption (PSA) is one possible technique that can be used for upgrading. ZSM-5 with high silica/aluminum (Si/Al) ratio has a reasonable CO2/CH4 selectivity and an almost linear CO2 adsorption isotherm, which can reduce power consumption. Extrusion of zeolites uses Al-based binders which can result in a denaturation and in a decrease of Si/Al ratio, promoting a steeper CO2 isotherm and also impacting the water adsorption. In this work, we have extruded a ZSM-5 (with a Si/Al = 200) using only silica-based binder. Different samples were obtained using different extrusion paste compositions and operating conditions and their textural properties characterized. The mechanical strength of the samples as well as the CO2, CH4, and H2O adsorption equilibrium isotherms at 303–343 K were measured. Our results show that it is possible to produce extrudates with mechanical resistance comparable to (or higher than) commercial zeolite materials with surface area reductions lower than 10% and little or no impact on the CO2/CH4 selectivity. |
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| Autores principais: | Almeida, Ana |
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| Outros Autores: | Ribeiro, Rui P. P. L.; Mota, José P. B.; Grande, Carlos |
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| Assunto: | Adsorption Biogas upgrading Extrusion Shaping Zeolite ZSM-5 Renewable Energy, Sustainability and the Environment Energy Engineering and Power Technology Energy (miscellaneous) Control and Optimization Electrical and Electronic Engineering SDG 7 - Affordable and Clean Energy |
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| Ano: | 2020 |
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| País: | Portugal |
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| Tipo de documento: | artigo |
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| Tipo de acesso: | acesso aberto |
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| Instituição associada: | Universidade Nova de Lisboa |
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| Idioma: | inglês |
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| Origem: | Repositório Institucional da UNL |
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