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VALORIZATION OF GLYCEROL INTO BIOFUEL ADDITIVES HETEROPOLYACIDS SUPPORTED IN ACID SOLIDS

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Detalhes bibliográficos
Resumo:Tungstosilicic acid (SiW) immobilized in silica with different amount has got high catalytic activity for the acetalisation of glycerol with butanal. The SiW2-S catalysts showed the highest catalytic activity. All catalysts showed high values of selectivity to five-member ring acetal (about 80-83%). PW2-S showed good catalytic stability. After the forth use, it was observed that the catalytic activity decreased about 6 % of its initial value.
Autores principais:Santos, F
Outros Autores:Farinha, J; Castanheiro, J
Assunto:Biodiesel Glycerol acetalisation heteropolyacids
Ano:2016
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso restrito
Instituição associada:Universidade de Évora
Idioma:português
Origem:Repositório Científico da Universidade de Évora
Descrição
Resumo:Tungstosilicic acid (SiW) immobilized in silica with different amount has got high catalytic activity for the acetalisation of glycerol with butanal. The SiW2-S catalysts showed the highest catalytic activity. All catalysts showed high values of selectivity to five-member ring acetal (about 80-83%). PW2-S showed good catalytic stability. After the forth use, it was observed that the catalytic activity decreased about 6 % of its initial value.