Publicação
Experimental and Theoretical Studies of the Corrosion Inhibition of 4-amino-2-(4-chlorophenyl)-8-(2, 3-dimethoxyphenyl)-6-oxo-2, 6-dihydropyrimido [2, 1-b][1, 3] thiazine-3,7-dicarbonitrile on Carbon Steel in a 1.0 M HCl Solution
| Resumo: | The corrosion inhibition of carbon steel in a 1.0 M HCl solution, using 4-amino-2-(4 chlorophenyl)-8-(2,3-dimethoxyphenyl)-6-oxo-2,6-dihydropyrimido [2,1b] [1,3] thiazine- 3,7-dicarbonitrile (ACMPT) was investigated by weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and quantum chemical calculations. Polarization curves indicate that the studied compound was acting as a mixed inhibitor with predominant cathodic effectiveness. The inhibition efficiency decreased with an increased temperature, and the thermodynamic and activation parameters obtained from this study were discussed. The adsorption behavior of ACMT follows Langmuir's isotherm. In addition, Density Function Theory (DFT) calculations were performed on the studied molecule. The theoretical parameters obtained from this method are in good agreement with the experimental results. |
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| Autores principais: | Serrar,H. |
| Outros Autores: | Larouj,M.; Gaz,H. L.; Benzekri,Z.; Zarguil,A.; Essebaai,H.; Boukhris,S.; Oudda,H.; Salghi,R.; Hassikou,A.; Souizi,A. |
| Assunto: | pyrimidothiazine carbon steel corrosion inhibition theoretical studies DFT |
| Ano: | 2018 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Fundação para a Ciência e Tecnologia |
| Idioma: | inglês |
| Origem: | SciELO Portugal |
| Resumo: | The corrosion inhibition of carbon steel in a 1.0 M HCl solution, using 4-amino-2-(4 chlorophenyl)-8-(2,3-dimethoxyphenyl)-6-oxo-2,6-dihydropyrimido [2,1b] [1,3] thiazine- 3,7-dicarbonitrile (ACMPT) was investigated by weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and quantum chemical calculations. Polarization curves indicate that the studied compound was acting as a mixed inhibitor with predominant cathodic effectiveness. The inhibition efficiency decreased with an increased temperature, and the thermodynamic and activation parameters obtained from this study were discussed. The adsorption behavior of ACMT follows Langmuir's isotherm. In addition, Density Function Theory (DFT) calculations were performed on the studied molecule. The theoretical parameters obtained from this method are in good agreement with the experimental results. |
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