Publicação
Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatus
| Resumo: | Three labdane diterpenoids were isolated from an acetone extract of Plectranthus ornatus. Their structures, closely related to that of forskolin, were determined by NMR studies. Unambiguous and complete assignments of the H-1 and C-13 NMR chemical shifts for these substances are presented. The assignments are based on 2D shift-correlated [H-1,H-1-COSY,H-1,C-13-gHSQC-(1)J (C,H), H-1, C-13-gHMBC-(n)J (C,H) (n = 2 and 3)] and NOE experiments. Copyright (c) 2005 John Wiley & Sons, Ltd. |
|---|---|
| Autores principais: | Rijo, P |
| Outros Autores: | Simoes, MF; Rodriguez, B |
| Assunto: | Chemistry, Multidisciplinary Chemistry, Physical Spectroscopy |
| Ano: | 2005 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso a metadados |
| Instituição associada: | Universidade de Lisboa |
| Idioma: | inglês |
| Origem: | Repositório da Universidade de Lisboa |
| _version_ | 1866810675758628864 |
|---|---|
| author | Rijo, P |
| author2 | Simoes, MF Rodriguez, B |
| author2_role | author author |
| author_facet | Rijo, P Simoes, MF Rodriguez, B |
| author_role | author |
| contributor_name_str_mv | Repositório Científico de Acesso Aberto da ULisboa |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Rijo, P\"},{\"Person.name\":\"Simoes, MF\"},{\"Person.name\":\"Rodriguez, B\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | Repositório Científico de Acesso Aberto da ULisboa |
| datacite.creators.creator.creatorName.fl_str_mv | Rijo, P Simoes, MF Rodriguez, B |
| datacite.date.Accepted.fl_str_mv | 2005-01-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2015-12-30T10:18:02Z |
| datacite.date.embargoed.fl_str_mv | 2015-12-30T10:18:02Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_14cb |
| datacite.subjects.subject.fl_str_mv | Chemistry, Multidisciplinary Chemistry, Physical Spectroscopy |
| datacite.titles.title.fl_str_mv | Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatus |
| dc.contributor.none.fl_str_mv | Repositório Científico de Acesso Aberto da ULisboa |
| dc.creator.none.fl_str_mv | Rijo, P Simoes, MF Rodriguez, B |
| dc.date.Accepted.fl_str_mv | 2005-01-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2015-12-30T10:18:02Z |
| dc.date.embargoed.fl_str_mv | 2015-12-30T10:18:02Z |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/10451/21374 |
| dc.language.none.fl_str_mv | eng |
| dc.publisher.none.fl_str_mv | JOHN WILEY & SONS LTD |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_14cb |
| dc.subject.none.fl_str_mv | Chemistry, Multidisciplinary Chemistry, Physical Spectroscopy |
| dc.title.fl_str_mv | Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatus |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Three labdane diterpenoids were isolated from an acetone extract of Plectranthus ornatus. Their structures, closely related to that of forskolin, were determined by NMR studies. Unambiguous and complete assignments of the H-1 and C-13 NMR chemical shifts for these substances are presented. The assignments are based on 2D shift-correlated [H-1,H-1-COSY,H-1,C-13-gHSQC-(1)J (C,H), H-1, C-13-gHMBC-(n)J (C,H) (n = 2 and 3)] and NOE experiments. Copyright (c) 2005 John Wiley & Sons, Ltd. |
| dirty | 0 |
| eu_rights_str_mv | metadataOnlyAccess |
| format | article |
| id | ul_9ca05210abbec9d023ef2b0dfd72f9c9 |
| identifier.url.fl_str_mv | http://hdl.handle.net/10451/21374 |
| instacron_str | ul |
| institution | Universidade de Lisboa |
| instname_str | Universidade de Lisboa |
| language | eng |
| network_acronym_str | ul |
| network_name_str | Repositório da Universidade de Lisboa |
| oai_identifier_str | oai:repositorio.ulisboa.pt:10451/21374 |
| organization_str_mv | urn:organizationAcronym:ul |
| person_str_mv | Rijo, P Simoes, MF Rodriguez, B |
| publishDate | 2005 |
| publisher.none.fl_str_mv | JOHN WILEY & SONS LTD |
| reponame_str | Repositório da Universidade de Lisboa |
| repository_id_str | urn:repositoryAcronym:ul |
| service_str_mv | urn:repositoryAcronym:ul |
| spelling | engJOHN WILEY & SONS LTDThree labdane diterpenoids were isolated from an acetone extract of Plectranthus ornatus. Their structures, closely related to that of forskolin, were determined by NMR studies. Unambiguous and complete assignments of the H-1 and C-13 NMR chemical shifts for these substances are presented. The assignments are based on 2D shift-correlated [H-1,H-1-COSY,H-1,C-13-gHSQC-(1)J (C,H), H-1, C-13-gHMBC-(n)J (C,H) (n = 2 and 3)] and NOE experiments. Copyright (c) 2005 John Wiley & Sons, Ltd.Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatusRijo, PSimoes, MFRodriguez, BHostingInstitutionOrganizationalRepositório Científico de Acesso Aberto da ULisboae-mailmailto:repositorio@reitoria.ulisboa.ptrepositorio@reitoria.ulisboa.ptISSNIsPartOf0749-1581DOIIsPartOfhttp://dx.doi.org/10.1002/mrc.16002015-12-30T10:18:02Z20052005-01-01T00:00:00ZHandlehttp://hdl.handle.net/10451/21374http://purl.org/coar/access_right/c_14cbmetadata only accessChemistry, MultidisciplinaryChemistry, PhysicalSpectroscopyliteraturehttp://purl.org/coar/resource_type/c_6501journal articleMAGNETIC RESONANCE IN CHEMISTRYVol. 43595598 |
| spellingShingle | Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatus Rijo, P Chemistry, Multidisciplinary Chemistry, Physical Spectroscopy |
| status | SINGLETON |
| subject.fl_str_mv | Chemistry, Multidisciplinary Chemistry, Physical Spectroscopy |
| title | Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatus |
| title_full | Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatus |
| title_fullStr | Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatus |
| title_full_unstemmed | Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatus |
| title_short | Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatus |
| title_sort | Structural and spectral assignment of three forskolin-like diterpenoids isolated from Plectranthus ornatus |
| topic | Chemistry, Multidisciplinary Chemistry, Physical Spectroscopy |
| topic_facet | Chemistry, Multidisciplinary Chemistry, Physical Spectroscopy |
| url | http://hdl.handle.net/10451/21374 |
| visible | 1 |